Estimation of Carbon Sequestration and Its Profit Analysis with Different Application Rates of Biochar during Corn Cultivation Periods

신중두,최용수,이선일,Shin, JoungDu,Choi, Yong-Su,Lee, SunIl Korea Organic Resources Recycling Association 2016 유기물자원화 Vol.25 No.3

바이오차 시용이 토양비옥도나 온실가스 완화에 기여하는 것 외에, 경작지 시용에 따른 탄소격리 및 순익 분석이 평가된바 거의 없다. 본 연구는 옥수수 재배 기간 동안 온실가스 완화에 대한 이익을 평가하고, 탄소격리를 산정하기 위해 수행되었다. 본 실험의 처리구는 돈분처리구, 돈분을 퇴비로 시용하면서 바이오차 처리를 2,600(0.2%), 13,000(1%), 및 26,000(2%) kg/ha로 나누어 시용하였다. 바이오차 시용에 따른 탄소 격리량을 예측하기 위해 Y = 0.5523X - 742.57 ($r^2=0.939^{**}$) 일차 모형식을 유도하였으며, 본 수식을 바탕으로 바이오차 0.2, 1 및 2% 시용 시 탄소 격리량은 각각 1,235, 3,978, 및 14,794 kg/ha로 산정되었고, 온실가스 완화는 각각 4.5, 14.6, 및 54.2 ton/ha로 평가 되었다. 이에 대한 이익 평가는 적게는 $14.6, 많게는 $452로 산정되었다. 또한 한국 기후변화 시장의 이산화탄소 시장 거래가로는 바이오차 0.2, 1 및 2% 시용 시 $35.6, $115.3 및 $428.2로 나타났다. 바이오차 시용에 대한 작물 재배에 있어, 초장과 수량은 처리간에 유의차가 인정되지 않았다. 따라서 본 실험결과는 농사활동에서 바이오차를 토양에 시용함으로서 탄소 배출건 거래제가 시행된다는 전제 조건하에 기초자료가 될 것이다. Despite the ability of biochar to enhance soil fertility and to mitigate greenhouse gas, its carbon sequestration and profit analysis with arable land application have been a few evaluated. This study was conducted to estimate carbon sequestration and to evaluate profit of greenhouse gas mitigation during corn cultivation periods. For the experiment, the biochar application rates were consisted of pig compost(non application), 2,600(0.2%), 13,000(1%), and 26,000(2%) kg/ha based on pig compost application. For predicting soil carbon sequestration of biochar application, it was appeared to be linear model of Y = 0.5523X - 742.57 ($r^2=0.939^{**}$). Based on this equation, soil carbon sequestration by 0.2, 1 and 2% biochar application was estimated to be 1,235, 3,978, and 14,794 kg/ha, and their mitigations of $CO_2$-eq. emissions were estimated to be 4.5, 14.6, and 54.2 ton/ha, respectively. Their profits were estimated at $14.6 for lowest and $452 for highest. In Korea Climate Exchange, it was estimated that the market price of $CO_2$ in corn cultivation periods with 0.2, 1 and 2% biochar application was $35.6, $115.3 and $428.2 per hectare, respectively. For the plant growth response, it was observed that plant height and fresh ear yield were not significantly different among the treatments. Therefore, these experimental results might be fundamental data for assuming a carbon trading mechanism exists for biochar soil application in agricultural practices.

돈분처리 시스템을 포함한 액비 시용에 따른 옥수수 재배과정에 대한 전과정 환경영향 평가

신중두,이선일,박우균,최용수,나영은,박유성 유기성자원학회 2014 유기물자원화 Vol.22 No.2

The application of the Life Cycle Impact Assessment (LCIA) methodology to analyze the environmental burden of appling the digestates to corn field including different swine waste treatment systems was investigated. The first part of LCA is an inventory of parameters used to emissions released due to the system under investigation. In the following step, the Life Cycle Impact Assessment, the inventory data were analyzed and aggregated in order to finally get one index representing the each environmental burden. Each corn field applied with the aerobic and anaerobic digestates including different swine waste treatment systems was used as an example for the life cycle impact analysis. With analyzing the agricultural environmental burden, it observed that the effect of corn field applied aerobic digestate including digestion system was 7.6 times higher at eutrophication effects, but global warming potential effect was 0.9 times less than its applied anaerobic digestate. 각기 다른 돈분 처리시스템 운영 과정을 포함하여 액비의 농경지 살포에 따른 옥수수 재배에 대한 환경영향을 분석하기 위하여 전과정 평가방법을 적용하였다. 전과정평가의 첫 번째 부분은 사용될 분석 항목을 구성하는 것으로 돈분 처리시스템 운영에 대한 유입 및 배출에 대한 항목이며, 전과정 영향평가를 위한 다음 단계로서 전체 환경부하를 최종적으로 하나의 지수로 통합하기 위하여, 특정 항목에 대한 자료를 취합하고 분석하는 것이다. 전과정 영향 분석을 위한 실례로서 호기 및 혐기소화시스템 운영부터 호기 및 혐기 액비의 농경지 시용에 대한 옥수수 재배과정에 이르기 까지를 평가하였다. 농업환경영향에 대한 부하량 평가에서, 혐기소화액을 이용한 옥수수 재배에서는 수계부영야화가 7.6배 높았으며, 지구온난화에 대한 생태지표 지수(Eco-indicator value)는 10.9 tonne CO2 eq.로 0.9배 적게 배출하는 것으로 산정되었다.

혐기소화 공정 및 원료 유형별 바이오가스 생산에 미치는 영향

신중두,홍승길,박우균,박상원 유기성자원학회 2011 유기물자원화 Vol.19 No.4

Objective of this study was to investigate the effect of biogas production to different systems and feeding stocks. For the biogas production through operating the temperature phase anaerobic digestion(TPAD) with different feeding stocks, the stage state of biogas production with 70% of methane concentration in the thermophilic digestion tank with co-digestion of food waste and swine manure(40 : 60) was delayed at 3.5times, but its mesophilic tank was short for 5 days as relative to the swine manure. The cumulative methane production in the thermophilic digestion tank with co-digestion of food waste and swine manure was started with greater than its swine manure at 60 days after digestion periods. However, its mesophilic tank with swine manure was great at 3 days after digestion periods. For aspect of anaerobic digestion processes with swine manure, it was appeared that the stage state of biogas production rate in TPAD was shorter than the two phase anaerobic digestion system. 본 연구의 목적은 TPAD(Temperature Phased Anaerobic Digestion)시스템〔고온조(55℃)와 중온조(35℃)〕과 이상혐기소화시스템〔중온조(35℃)와 중온조(35℃)〕공정을 비교하고, 이러한 공정을 적용한 유기성 자원별 바이오가스 생산량을 비교하는 것이었다. 원료별 TPAD시스템을 적용한 바이오가스 생산량을 비교해 볼 때, 고온조에서 돈분과 음식물류폐기물을 혼합한 원료를 사용한 경우는 돈분만 사용하였을 때 보다 혐기소화 공정의 안정화에 걸리는 기간은 3.5배가 지연되었지만, 중온조의 경우, 돈분과 음식물류폐기물을 혼용 처리하였을 때 메탄가스 농도 약 70%로 체류시간을 5일 앞당겨 안정화 단계에 도달하는 것으로 나타났다. 돈분과 음식물류폐기물을 혼합한 원료의 경우 고온조에서 혐기소화 60일을 기점으로, 또한 중온조의 경우 초기단계인 혐기소화 3일 후부터 돈분만 사용한 경우 보다 누적메탄가스 발생량이 많게 나타났다. 또한 혐기소화 공정측면에서 돈분을 이용한 TPAD시스템 운영은 이상혐기소화시스템 보다 조기에 공정의 안정화 단계에 도달하는 것으로 나타났다.

Estimation of potential methane production through the mass balance equations from agricultural biomass in Korea

신중두,홍승길,김성철,양재의,이상룡,Fan-Zhu Li 한국응용생명화학회 2016 Applied Biological Chemistry (Appl Biol Chem) Vol.59 No.5

Biomass is a renewable energy resource derived from all organic materials produced by both human and natural activities. Total biomass is amounted to be 58,010 Gg yr-1 from agricultural sector during 2013 in Korea: livestock manure, crop residues, and agro-industrial wastes. Potential methane production from agricultural biomass was calculated based on IPCC guidelines using manipulated equations. The main parameters were emission factor, total waste amount, and physico-chemical properties of each waste to estimate methane production. Calculated total potential methane production from the different categories for livestock, crop residues, and agro-industrial wastes was 502 Gg yr-1 in Korea. Poultry waste generated the highest methane potential with 227 Gg yr-1 followed by 80 Gg yr-1 from cattle waste. For crop residues and agroindustrial wastes, estimated methane production was 1 and 126 Gg yr-1, respectively. Results of this study show that livestock manure gave the highest methane emission in the agricultural sector. With this, more effective management of livestock wastes is necessary to develop and maximize technology on harnessing methane as alternative energy.

Predicting Methane Production on Anaerobic Digestion to Crop Residues and Biomass Loading Rates

신중두,홍승길,박상원,김현욱,Shin, JoungDu,Hong, Seung-Gil,Park, SangWon,Kim, HyunWook Korea Organic Resources Recycling Association 2016 유기물자원화 Vol.25 No.3

본 연구의 목적은 농업에서 발생하는 식물체 잔사 종류별 투입비율에 따른 메탄 잠재 발생량을 예측하는 것이다. 바이오가스를 생산하기 위하여 보릿짚 및 유채대 등의 식물체 잔사를 다양한 투입율로 사용하여 세륨병에서 실험을 수행하였다. 표면 방법론의 운동방법을 통하여 메탄 생산은 Gomperz 수식에 적합한 것으로 나타났다. 중온소화 시 식물체 잔사별 바이오가스 생산에 있어, 최대생산량은 보릿짚 및 유채대 투입율 1%로 혐기소화 후 각각 6.8일에 37.2 mL/g과 7.5일에 28.0 mL/g로 나타났다. 중온소화 시 메탄 함량은 보릿짚 및 유채대 투입율 5%로 혐기소화 후 각각 5.5일에 61.7%와 3.4일에 75.0%로 가장 높게 관측되었다. 중온 소화시 최대 메탄 잠재발생량은 1% 보릿짚 투입율에서 159.59 mL/g 와 3% 유채대 투입율에서 156.62 mL/g로 산정되었다. 전반적으로 중온소화 시 바이오매스 투입율은 유채대 3% 및 보릿짚 1%를 투입하는 것이 적정 비율인 것으로 나타났다. Objective of this experiment was to predict the potential methane production with crop residues at different loading rates. Anaerobic digestion of barley and rapeseed straw substrates for biogas production was performed in Duran bottles at various biomass loading rates with crop residues. Through kinetic model of surface methodology, the methane production was fitted to a Gompertz equation. For the biogas production at mesophilic digestion with crop residues, it was observed that maximum yield was 37.2 and 28.0 mL/g at 6.8 and 7.5 days after digestion with 1% biomass loading rates of barley and rapeseed straws, respectively. For the methane content of mesophilic digestion, there were highest at 61.7% after 5.5 days and 75.0% after 3.4 days of digestion with barley and rapeseed straw on both 5% biomass loading rates, respectively. The maximum methane production potentials were 159.59 mL/g for 1% barley straw and 156.62 mL/g for 3% rapeseed straw at mesophilic digestion. Overall, it would be strongly recommended that biomass loading rate was an optimum rate at mesophilic digestion for using 1% barley and 3% rapeseed straws for feed stocks.

Hydro-thermal Liquefaction Technology적용시유채대를이용한Crude oil생산에미치는반응온도의영향

신중두,홍승길,권순익,박우균,박상원 유기성자원학회 2010 유기물자원화 Vol.18 No.1

Hydro-thermal liquefaction technology for rapeseed straws was investigated the biomassconversion rate with different catalysts and reaction temperatures. NaOH and KOH were usedfor catalysts, and the reaction temperature were ranged from 180 to 320℃at every 20℃ofintervals for 10 minutes. The reaction was carried out in a 5,000 mL liquefaction system withdispenser and external electrical furnace. Raw materials (160g), 2,000 mL of distilled water and10% (wt/wt) of catalyst to plant residue were fed into the reactor. It was observed that themaximum crude oil yield was about 36% at temperature range, 260~280℃with KOH and at 300℃with NaOH, respectively. It was observed that the more calorific values of crude oil, thehigher reaction temperature with KOH, but it had the reverse pattern in NaOH. 본연구는hydrothermal 액화공정에서는유채대를사용하여액화공정적용시반응온도에따른Crude oil 전환효율을비교하였다. 촉매제로NaOH 및KOH와같은촉매제를사용하여반응온도180~320℃범위에서20℃간격으로10분동안반응시켰다. 액화공정시스템은외부전기화로, 교반기및5,000 mL의반응기로구성되어있다. 반응기에식물체잔사160g, 증류수2,000 mL 및촉매제를혼합하였으며, 촉매제량은식물체잔사량의10%(wt/wt)를투입하였다. Crude oil생산량은반응온도260~280℃에서약36%로나타났으며, NaOH의경우반응온도300℃에서전환효율이NaOH와비슷함을보였다. 촉매제별Crude oil에대한발열량변화는NaOH를사용한경우반응온도가증가함에따라발열량은감소하였지만, KOH의경우발열량은증가하는경향을보였다.

Run-off Impact Assessment of the Steeped Cornfield to Small Stream

신중두,이종식,김원일,정구복,소규호,이정택,이명선 한국환경농학회 2005 한국환경농학회지 Vol.24 No.4

This experiment was conducted to evaluate the nutrient loss and to assess the eutrophication into small stream by intensive rains in the steeped cornfield during cultivation. The crop cultivated was a soiling corn (DW5969), and the experimental plots were divided into two parts that were 10 and 18% of slope degrees. The amount of T-N and T-P loss was calculated by analysis of surface run-off water quality, and was investigated the effect of eutrophication to small stream as a part of life cycle assessment (LCA) methodology application. For the surface run-off water quality, EC and T-N values were highest in first runoff event as compared to the other events and maintained the stage state with litter variations at every hour during the runoff period except for EC in the slope 18%. However, T-P concentration has been a transient stage after runoff event of July 27. Total surface run-off ratio was not significantly different with slope degrees, but amount of T-N and T-P losses at 18% of slope were high as 5.96 kg ha-1 and 0.65 kg ha-1 as relative to 10% of slope degree, respectively. Furthermore, T-N losses from run-off water in the sloped cornfield 10 and 18% were approximately 9.8 and 12.5% of the N applied as fertilizer when the fertilizer applied at recommended rates after soil test, respectively. For the eutrophication impact to the small stream, it was shown that PO4 equivalence and Eco-indicator value at 18% of slope degree were greater as much 6.11 kg ha-1 and 0.81 as compared to the slope angle 10%, respectively. Therefore, it was appeared that each effect of nutrient losses, eutrophication and Eco-indicator value was enhanced according with higher slope degree.

가축분뇨 처리시스템에 대한 전과정평가 방법을 적용한 환경영향 평가

신중두,이선일,박우균,홍승길,최용수 유기성자원학회 2013 유기물자원화 Vol.21 No.3

가축분뇨 처리시스템에 대한 환경영향을 분석하기 위하여 전과정 평가방법을 적용하였다. 전과정평가의 첫 번째 부분은 사용될 분석 항목을 구성하는 것으로, 가축분뇨 처리시스템에 대한 유입 및 배출에 대한 항목이다. 전과정 영향평가를 위한 다음 단계로서 전체 환경부하를 최종적으로 하나의 지수로 통합하기 위하여, 특정 항목에 대한 자료를 취합하고 분석하는 것이다. 전과정 영향평가를 위해, Eco-indicator 95 방법은 체계화 되었으며, 규칙적으로 적용된 영향평가 방법이기 때문에 선택하였다. 전과정 영향 분석을 위한 실례로서 호기 및 혐기소화 시스템과 같은 두 종류의 돈분 처리시스템을 선정하였다. 돈 분뇨 처리시스템에 대한 농업환경영향을 평가한 항목을 확립하였고, 혐기소화시스템에서는 전 인산 배출이 높았으며, 호기소화시스템에서는 이산화탄소 배출이 높은 것으로 관측되었다. 돈분 1ton을 처리하는데 관련된 돈분처리시스템에 대한 환경영향 평가에서 Eco-indicator 수치에 따르면, 호기소화 시스템에 있어 지구온난화 및 토양산성화에서 음의 지수를 보인 반면 혐기소화시스템은 수계 부영양화 부분에서 비교적 높은 양의 지수를 보였다. The application of the Life Cycle Assessment (LCA) methodology to analyze the environmental impact to different swine waste treatment systems was investigated. The first part of LCA is to organize an inventory of parameters and emissions released due to the system under investigation. In the following step of the Life Cycle Impact Assessment, the inventory data were analyzed and aggregated in order to finally get one index representing the total environmental burden. For the Life Cycle Impact Assessment (LCIA) the Eco-indicator 95 method has been chosen because this is well documented and regularly applied impact method. Two different swine waste treatment systems such as aerobic and anaerobic digestion systems were chosen as an example for the life cycle impact analysis. For establishing the parameters to be assessed the agricultural environmental effects to above swine waste treatment systems, it has been observed that there was high at T-P emission in anaerobic digestion system and CO2 emission in aerobic digestion system. For Eco-indicator values per environmental effect for swine waste treatment systems related to one tonne of swine waste, it was shown that there was a negative index for global warm potential and soil acidification in aerobic digestion system, but relatively high positive index for eutrophication in anaerobic digestion system.

벼 재배 시 바이오차 펠렛 시용 수준에 따른 농업 환경 영향 및 토양 탄소격리 평가

신중두,박도균,김희선,이선일,홍승길 한국환경농학회 2020 한국환경농학회지 Vol.39 No.2

BACKGROUND: Biochar-based fertilizers delay the nutrient release and feature a slow release effect for agricultural and environmental advantages. This experiment was conducted to evaluate agro-environmental effects of different application ratios of modified biochar pellets supplemented. METHODS AND RESULTS: The treatments consisted of the control, 40% N, 60% N and 60% N (0.07M MgO) of modified supplemented biochar pellets (MSBP), which were based on recommended ratio of nitrogen for rice cultivation. For the paddy water, the NH4-N and NO3-N concentrations in whole treatments rapidly increased at 84 days and 40 days after transplanting, respectively. The PO4-P concentrations in the MSBP were generally lower than those of the control. For the paddy soil, NH4-N concentrations in the MSBP were higher than those of the control at 5 days after transplanting, while NO3-N concentrations were not significantly different in the treatments through rice cultivation. P2O5 concentrations in the control were higher than those of the MSBP until 40 days after transplanting while K2O concentrations were not significantly different among the treatment. The highest carbon sequestration was 970 kg ha-1 in the 60% N (0.07M MgO), and the potential carbon storage in the 60% N (0.07M MgO) was higher at 222 kg ha-1 than the control during rice cultivation. It shown that the rice yield in the control was not significantly different from the 40% N and 60% N (0.07M MgO) application plots. CONCLUSION: Application of MSBP for rice cultivation was effective for carbon sequestration and agro-environmental effects even though nitrogen application ratio was reduced at 40% based on recommended application ratio of fertilizer. .

Influnce of Plant Residues on Net Mineralization and Nitrification of the Selected Piedmont Soils in North Carolina

신중두,Shin, Joung-Du 한국토양비료학회 1997 한국토양비료학회지 Vol.30 No.1

Determination of N mineralization and nitrification potentials of selected Piedmont soils of North Carolina requires a better understanding of the influences of incorporated plant residues. The net N mineralization and nitrification were significantly influenced by the soil types and by plant species. The net N mineralization and nitrification of soils mixed with plant residues were consistently increased with successional incubation periods. The net mineralization and nitrification ranged from $9.77{\mu}g/g$ to $143.80{\mu}g/g$, and from $5.31{\mu}g/g$ to $145.66{\mu}g/g$ during the incubation periods, respectively. The net N mineralization was more influenced by NO3-N than by NH4-N. Overall, the greatest proportions of net N mineralization and nitrification occurred in Chewacla and Wehadkee and lowest in Enon and Mecklenburg. For the plant residues, the net N mineralization and nitrification were observed to be lowest in corn and highest in soybean. In a low-input agricultural systems, soybean may be planted as cover crop which may improve the nitrogen status of selected Piedmont soils of North Carolina. North Caralina의 대표적인 piedmont 토양에 내재하고 있는 질소무기화 및 질산화 과정에 대한 결정은 식물체 잔사 처리로 인한 효과에 관한 이해를 필요로 한다. 질소무기화 및 질산화 과정은 토양종류 및 식물체의 종류에 따라 유의성 있게 영향을 받았다. 식물체 잔사를 처리한 토양의 질소 무기화 및 질산화량은 계속적인 배양 기간에 따라 꾸준히 증가되었으며, 질소무기화 및 질산화량은 배양 기간 동안 각각 $9.77{\mu}g/kg{\sim}143.80{\mu}g/kg$과 $5.31{\mu}g/kg{\sim}145.66{\mu}g/kg$ 이었다. 질소무기화 과정은 $NH_4-N$보다는 $NO_3-N$에 더 영향을 받았다. 전반적으로 가장 많은 질소무기화 및 질산화량은 Chewela와 Wehadkee 토양에서 발생하였으며, Enon과 Mecklenburg 토양에서 낮은 수치로 나타났다. 식물체 잔사 효율은 옥수수 식물체 잔사 처리에서 가장 낮았으며, 콩 식물체 잔사 처리에서 가장 높은 것으로 관측되었다. 저 투입 농업체계에서 콩 식물체의 잔사 처리가 North Caralina의 대표적인 Piedmont의 질소상태를 증진시키는 피복작물로서 유효하다고 사료된다.