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토양 공극수 내 Cu의 존재형태가 terrestrial biotic ligand model을 이용한 보리의 급성독성 예측에 미치는 영향
안진성,정부윤,이병준,남경필,An, Jinsung,Jeong, Buyun,Lee, Byungjun,Nam, Kyoungphile 한국지하수토양환경학회 2017 지하수토양환경 Vol.22 No.5
In this study, the predictive toxicity of barley Hordeum vulgare was estimated using a modified terrestrial biotic ligand model (TBLM) to account for the toxic effects of $CuOH^+$ and $CuCO_3(aq)$ generated at pH 7 or higher, and this was compared to that from the original TBLM. At pH values higher than 7, the difference in $EA_{50}\{Cu^{2+}\}$ (half maximal effective activity of $Cu^{2+}$) between the two models increased with increasing pH. As Mg concentration increased from 8.24 to 148 mg/L in the pH range of 5.5 to 8.5, the difference in $EA_{50}\{Cu^{2+}\}$ increased, and it reached its maximum at pH 8. The difference in $EC_{50}[Cu]_T$ (half maximal effective concentration of Cu) between the two models increased as dissolved organic carbon (DOC) concentration increased when pH was above 7. Thus, for soils with alkaline pH, the toxic effect of $CuOH^+$ and $CuCO_3(aq)$ are greater at higher salt and DOC concentrations. The acceptable Cu concentration in soil porewater can be estimated by the modified TBLM through deterministic method at pH levels higher than 7, while combination of TBLM and species sensitivity distribution through the probabilistic method could be utilized at pH levels lower than 7.
안진성,김주애,윤혜온,An, Jinsung,Kim, Joo-Ae,Yoon, Hye-On 한국지하수토양환경학회 2013 지하수토양환경 Vol.18 No.1
Current status of soil contamination with fluorine and its source were investigated. The basic principles and procedures of various techniques for the analysis of fluorine contents in soil and solid phase samples were summarized in this review. Analysis of fluorine in solid matrices can be achieved by two types of techniques: (i) UV/Vis spectrophotometer or ion selective electrode (ISE) analysis after performing appropriate extraction steps and (ii) direct solid analysis. As the former cases, the standard method of Korean ministry of environment, alkali fusion-ISE method, pyrohydrolysis, oxygen bomb combustion, aqua regia digestion-automatic analysis, and sequential extraction-ISE method were introduced. In addition, direct analysis methods (i.e., X-ray fluorescence spectrometry and proton induced gamma-ray emission spectrometry) and atomic spectrometry combining with the equipment for introducing solid phase sample were also reviewed. Fluorine analysis techniques can be reasonably selected through site-specific information such as matrix condition, contamination level, the amount of samples and the principles of various methods for the analysis of fluorine presented in this review.
안진성(Jinsung An),이창민(Changmin Lee),최경호(Kyungho Choi),김재영(Jae Young Kim) 유기성자원학회 2019 유기성자원학회 학술발표대회논문집 Vol.2019 No.추계
가축의 질병 치료 및 생장 촉진을 위해 사용되는 가축용 항생제(antibiotics)는 분뇨를 통해 체외로 배출된다. 이후 주변 토양 및 수계로 확산되어 생태계에 노출됨에 따라 유전자 전파 등을 통해항생제 내성균 출현을 야기하는 등 다양한 환경문제를 유발할 수 있다. 본 연구에서는 단일 농장에서발생한 돼지분뇨 내에 포함될 수 있는 chlorotetracycline(CTC)의 농도를 합리적으로 추정하기 위해축산 양태, 발생 분뇨에 대한 혐기성 소화 여부, 슬러리 구덩이 세정 빈도 등 다양한 변수를 고려하였으며, 돼지 분뇨 내 CTC가 주변 토양으로 확산될 경우를 가정하여 생태위해성평가를 수행함으로써, 축산분뇨 기원의 항생제가 주변 생태계에 미치는 영향을 정량화하였다. 생태위해성평가는 각 변수의분포에 대한 Monte-Carlo simulation을 통해 불확실성을 고려하여 진행되었으며, 민감도 분석을 통해주요한 영향인자를 도출하였다.
도시 물 문제 저감을 위한 회복탄력적 사회기반시설 구축: 1. 도시 홍수 문제 구조적 대안의 내구성 평가
이창민,정지현,안진성,김재영,최용주,Lee, Changmin,Jung, Jihyeun,An, Jinsung,Kim, Jae Young,Choi, Yongju 응용생태공학회 2016 Ecology and resilient infrastructure Vol.3 No.2
도시 내 인구집중과 기후변화로 인해 다양한 형태의 도시 물 문제가 발생한다. 이에 대한 피해 예방과 사회적 손실 최소화를 위해 회복탄력적인 대안 수립이 필요하다. 본 연구는 도시 물 문제 저감을 위한 회복탄력적 사회기반시설 구축 전략 수립에 관한 기초연구로서, 대표적인 도시 물 문제 중 하나인 도시홍수를 사례로 하여 구조적 대안의 내구성을 평가하였다. 내구성 평가를 위한 지표로 내구성 지수 (robustness index, RI) 및 비용지수 (cost index, CI)를 결합한 내구성-비용지수 (robustness cost index, RCI)를 제안하고, 이를 강남역 상습침수구역에 적용하여 기존 기반시설과 구조적 대안 (하수관거 확충, 저류조 설치, 옥상녹화)을 평가하였다. 그 결과, 2~20년 빈도의 강우강도범위에서 저류조와 옥상녹화설치가 상대적으로 높은 RCI 값을 나타내었고 두 대안 중 RCI가 보다 높은 대안은 강우강도에 따라 달라지는 경향을 보였다. 30년 빈도 강우강도에 대하여는 저류조와 옥상녹화를 병용 설치하는 대안이 가장 높은 RCI 값을 나타내어 가장 회복탄력적인 대안으로 확인되었다. 최종적으로 재해의 계획규모에 따른 현행 사회기반시설의 내구성 평가 및 최적의 구조적 대안 선택 절차를 수립하여, 도시홍수 문제에 대한 회복탄력적 사회기반시설 구축 전략을 제시하였다. Current cities encounter various types of water problems due to rapid urbanization and climate change. The increasing significance of urban water problems calls for the establishment of resilient alternatives to prevent and minimize social loss that results from these phenomena. As a background research for establishing resilient infrastructures for the mitigation of urban water problems, we evaluated the robustness of structural alternatives for urban flood as a representative case. Combining the robustness index (RI) and the cost index (CI), we suggested the robustness-cost index (RCI) as an indicator of the robustness of structural alternatives, and applied the index to assess the existing infrastructures and structural alternatives (i.e., sewer network expansion, additional storage tank construction, and green roof construction) at a site prone to floods located around Gangnam-station, Seoul, Korea. At a rainfall intensity frequency range of 2 to 20 years, the usage of a storage tank and a green roof showed relatively high RCI value, with a variation of an alternative showing greater RCI between the two depending on the size of design rainfall. For a rainfall intensity frequency of 30 years, installing a storage tank with some green roofing was the most resilient alternative based on the RCI value. We proposed strategies for establishing resilient infrastructures for the mitigation of urban floods by evaluating the robustness of existing infrastructures and selecting optimal structural alternatives with the consideration of scales of design disaster.
Biotic ligand model과 종 민감도 분포를 이용한 토양 공극수 내 Cu의 생태독성학적 허용농도 결정에 미치는 환경인자의 영향
유기현,안진성,정부윤,남경필,Yu, Gihyeon,An, Jinsung,Jeong, Buyun,Nam, Kyoungphile 한국지하수토양환경학회 2017 지하수토양환경 Vol.22 No.1
Biotic ligand model (BLM) and species sensitivity distribution (SSD) were used to determine the site-specific Cu threshold concentration (5% hazardous concentration; HC5) in soil pore water. Model parameters for Cu-BLM were collected for six plants, one collembola, and two earthworms from published literatures. Half maximal effective concentration ($EC_{50}\{Cu^{2+}\}$), expressed as $Cu^{2+}$ activity, was calculated based on activities of major cations and the collected Cu-BLM parameters. The $EC_{50}\{Cu^{2+}\}$ varied from 2 nM to $251{\mu}M$ according to the variation in environmental factors of soil pore water (pH, major cation/anion concentrations) and the type of species. Hazardous activity for 5% (HA5) and HC5 calculated from SSD varied from 0.076 to $0.4{\mu}g/L$ and 0.4 to $83.4{\mu}g/L$, respectively. HA5 and HC5 significantly decreased with the increase in pH in the region with pH less than 7 due to the decrease in competition with $H^+$ and $Cu^{2+}$. In the region with pH more than 7, HC5 increased with the increase in pH due to the formation of complexes of Cu with inorganic ligands. In the presence of dissolved organic carbon (DOC), Cu and DOC form a complex, which decreases $Cu^{2+}$ activity in soil pore water, resulting in up to 292-fold increase in HC5 from 0.48 to $140{\mu}g/L$.