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올레핀 저장/회수 기술 응용을 위한하이드로퀴논 크러스레이트의 분광학적 분석 연구
이종원,도뗄 쁘라틱,강성필 한국수소및신에너지학회 2013 한국수소 및 신에너지학회논문집 Vol.24 No.5
Clathrate samples, using hydroquinone as a host and ethylene or propylene as a possible guest, were prepared and analyzed by means of spectroscopic measurements. Obtained results showed that ethylene can form clathrate compounds with hydroquinone at 4.0MPa and room temperature, while propylene cannot form clathrate compounds. Different formation behaviors of these two olefin compounds can be applied to a clathrate-based storage/recovery of ethylene in a selective way, and can provide useful information on the cavity size of the formed clathrate compounds.