비교란 Lysimeter를 활용한 논 토양에서의 살충제 Fenobucarb 용탈특성 구명

오영탁 ( Youngtak Oh ),임성진 ( Sungjin Lim ),김남희 ( Namhee Kim ),양지연 ( Jiyeon Yang ),최근형 ( Geunhyoung Choi ),류송희 ( Songhee Ryu ),문병철 ( Byeongchul Moon ),박병준 ( Byungjun Park ) 한국환경농학회 2016 한국환경농학회 학술대회집 Vol.2016 No.-

This study was conducted to investigate the leaching characteristics of insecticide fenobucarb using undisturbed lysimeter. Soil horizons of sandy loam, loam, and silty clay loam lysimeter were composed of 6, 6, and 5, and clay contents were ranged from 53.1-63.2, 40.2-47.7, and 32.6-39.2 %, respectively. Bulk densities of each lysimeter were 1.38, 1.30, and 1.35 Mg/m3, respectively. Fenobucarb was treated to each lysimeter at 14 days after rice planting, and water was supplied according to rice cultivation method. Pore volumes of sandy loam, loam, and silty clay loam lysimeter were calculated to 718.9, 764.2, and 735.9 L, and pore volume numbers of supplied water for rice cultivation were 2.1, 1.6, and 1.3, respectively. Movement of fenobucarb in each lysimeter was investigated through the residue of fenobucarb in 30, 55, 85, and 125 cm soil water from topsoil and leaching water. Liquid chromatography (LC)-mass spectrometry (MS)-MS was used for fenobucarb analysis in water sample. Recovery and limit of quantitation (LOQ) of fenobucarb in water were 83.2-84.7% and 50 ng/L. Changes of moisture tension, humidity, and temperature in sandy loam, loam, and silty clay loam lysimeter was not significantly different. Weight of silty clay loam lysimeter was higher than other lysimeter because of less leaching. Leaching volume decreased with increasing clay content of paddy soil, and the volume of sandy loam, loam, and silty clay loam lysimeter were 1964.7, 1868.4, and 1265.6 L, respectively. Total leaching content of fenobucarb (treatment content 1541 mg) during experiment period in sandy loam, loam, and silty clay loam lysimeter were 9.6, 14.2, 21.7 μg, respectively. The content in three lysimeter was not significantly different. Fenobucarb in soil horizon of sandy loam, loam, and silty clay loam paddy soil were detected at 180.1, 54.5, and 0.4 μg, respectively. However, the most of fenobucarb in soil horizon and leaching water detected at the primary stage of experiment. These results showed that the movement of fenobucarb in sandy loam, loam, and silty clay loam paddy soil was very high.

비교란 Lysimeter를 활용한 논 토양에서의 살충제 Chlorpyrifos-methyl의 용탈특성

오영탁 ( Youngtak Oh ),임성진 ( Sungjin Lim ),박정훤 ( Jeonghwon Park ),주형곤 ( Hyeonggon Joo ),이민호 ( Minho Lee ),윤효인 ( Hyoin Yoon ),최근형 ( Geunhyoung Choi ),류송희 ( Songhee Ryu ),박병준 ( Byungjun Park ) 한국환경농학회 2018 한국환경농학회 학술대회집 Vol.2018 No.-

This study was conducted to investigate the leaching characteristics of insecticide chlorpyrifos-methyl in paddy soil using undisturbed lysimeter. Soil horizons of sandy loam, loam, and silty clay loam lysimeter were composed of 6, 6, and 5, and clay contents were ranged from 53.1-63.2, 40.2-47.7, and 32.6-39.2 %, respectively. Bulk densities of each lysimeter were 1.38, 1.30, and 1.35 Mg/m3, respectively. Chlropyrifos-methyl was treated to each lysimeter at 15 days after rice planting, and water was supplied according to rice cultivation method. Pore volumes of sandy loam, loam, and silty clay loam lysimeter were calculated to 718.87, 764.15, and 735.85 L, and pore volume numbers of supplied water for rice cultivation were 0.98, 1.08, and 0.24, respectively. Movement of chlorpyrifos-methyl in each lysimeter was investigated through the residue of it in 30, 55, 85, and 125 cm soil water from topsoil and leaching water. Gas chromatography (GC) was used for chlorpyrifos-methyl analysis in water sample. Recovery and limit of quantitation (LOQ) of chlorpyrifos-methyl in water were 112.1-115.5% and 3 μg/L. Changes of moisture tension, humidity, and temperature in sandy loam, loam, and silty clay loam lysimeter was not significantly different during experiment period. Weight of silty clay loam lysimeter was higher than other lysimeter because of less leaching. Leaching volume of sandy loam, loam, and silty clay loam lysimeter were 705.9, 828.7, and 174.5 L, respectively. Total leaching content of chlorpyrifos-methyl (treatment content 770.57 mg) during experiment period in sandy loam, loam, and silty clay loam lysimeter were 0, 0, and 0.03 mg, respectively. These results showed that the movement of chlorpyrifos-methyl in sandy loam, loam, and silty clay loam paddy soil was very low.

볏짚 중 항생제 잔류량 동시분석

오영탁 ( Youngtak Oh ),임성진 ( Sungjin Lim ),구명화 ( Myounghwa Ku ),주형곤 ( Hyeonggon Joo ),이민호 ( Minho Lee ),윤효인 ( Hyoin Yoon ),최근형 ( Geunhyoung Choi ),류송희 ( Songhee Ryu ),박병준 ( Byungjun Park ) 한국환경농학회 2017 한국환경농학회 학술대회집 Vol.2017 No.-

This study was conducted to develop the simultaneous analysis of veterinary pharmaceuticals (VPs) in rice straw. The method for VPs in rice straw was developed and validated by LC-QTOF-MS. The method was established using solid phase extraction (SPE) cartridges. Efficiency of cartridges was tested in view of recovery and relative standard deviation (RSD). Hydrophilic lipophilic balance (HLB) cartridge was showed the higher result than that of tested other SPE cartridges. Recovery and limit of quantitation (LOQ) of tested 9 VPs in rice straw were 72.0-90.4% and 0.076-7.6 μg/L, respectively. The precision was reliable since RSD percentage (1.7-4.6%) was below 20, which was the normal percent value. The results showed that the developed method might be used the monitoring of VPs in rice straw.

농업용수 중 잔류성유기염소계 농약의 분포

임성진 ( Sungjin Lim ),오영탁 ( Youngtak Oh ),구명화 ( Myounghwa Ku ),주형곤 ( Hyeonggon Joo ),이민호 ( Minho Lee ),윤효인 ( Hyoin Yoon ),최근형 ( Geunhyoung Choi ),류송희 ( Songhee Ryu ),박병준 ( Byungjun Park ) 한국환경농학회 2017 한국환경농학회 학술대회집 Vol.2017 No.-

This study was conducted to investigate residual organochlorine pesticides (OCPs) in agricultural waters. Extraction and clean-up method were developed using the liquid-liquid extraction for OCPs in water. Limit of detection (LOD), recovery, and relative standard deviation (RSD) of OCPs and in agricultural waters ranged from 0.001-0.004 mg/L, 73.7-110.9%, and 0.9-4.2%, respectively. The residues of OCPs in agricultural water were analyzed by the developed method, and α-endosulfan, β-endosulfan, and endosulfan sulfate were detected at 0.11-0.18, 0.08-0.12, and 0.11-0.13 mg/L, respectively. The detection number of three compounds in agricultural water were 8 (9.1%), 10 (11.4%), and 20 (22.7%) among 88 samples, respectively. These results showed that endosulfans were detected in agricultural waters and the continuous monitoring of them will be conducted.

비교란 Lysimeter를 활용한 논 토양에서의 살충제 Carbosulfan 용탈특성 구명

임성진 ( Sungjin Lim ),오영탁 ( Youngtak Oh ),김남희 ( Namhee Kim ),양지연 ( Jiyeon Yang ),최근형 ( Geunhyoung Choi ),류송희 ( Songhee Ryu ),문병철 ( Byeongchul Moon ),박병준 ( Byungjun Park ) 한국환경농학회 2016 한국환경농학회 학술대회집 Vol.2016 No.-

This study was conducted to investigate the leaching characteristics of insecticide carbosulfan using undisturbed lysimeter. Soil horizons of sandy loam, loam, and silty clay loam lysimeter were composed of 6, 6, and 5, and clay contents were ranged from 53.1-63.2, 40.2-47.7, and 32.6-39.2 %, respectively. Bulk densities of each lysimeter were 1.38, 1.30, and 1.35 Mg/m3, respectively. Carbosulfan was treated to each lysimeter at 14 days after rice planting, and water was supplied according to rice cultivation method. Pore volumes of sandy loam, loam, and silty clay loam lysimeter were calculated to 718.9, 764.2, and 735.9 L, and pore volume numbers of supplied water for rice cultivation were 2.1, 1.6, and 1.3, respectively. Movement of carbosulfan in each lysimeter was investigated through the residue of carbosulfan in 30, 55, 85, and 125 cm soil water from topsoil and leaching water. Liquid chromatography (LC)-mass spectrometry (MS)-MS was used for carbosulfan analysis in water sample. Recovery and limit of quantitation (LOQ) of carbosulfan in water were 101.1-106.4% and 50 ng/L. Changes of moisture tension, humidity, and temperature in sandy loam, loam, and silty clay loam lysimeter was not significantly different. Weight of silty clay loam lysimeter was higher than other lysimeter because of less leaching. Leaching volume decreased with increasing clay content of paddy soil, and the volume of sandy loam, loam, and silty clay loam lysimeter were 1964.7, 1868.4, and 1265.6 L, respectively. Total leaching content of carbosulfan (treatment content 1541 mg) during experiment period in sandy loam, loam, and silty clay loam lysimeter were 30.7, 19.4, 23.5 ng, respectively. The content in three lysimeter was not significantly different. However, carbosulfan in soil horizon of sandy loam, loam, and silty clay loam paddy soil were detected at 2222.1, 2146.0, and 166.3 ng, respectively. These results showed that the movement of carbosulfan in sandy loam, loam, and silty clay loam paddy soil was very low, and the movement in silt clay lam paddy soil was relatively lower than sandy loam and loam paddy soil.

Head-space GC-MS를 활용한 마늘추출물 함유 유기농자재 중 Allylmethyl Sulfide, Dimethyl Disulfide 및 Dipropyl Sulfide 분석

임성진 ( Sungjin Lim ),오영탁 ( Youngtak Oh ),김진효 ( Jinhyo Kim ),최근형 ( Geunhyoung Choi ),박병준 ( Byungjun Park ) 한국환경농학회 2015 한국환경농학회지 Vol.34 No.3

BACKGROUND: Garlic (Allium sativum) contains polyphenols and sulfur compounds that are recognized as antioxidant, antithrombotic, anticancer, antibacterial, antimicrobial, nematicidal, and insecticidal activity. For this reason, the Environmentally-friendly Agriculture Promotion Act allowed the garlic extract as commercial biopesticide material for crop protection, nine commercial biopesticides containing A. sativum extract have been marketed in Korea. METHODS AND RESULTS: The determination of allylmethyl sulfide (AMS), dimethyl disulfide (DMDS), and dipropyl sulfide (DPS) in biopesticides containing A. sativum extract was developed and validated by gas chromatography (GC) mass spectrometry (MS) with head-space sampler. The developed method was validated, and the limit of quantification (LOQ) and recovery rates of AMS, DMDS, and DPS were 0.08, 0.32, and 0.09 mg/L and 90.3-91.3, 86.2-88.3, and 87.6-89.5%, respectively. From the nine commercial biopesticide samples, contents of AMS, DMDS, and DPS were analyzed using the developed method and results showed <LOQ, <LOQ-20.0 mg/L, and <LOQ, respectively. CONCLUSION: The developed method would contribute to manufactures producing commercial biopesticides and the quality control of biopesticides containing A. sativum extract.

비교란 Lysimeter를 활용한 밭 토양에서의 살충제 Chlorpyrifos 용탈특성 구명

윤효인 ( Hyoin Yoon ),임성진 ( Sungjin Lim ),오영탁 ( Youngtak Oh ),구명화 ( Myounghwa Ku ),주형곤 ( Hyeonggon Joo ),이민호 ( Minho Lee ),최근형 ( Geunhyoung ),류송희 ( Choi Songhee Ryu ),문병철 ( Byeongchul Moon ),박병준 ( Byungj 한국환경농학회 2017 한국환경농학회 학술대회집 Vol.2017 No.-

This study was conducted to investigate the leaching characteristics of insecticide chlorpyrifos in upland soil using undisturbed lysimeter. Soil horizons of sandy loam, loam, and silty clay loam lysimeter were composed of 6, 6, and 5, and clay contents were ranged from 5.0-12.0, 7.0-12.0, and 25.0-37.0%, respectively. Bulk densities of each lysimeter were 1.40, 1.41, and 1.45 Mg/m3, respectively. Chlorpyrifos was treated to each lysimeter at 14 days after Chinese cabbage planting, and water was supplied according to Chinese cabbage cultivation method. Pore volumes of sandy loam, loam, and silty clay loam lysimeter were calculated to 718.9, 701.9, and 679.3 L, and pore volume numbers of supplied water for Chinese cabbage cultivation were 0.48, 0.53, and 0.38, respectively. Movement of chlorpyrifos in each lysimeter was investigated through the residue of chlorpyrifos in 30, 55, 85, and 125 cm soil water from topsoil and leaching water. Liquid chromatography (LC)-quadrupole time of flight (QTOF)-mass spectrometry (MS) was used for chlorpyrifos analysis in water sample. Recovery and limit of quantitation (LOQ) of chlorpyrifos in water were 95.0-102.1% and 0.01 μg/L. Changes of moisture tension, humidity, weight, and temperature in sandy loam, loam, and silty clay loam lysimeter was not significantly different. Leaching volume decreased with increasing clay content of upland soil, and the volume of sandy loam, loam, and silty clay loam lysimeter were 343.1, 372.3, and 256.3 L, respectively. Total leaching content of chlorpyrifos (treatment content 770.5 mg) during experiment period in sandy loam, loam, and silty clay loam lysimeter were 0.028, 0.034, and 0.024 mg, respectively. The content in three lysimeter was not significantly different. However, chlorpyrifos in soil horizon of sandy loam, loam, and silty clay loam upland soil were detected at 307.0, 191.3, and 137.6 μg, respectively. These results showed that the movement of chlorpyrifos in sandy loam, loam, and silty clay loam paddy soil was very low because the pesticide was steadily detected in soil horizon and leachate at 150 days after treatment.

토양 중 항생제 잔류량 동시분석

주형곤 ( Hyeonggon Joo ),임성진 ( Sungjin Lim ),오영탁 ( Youngtak Oh ),구명화 ( Myounghwa Ku ),이민호 ( Minho Lee ),윤효인 ( Hyoin Yoon ),최근형 ( Geunhyoung Choi ),류송희 ( Songhee Ryu ),박병준 ( Byungjun Park ) 한국환경농학회 2017 한국환경농학회 학술대회집 Vol.2017 No.-

This study was conducted to develop the simultaneous analysis of veterinary pharmaceuticals (VPs) in soil. The method for VPs in soil was developed and validated by LC-QTOF-MS. The method was established using solid phase extraction (SPE) cartridges. Efficiency of cartridges was tested in view of recovery and relative standard deviation (RSD). Hydrophilic lipophilic balance (HLB) cartridge was showed the higher result than that of tested other SPE cartridges. Recovery and limit of quantitation (LOQ) of tested 13 VPs in soil were 72.3-117.090.4% and 0.038-3.8 μg/L, respectively. The precision was reliable since RSD percentage (1.6-5.3%) was below 20, which was the normal percent value. The results showed that the developed method might be used the monitoring of VPs in soil.

비교란 Lysimeter를 활용한 논 토양에서의 제초제 Butachlor의 용탈특성

박정훤 ( Jeonghwon Park ),임성진 ( Sungjin Lim ),오영탁 ( Youngtak Oh ),주형곤 ( Hyeonggon Joo ),이민호 ( Minho Lee ),윤효인 ( Hyoin Yoon ),최근형 ( Geunhyoung Choi ),류송희 ( Songhee Ryu ),박병준 ( Byungjun Park ) 한국환경농학회 2018 한국환경농학회 학술대회집 Vol.2018 No.-

This study was conducted to investigate the leaching characteristics of herbicide butachlor in paddy soil using undisturbed lysimeter. Soil horizons of sandy loam, loam, and silty clay loam lysimeter were composed of 6, 6, and 5, and clay contents were ranged from 53.1-63.2, 40.2-47.7, and 32.6-39.2 %, respectively. Bulk densities of each lysimeter were 1.38, 1.30, and 1.35 Mg/m3, respectively. Butachlor was treated to each lysimeter at 15 days after rice planting, and water was supplied according to rice cultivation method. Pore volumes of sandy loam, loam, and silty clay loam lysimeter were calculated to 718.87, 764.15, and 735.85 L, and pore volume numbers of supplied water for rice cultivation were 0.98, 1.08, and 0.24, respectively. Movement of butachlor in each lysimeter was investigated through the residue of it in 30, 55, 85, and 125 cm soil water from topsoil and leaching water. Gas chromatography (GC) was used for butachlor analysis in water sample. Recovery and limit of quantitation (LOQ) of butachlor in water were 88.1-104.6% and 3 μg/L. Changes of moisture tension, humidity, and temperature in sandy loam, loam, and silty clay loam lysimeter was not significantly different during experiment period. Weight of silty clay loam lysimeter was higher than other lysimeter because of less leaching. Leaching volume of sandy loam, loam, and silty clay loam lysimeter were 705.9, 828.7, and 174.5 L, respectively. Total leaching content of butachlor (treatment content 770.57 mg) during experiment period in sandy loam, loam, and silty clay loam lysimeter were 0.01, 0, and 0.07 mg, respectively. These results showed that the movement of butachlor in sandy loam, loam, and silty clay loam paddy soil was low.

비교란 Lysimeter를 활용한 밭 토양에서의 살균제 Flutolanil 용탈특성 구명

임성진 ( Sungjin Lim ),박정훤 ( Jeonghwon Park ),오영탁 ( Youngtak Oh ),주형곤 ( Hyeonggon Joo ),이민호 ( Minho Lee ),윤효인 ( Hyoin Yoon ),최근형 ( Geunhyoung Choi ),류송희 ( Songhee Ryu ),박병준 ( Byungjun Park ) 한국환경농학회 2018 한국환경농학회 학술대회집 Vol.2018 No.-

This study was conducted to investigate the leaching characteristics of fungicide flutolanil in paddy soil using undisturbed lysimeter. Soil horizons of sandy loam, loam, and silty clay loam lysimeter were composed of 6, 6, and 5, and clay contents were ranged from 53.1-63.2, 40.2-47.7, and 32.6-39.2 %, respectively. Bulk densities of each lysimeter were 1.38, 1.30, and 1.35 Mg/m3, respectively. Flutolanil was treated to each lysimeter at 15 days after rice planting, and water was supplied according to rice cultivation method. Pore volumes of sandy loam, loam, and silty clay loam lysimeter were calculated to 718.87, 764.15, and 735.85 L, and pore volume numbers of supplied water for rice cultivation were 0.98, 1.08, and 0.24, respectively. Movement of flutolanil in each lysimeter was investigated through the residue of it in 30, 55, 85, and 125 cm soil water from topsoil and leaching water. Gas chromatography (GC) was used for flutolanil analysis in water sample. Recovery and limit of quantitation (LOQ) of flutolanil in water were 72.8-84.0% and 3 μg/L. Changes of moisture tension, humidity, and temperature in sandy loam, loam, and silty clay loam lysimeter was not significantly different during experiment period. Weight of silty clay loam lysimeter was higher than other lysimeter because of less leaching. Leaching volume of sandy loam, loam, and silty clay loam lysimeter were 705.9, 828.7, and 174.5 L, respectively. Total leaching content of flutolanil (treatment content 770.57 mg) during experiment period in sandy loam, loam, and silty clay loam lysimeter were 5.66, 15.76, and 21.05 mg, respectively. These results showed that the movement of flutolanil in sandy loam and silty clay loam paddy soil was high.