포천시 공단지역 미세먼지 중 중금속농도 특성

신형순,신형순,정연훈,김진길,정종필,이상수,유한조,오조교 한국환경보건학회 2019 한국환경보건학회지 Vol.45 No.6

Objectives: The purpose of this survey was to assess the concentrations of heavy metals in the atmosphere of Pocheon City by measuring heavy metals in the industrial complex area and at the city air measuring station, and also to assess the degree of impact that the industrial area has on urban air quality. Methods: Sampling was carried out between February 2018 and November 2018 at two sites in the industrial complex and in the city air monitoring stations. Results: At the industrial complex in Pocheon City, air pollutant emitting businesses were emitting concentrations of fine dust (PM10) between 45 and 60 µg/m3 higher than in the city air. The daily maximum concentrations of lead (Pb), manganese (Mn), and cadmium (Cd) in the industrial complex are below the WHO recommendation standard (annual average), and the impact on the urban atmosphere is judged to be insignificant. Three to five percent of fine dust (PM10) consists of metallic materials, and as the fine dust increased, metals were detected proportionally. Although cadmium (Cd) and beryllium (Be) were not detected in the city air in Pocheon and chromium (Cr), copper (Cu), and arsenic (As) were found to be 50 percent or less, it is deemed that copper (Cu) was detected at unusually high levels due to unknown air pollutants, which requires regular heavy metal measurement and cause verification. Conclusions: An analysis of the heavy metals in the industrial zone and the urban atmosphere in Pocheon City in this study showed that the linear relationship of heavy metals in the industrial zone, or the direct impact relationship, on the heavy metals in the urban atmosphere could not be estimated. The sampling device for equivalent assessment of particulate matter installed at air pollution monitoring stations is highly likely to be used for analysis of fine dust and heavy metals.

난각칼슘의 제조 조건 및 유기산이 칼슘의 이온화에 미치는 영향

신형순,김공환,Shin, Hyung-Soon,Kim, Kong-Hwan 한국응용생명화학회 1997 Applied Biological Chemistry (Appl Biol Chem) Vol.44 No.4

폐기물로 버려지고 있는 난각에 다량으로 포함되어 있는 칼슘을 효율적으로 회수하고, 이온화 정도를 높일 수 있는 방법을 조사하였다. Ball mill을 이용해 난각을 분쇄해 물속에서 비중의 차이를 이용하여 난각분을 얻었고, 회전속도 30 rpm, 체류시간 30분, volume fraction 0.08에서 가장 높은 난막 제거 효과를 보였다. 난각분을 전기로에서 회화시켜 얻은 난각칼슘분의 백색도를 측정해 L값이 90이상에 도달하는 시간은 전기로 온도 850, 900, $1000^{\circ}C$에서 각각 14, 9, 3시간이 소요 되었으며, 난각칼슘분의 Hausner ratio는 1.43으로 조사되었다. 난각칼슘분은 물, 초산, 구연산, 젖산$(0.05{\sim}3%)$ 용액에서 각각 990, 3500, 3900, 4200 ppm의 이온화 정도를 나타내었다. Calcium-citrate-malate complex(CCM), calcium-citric acid complex(CC), calcium-malic acid complex(CM)는 물에서 이온화 정도가 난각칼슘분에 비해 약 4-5배 증가 하였다. An efficient process for recovery of calcium from the eggshell was developed and some organic acids were used in an attempt to enhance the degree of calcium ionization. Eggshell membrane was readily separated from crushed eggshell based on the differences in specific gravities. The conditions which allowed most efficient membrane removal were found to be 30 rpm of speed, 30 min of residence time and 0.08 of volume fraction. It took 3 hours for the eggshell powder prepared at $1000^{\circ}C$ to reach L value of 90 with the Hausner ratio being 1.43. The calcium ion concentrations were 990, 3500, 3900 and 4200 ppm in pure water, acetic acid, citric acid and lactic acid$(0.05{\sim}3%)$ aqueous solution, respectively. The degrees of ionization of calcium-citrate-malate complex(CCM), calcium-citric acid complex(CC) and calcium malic acid complex(CM) increased by 4 to 5 times compared to eggshell calcium powder.

난각칼슘의 제조 조건 및 유기산이 칼슘의 이온화에 미치는 영향

신형순,김공환 ( Hyung Soon Shin,Kong Hwan Kim ) 한국응용생명화학회 1997 Applied Biological Chemistry (Appl Biol Chem) Vol.40 No.6

An efficient process for recovery of calcium from the eggshell was developed and some organic acids were used in an attempt to enhance the degree of calcium ionization. Eggshell membrane was readily separated from crushed eggshell based on the differences in specific gravities. The conditions which allowed most efficient membrane removal were found to be 30 rpm of speed, 30 min of residence time and 0.08 of volume fraction. It took 3 hours for the eggshell powder prepared at 1000℃ to reach L value of 90 with the Hausner ratio being 1.43. The calcium ion concentrations were 990, 3500, 3900 and 4200 ppm in pure water, acetic acid, citric acid and lactic acid(0.05∼3%) aqueous solution, respectively. The degrees of ionization of calcium-citrate-malate complex(CCM), calcium-citric acid complex(CC) and calcium malic acid complex(CM) increased by 4 to 5 times compared to eggshell calcium powder.

DRAM 소프트 에러율 시뮬레이터

신형순,Shin, Hyung-Soon 대한전자공학회 1999 電子工學會論文誌, D Vol.d36 No.2

DRAM에서 알파 입자의 입사에 의한 소프트 에러율을 예측하는 시뮬레이터를 개발하였다. 새로운 시뮬레이터는 수집 전하량에 대한 해석적 모델을 사용함으로서 소자 시뮬레이터나 몬테칼로 시뮬레이터를 사용하는 기존의 예측 시뮬레이터에 비하여 계산시간을 크게 감소하였다. DRAM에서 발생하는 소프트 웨어의 모드를 분석한 결과, bit-bar 모드에 의한 소프트 에러율이 가장 큰 것을 알 수 있었으며 256M DRAM의 셀 구조에 대한 소프트 에러율을 시뮬레이션하여 storage 캐패시턴스가 약 5fF의 margin을 갖고있음을 밝혔다. A soft error rate (SER) simulator for DRAM was developed. In comparison to the other SER simulator using device simulator or Monte Carlo simulator, the proposed simulator substantially reduced the CPU time using an analytical model for the alpha-particle-induced charge collection. By analysing the soft error modes in DRAM, the bit-bar mode was identified as the main cause of soft error. Using the new SER simulator, SER of 256M DRAM was investigated and it was found that the storage capacitance had a 5fF margin.

알파 입자에 의한 전하 수집량에 대한 통합 모델

신형순,Shin, Hyung-Soon 대한전자공학회 1999 電子工學會論文誌, D Vol.d36 No.1

알파 입자의 입사에 의하여 생성된 전하중 접합으로 수집되는 전하량을 예측할 수 있는 통합 모델을 개발하였다. 이 모델은 funneling과 diffusion에 의한 전하 수집 현상을 모두 고려함으로써 접합 면적, 접합 전압 알파 입자의 입사 에너지, 입사 각도, 입사점의 위치, 그리고 접합간 격리에 사용되는 트랜치 산화막 깊이의 변화에 따른 수집전하량의 변화를 정확하게 예측할 수 있다. A Unified model for the alpha-particle-induced charge collection has been developed. By accounting for funneling and diffusion charges separately, new model accurately describes the dependence of collected charge on junction size, junction bias, injection energy, injection angle, injection point, and trench oxide depth.

Submicron에서의 소자 기술 동향

신형순 대한전자공학회 1991 전자공학회지 Vol.18 No.9

MOS소자 반전층의 전자이동도에 대한 해석적 모델

신형순 한국전기전자재료학회 1996 電氣電子材料學會誌 Vol.9 No.2

We present a new physically based analytical equation for electron effective mobility in MOS inversion layers. The new semi-empirical model is accounting expicitly for surface roughness scattering and screened Coulomb scattering in addition to phonon scattering. This model shows excellent agreement with experimentally measured effective mobility data from three different published sources for a wide range of effective transverse field, channel doping and temperature. By accounting for screened Coulomb scattering due to doping impurities in the channel, our model describes very well the roll-off of effective mobility in the low field (threshold) region for a wide range of channel doping level (Na=3.0*10$^{14}$ - 2.8*10$^{18}$ cm$^{-3}$ ).

묵현천 유역 개인하수처리시설 배출특성 연구

신형순,권경안,김세광,최필권,신종현,원종무,김구환 대한환경공학회 2013 대한환경공학회 학술발표논문집 Vol.2013 No.6

Accuracy of Root ZX in teeth with simulated root perforation in the presence of gel or liquid type endodontic irrigant

신형순,양원경,김미리,고현정,조경모,박세희,김진우 대한치과보존학회 2012 Restorative Dentistry & Endodontics Vol.37 No.3

Objectives: To evaluate the accuracy of the Root ZX in teeth with simulated root perforation in the presence of gel or liquid type endodontic irrigants, such as saline, 5.25% sodium hypochlorite (NaOCl), 2% chlorhexidine liquid, 2% chlorhexidine gel, and RC-Prep, and also to determine the electrical conductivities of these endodontic irrigants. Materials and Methods: A root perforation was simulated on twenty freshly extracted teeth by means of a small perforation made on the proximal surface of the root at 4 mm from the anatomic apex. Root ZX was used to locate root perforation and measure the electronic working lengths. The results obtained were compared with the actual working length (AWL) and the actual location of perforations (AP), allowing tolerances of 0.5 or 1.0 mm. Measurements within these limits were considered as acceptable. Chi-square test or the Fisher’s exact test was used to evaluate significance. Electrical conductivities of each irrigant were also measured with an electrical conductivity tester. Results: The accuracies of the Root ZX in perforated teeth were significantly different between liquid types (saline, NaOCl) and gel types (chlorhexidine gel, RC-Prep). The accuracies of electronic working lengths in perforated teeth were higher in gel types than in liquid types. The accuracy in locating root perforation was higher in liquid types than gel types. 5.25% NaOCl had the highest electrical conductivity, whereas 2% chlorhexidine gel and RC-Prep gel had the lowest electrical conductivities among the five irrigants. Conclusions: Different canal irrigants with different electrical conductivities may affect the accuracy of the Root ZX in perforated teeth. Objectives: To evaluate the accuracy of the Root ZX in teeth with simulated root perforation in the presence of gel or liquid type endodontic irrigants, such as saline, 5.25% sodium hypochlorite (NaOCl), 2% chlorhexidine liquid, 2% chlorhexidine gel, and RC-Prep, and also to determine the electrical conductivities of these endodontic irrigants. Materials and Methods: A root perforation was simulated on twenty freshly extracted teeth by means of a small perforation made on the proximal surface of the root at 4 mm from the anatomic apex. Root ZX was used to locate root perforation and measure the electronic working lengths. The results obtained were compared with the actual working length (AWL) and the actual location of perforations (AP), allowing tolerances of 0.5 or 1.0 mm. Measurements within these limits were considered as acceptable. Chi-square test or the Fisher’s exact test was used to evaluate significance. Electrical conductivities of each irrigant were also measured with an electrical conductivity tester. Results: The accuracies of the Root ZX in perforated teeth were significantly different between liquid types (saline, NaOCl) and gel types (chlorhexidine gel, RC-Prep). The accuracies of electronic working lengths in perforated teeth were higher in gel types than in liquid types. The accuracy in locating root perforation was higher in liquid types than gel types. 5.25% NaOCl had the highest electrical conductivity, whereas 2% chlorhexidine gel and RC-Prep gel had the lowest electrical conductivities among the five irrigants. Conclusions: Different canal irrigants with different electrical conductivities may affect the accuracy of the Root ZX in perforated teeth.

소독부산물 최소화를 위한 운영조건 연구

신형순,최필권,김종수,최일우,김상훈,김태현,이경희,이수문,장은아,정연훈,김주열 대한상하수도학회 2005 상하수도학회지 Vol.19 No.3