LED용 Sr2Ga2S5:Eu2+ 황색 형광체의 합성 및 발광특성

김재명,박정규,김경남,이승재,김창해,장호겸,Kim, Jae-Myeong,Park, Jeong-Gyu,Kim, Gyeong-Nam,Lee, Seung-Jae,Kim, Chang-Hae,Jang, Ho-Gyeom 대한화학회 2006 대한화학회지 Vol.50 No.3

LED는 고휘도 청색 칩의 개발로 인해 단순표시소자로만 이용되던 것이 다양한 분야의 발광소자로 적용되기 시작하였다. 특히, 최근에 InGaN 칩과 황색 형광체(YAG:Ce3+)를 이용한 방법이 많이 연구되어지고 있다. 하지만 이 방법은 2 파장을 이용한 것으로 색연지수가 낮은 단점을 지니며, 황색의 YAG:Ce3+ 형광체 이외에 450~470 nm의 여기 영역에서 효율적으로 발광하는 형광체가 거의 없다. 따라서 본 연구에서는 장파장 영역의 여기 특징을 지닌 thiogallate 형광체의 합성을 시도하였다. 그 중에 가장 잘 알려진 SrGa2S4:Eu2+ 형광체의 모체를 변화시켜 Sr2Ga2S5:Eu2+ 형광체를 합성하였으며, 발광특성을 조사하였다. 그리고 무해성과 제조 공정의 단순화를 위하여, 황화물질과 5 % H2/95 % N2 혼합 기체를 CS2와 H2S 가스 대신에 사용하였다. 이렇게 합성되어진 형광체는 550 nm의 발광 중심을 가지는 황색 형광체로서 300~500 nm에 이르는 넓은 여기원을 통한 발광이 가능하다. 그리고 YAG:Ce3+ 형광체와 비교해 볼 때 강도 면에서 110 % 이상을 보이며, UV 영역의 여기적 특성을 이용해 UV LED에도 응용이 가능하다. Nowadays, LEDs has been applied to the luminescent devices of various fields because of the invention of high efficient blue chip. Recently, especially, the white LEDs composed of InGaN blue chips and a yellow phosphor (YAG:Ce3+) have been investigated extensively. With the exception of YAG:Ce3+ phosphor, however, there are no reports on yellow phosphor that has significant emission in the 450~470 nm excitation range and this LED system is the rather low color rendering index due to their using two wavelength. Hence, we have attempted to synthesize thiogallate phosphors that efficiently under the long wavelength excitation range in the present case. Among those phosphors, we have synthesized Sr2Ga2S5:Eu2+ phosphor by change the host material of SrGa2S4:Eu2+ which is well known phosphor and we investigated the luminescent properties. In order to obtain the harmlessness and simplification of the synthesis process, sulfide materials and mixture gas of 5 % H2/95 % N2 were used instead of the CS2 or H2S gas. The prepared phosphor shows the yellow color peaking at the 550 nm wavelength and it possible to emit efficiently under the broad excitation band in the range of 300~500 nm. And this phosphor shows high luminescent intensity more than 110 % in comparison with commercial YAG:Ce3+ phosphor and it can be applied for UV LED due to excitation property in UV region.

산 에칭에 의한 BaO-B₂O₃-ZnO계 유리조성물의 용출 현상

김재명,홍경준,김남석,김형순,Kim, Jae-Myung,Hong, Kyung-Jun,Kim, Nam-Suk,Kim, Hyung-Sun 한국세라믹학회 2006 한국세라믹학회지 Vol.43 No.1

For producing the fine ribs structure of plasma display panel, the metal ions of barrier materials during the etching process should be understood on the etching mechanism with etching conditions. Etching was done on bulk glasses of the $BaO_B_2O_3-ZnO$ system with $HNO_3$ solution at $40^{\circ}C$. The surface structure of glasses and ion dissolution were analyzed by ICP (Inductive Coupled Plasma measurement). The structure and surface of the etched bulk glass were investigated by using scanning electron microscopy and nanoindenter. As a result, Ba (3-35 ppm/min) and Zn (2-27 ppm/min) ions as major components were leached in the solution and the leached layers were found to be phosphor-rich surface layers. A decrease of the bridge oxygen and relative increase of non bridge oxygen in the etched glass were found by X-ray photoelectron spectroscopy.

고상법을 이용한 LED용 SrGa₂S₄:Eu 녹색 형광체의 합성 및 발광특성

김재명,김경남,박정규,김창해,장호겸,Kim, Jae-Myung,Kim, Kyung-Nam,Park, Joung-Kyu,Kim, Chang-Hae,Jang, Ho-Gyeom 대한화학회 2004 대한화학회지 Vol.48 No.4

The $SrGa_2S_4:Eu^{2+}$ green emitting phosphor has been studied as a luminous device for CRT (Cathode Ray Tube) or FED (Field Emission Display) and EL (Electroluminescence). This phosphor, also, is under noticed for LED (Lighting Emitting Diode) phosphor, which makes use of excitation characteristics of long wavelength region. The $SrGa_2S_4:Eu^{2+}$ phosphor was prepared generally conventional synthesis method using flux. However, this method needs high heat-treated temperature, long reaction time, complex process and harmful $H_2S$or $CS_2$ gas. In this works, therefore, we have synthesized $SrGa_2S_4:Eu^{2+}$ using SrS, $Ga_2S_3$, and EuS as starting materials, and the mixture gas of 5% H2/95% N2 was used to avoid the $H_2S$or $CS_2$. We investigated the luminescence characteristic of $SrGa_2S_4:Eu^{2+}$ phosphor prepared in various synthesis conditions, performed post-treatment and sieving process for application to LED. 기존의 $SrGa_2S_4:Eu^{2+}$ 녹색 발광 형광체는 주로 CRT (Cathode Ray Tube)용이나 FED (Field Emission Display), 그리고 EL (Electroluminescence)용 발광소자로 많이 연구되어졌다. 현재는 장파장 영역의 여기 특성을 이용한 LED (Light Emitting Diode)용 형광체로 주목 되어지고 있다. $SrGa_2S_4:Eu^{2+}$ 형광체의 일반적 합성 방법은 Flux를 이용하여 인체에 유해한 $H_2S$나 $CS_2$ 기체를 사용할 뿐만 아니라 높은 합성온도, 긴 반응시간 및 공정이 복잡한 단점을 지니고 있다. 따라서 본 실험은 황화물계 원료인 SrS, $Ga_2S_3$ 그리고 EuS를 출발 물질로 하여 $H_2S$ 기체를 사용하지 않고 혼합 기체$(5% H_2/95% N_2)$를 사용해 환원 분위기 하에서 $SrGa_2S_4:Eu^{2+}$을 합성하였다. 그리고 다양한 합성 조건과 LED용으로 사용되기 위해 수세처리와 Sieving 과정을 거친 형광체의 발광특성을 검토하였다.

LED용 BaGa₂S₄:Eu²⁺ 녹색 형광체의 합성 및 발광특성

김재명,박정규,김경남,이승재,김창해,Kim, Jae-Myung,Park, Joung-Kyu,Kim, Kyung-Nam,Lee, Seung-Jae,Kim, Chang-Hae 한국재료학회 2006 한국재료학회지 Vol.16 No.12

[ $II-III_2-(S,Se)_4$ ] structured of phosphor has been used at various field because those have high luminescent efficiency and broad emission band. Among these phosphors, the europium doped $BaGa_2S_4$ was prepared by solid-state method and had high potential application due to an emissive property of UV region. Also, the common sulfide phosphors were synthesized by using injurious $H_2S\;or\;CS_2$ gas. However, in this study $BaGa_2S_4:Eu^{2+}$ phosphor in addition to excess sulfur was prepared under at 5% $H_2/95%\;N_2$ reduction atmosphere. Thus, this process could be considered as large scale synthesis because of non-harmfulness and simplification. The photoluminescence efficiency of the prepared $BaGa_2S_4:Eu^{2+}$ phosphor increased 20% than that of commercial $SrGa_2S_4:Eu^{2+}$ phosphor. The prepared $BaGa_2S_4:Eu^{2+}$ could be applied to green phosphor for white LED of three wavelengths.

축산식품 중에 잔류하는 Gentamicin 검사를 위한 ELISA 개발에 관한 연구

김재명,이문한,이항,류판동,조명행,박종명,Kim, Jae-Myung,Lee, Mun-Han,Lee, Hang,Ryu, Pan-Dong,Cho, Myung-Haing,Park, Jong-Myung 한국식품위생안전성학회 1994 한국식품위생안전성학회지 Vol.9 No.3

An enzyme-linked immunosorbent assay(ELISA) was developed for the detection of residual gentamicin(GM) in edible animal products. The immunogen(GM-KLH conjugate) and coating antigen(GM-BSA conjugate) were prepared by coupling GM sulfate to keyhole limpet hemocyanin(KLH) and bovine serum albumin(BSA) in the presence of 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride, respectively. Polyclonal antibody to GM was produced in rabbits(New Zealand White, female) by using the immunogen and the antibody titer was measured by indirect ELISA. A competitive ELISA was developed using GM-bovine serum albumin conjugate as a coating antigen, GM(as standards or sample), polyclonal antibody to GM, secondary antibody conjugated with horseradish peroxidase as an enzyme, and H2O2 and o-phenylenediamine dihydrochloride as a substrate and a chromophore, respectively. The detection limit of GM was 10 ng/ml and the standard curve of GM(n=26) was linear up to 10 $\mu\textrm{g}$/ml in this competitive ELISA system. There were no cross-reactivities of the partially purified antibody between GM and the various antibiotice such as amikacin, benzyl-penicillin, chloramphenicol, erythromycin, furazlidone, kanamycin, neomycin, oleandomycin, streptomycin, sulfathiazole and thiamphenicol(CR50<0.05%)

상수도 지하시설물 탐사 개선에 관한 연구

김재명,이병운,최윤수,윤하수,Kim, Jae-Myeong,Lee, Byung-Woon,Choi, Yun-Soo,Yoon, Ha-Su 한국공간정보학회 2010 한국공간정보학회지 Vol.18 No.4

상수도 시설물은 노사 인프라를 구성하는 필수적인 요소이다. 이러한 상수도 지하시설물을 체계적이고 과학적으로 관리하기 위하여 상수도 GIS를 구축하였으며, 이러한 상수도 GIS 구축을 위해서는 지하에 매설된 상수도 시설물을 정확히 탐사하여 DB를 구축하여야 한다. 본 연구에서는 상수도 지하시설물에 대한 탐사율 재고방안을 모색하기 위하여 통계적인 자료를 동하여 탐사율 저하 원인을 분석하고, 서울시 상수도 GIS의 사례 조사를 통하여 탐사에 대한 표준화 방안을 제시하였다. 연구결과 상수도 지하시설물 측량 시 비금속 관로는 탐사 결과가 불확실하고 공공측량 성과심사를 받기가 어렵기 때문에 탐사를 하지 않고 있으며, 탐사에 대한 표준 작업규정이 없어 체계적인 탐사를 시행하지 못하고 있는 것으로 조사되었는데, 이 두 가지 요인이 탐사율 저하의 주요 원인으로 파악되었다. 본 연구를 통하여 상수도 지하시설물 탐사에 대한 업무 표준화 방안용 제시하였으므로 탐사 작업 시 체계적인 탐사가 가능하여 탐사율을 향상시킬 수 있을 것으로 판단되며, 탐사율 제고를 위한 정책 제안으로 비금속 관로에 대한 효과적인 성과심사 방안을 제시하고, 공공측량 작업규정을 보완할 탐사관련 사항을 체계적으로 기술하였다. Water mains underground facilities are essential components to make up urban infrastructure. In order to manage these water mains underground facilities systematically and scientifically, GIS (Geographic Information System) had been constructed. For the sake of construction of GIS for water mains underground facilities, an exact underground detection and the construction of DB (Data Base) for buried water mains underground facilities should be preceded. In this study, in order to find out the ways to improve exact detection rate of data, the statistical analysis for the causes of detection raw degradation was done, and standardization methods of detection through a case study were suggested, When water mains underground facilities were measured, the detection of non-metallic water pipes was not carried out. The reason was that the results of detection was uncertain and detection was difficult because the assessment of public measurements was vulnerable. Moreover, due to the absence of standardized operating regulations for detection, systematic surveys weren't conducted. In this study, methods to standardize works over the detection of water mains underground facilities were presented so that we can improve the detection rate when we are doing that. As the proposals to improve detection rate, effective performance assessment over non-metallic pipes were presented, and related issues to supplement work regulations of public survey were described systematically.

독일어 수동형 형태의 생성과정과 그 통시적 변화과정

김재명,Kim Jai-Myoung 한국독어학회 2002 독어학 Vol.6 No.-

Im Mittelpunkt der vorliegenden Arbeit steht die Untersuchung der Dynamik im System des deutschen Passivs mit dem $R\"{u}ckblick$ auf das Genuanische. Dabei steht es vorrangig im Zusammenhang mit der Grammatikalisierung der $Verbalf\"{u}gungen$ 'werden + PP' und 'sein + PP'. Und im heutigen deutschen Passivsystem ist zwar die $F\"{u}gung$ 'werden + PP' unmarkiert, aber im Genuanischen $\"{u}berwiegt\;die\;F\"{u}gung$ 'sein + PP'. Das Partizip der Kombination 'werden/sein + PP' wird im Gotischen $ausschlie{\ss}lich$ und im Althochdeutschen noch stellenweise flektiert. Hieraus darf geschlossen werden, dass im $Fr\"{u}hdeutschen$ das Verb finita und das Partizip als relativ $unabh\"{a}ngige$ Glieder einander $gegen\"{u}ber$ stehen und in einer Konstruktion verkettet werden, die einfach den Status der neuhochdeutschen periphrastischen Konstruktion aufweist. Die aspektuelle Bedeutung der $Passivf\"{u}gungen\;l\"{a}sst$ sich da als $bin\"{a}re$ Opposition von kategoriellen Merkmalen 'mutativ' (= Zustandswechel) und 'statal' (= Zustand), verteilt auf die F\"{u}gungen$ 'werden + PP' und 'sein + pp', beschreiben. Diese Merkmale kommt jeweils aus dem inchoativen bzw. durativen Verbalaspekt der Verba 'werden' bzw. 'sein' heraus. Diese Opposition unterscheidet sich von der neuhochdeutschen $Gegen\"{u}berstellung$ vom Vorgangspassiv und Zustandspassiv. Die Eigenbedeutung der Verben 'werden' und 'sein' $l\"{o}st$ sich nun, insbesondere im $Sp\"{a}talthochdeutschen$ in der Semantik der ganzen $F\"{u}gungen$ weitgehend auf, was seinerseits den Verlust der aspektualen Markiertheit der Passiv-Periphrasen mit den Verben finiten verursacht und ihre Entwicklung in Richtung auf die Paradigmatisierung der beiden $F\"{u}gungen\;erm\"{o}glicht$. Die weiter Entwicklung von $Passivf\"{u}gungen$ zeichnet sich durch eine zunehmende Expansion der $F\"{u}gung$ 'werden+PP' in die ursprungliche aspektuale $Sph\"{a}re$ der sein-Konstruktion aus. Dieser Prozess, der zur Auxilialisierung des Verbums finitum $f\"{u}hrt$, setzt schon im $Sp\"{a}talthochdeutschen$ ein und gelangt im Mittelhochdeutschen zur vollen $Auspr\"{a}gung$. Die Konkurrenz der beiden Passivkonstruktionen $f\"{u}hrt$ nun zur $allm\"{a}hlichen$ Verengung des aspektualen Bereichs der $F\"{u}gung$ '.sein+PP', $f\"{u}r$ die nun nur das Resultivum $\"{u}brig$ bleibt.

비도시지역 디지털 지리정보 구축을 위한 기초연구

김재명,최윤수,서창완,조한근,Kim, Jae-Myeong,Choi, Yun-Soo,Seo, Chang-Wan,Cho, Han-Keun 한국공간정보학회 2010 한국공간정보학회지 Vol.18 No.5

본 연구는 비도시지역 디지털 지리정보구축 추진을 위한 중장기 기본계획안에 대한 연구를 수행하여 도출된 제도적 기반 확립을 통해, 비도시지역을 중심으로 한 디지털 지리정보구축을 토대로 전국토가 세계화 개방화 정보화 시대에 대응할 수 있도록 기초자치단체의 정보화를 강화하고자 하는데 그 목적이 있다. 중장기 계획안은 1/1,000 수치지도와 영상지도, 수치표고모형을 동시에 제작함으로써 1단계에서 디지털 지리정보 구축 및 유지관리 조직 구성, 비도시지역 공간정보인프라 구축, 관련법규 정비 및 지역협의회 구성의 기반정보를 구축하고, 2단계에서는 디지털 지리정보 구축확산, 지리정보유통 활성화, 공간데이터웨어하우스 구축, 도시계획종합관리시스템 구축 및 3차원공간정보시스템 구축의 정보화 확산 및 3단계에서는 지리정보 현행화 및 유지관리, 부가가치정보 생산, 행정업무의 고도화 및 대민서비스 극대화를 통한 정보 고도화를 실현함으로써 시군구/시도/중앙정부의 통합지리정보의 기반이 되는 지리정보를 구축 방안을 제시하고자 한다. The construction of digital geographic information of Non-Urban Area have been needed to build a nationwide information infrastructure for the balanced development of nation to reduce a gap between city and Non-Urban Area due to the emphasis on a large scale digital map (1/1,000) implementation for cities. In this research, we researched the basic long-term blueprint for establishing digital geographic information in non-urban area. From the proposed institutional foundation, we want to build this information for Non-Urban Areas and to make a long-term plan to strengthen the national com petitiveness dealing with the globalization, liberalization, and information based on the digital geographic information in non-urban area. This study suggested 3 alternatives to implement digital geographic information of Non-Urban Area as follow. Firstly central government fund whole cost, secondly central government and local government fund a cost half and half, lastly combining first and second alternative. This study can be a basis on building national information infrastructure, provide core information for national projects and revitalize the use of spatial information for Non-Urban Area.

생명보험기업(生命保險企業)의 자산(資産)/부채종합관리(負債綜合管理) 전략(戰略)

김재명,Kim, Jai-Myung 한국산학경영학회 1992 산학경영연구 Vol.5 No.-

다량 Cl성분이 함유된 플라이 애쉬로부터 유리화 및 결정화 현상

김재명,김형순,Kim, Jae-Myung,Kim, Hyung-Sun 한국재료학회 2002 한국재료학회지 Vol.12 No.12

To recycle waste materials, this work was focused on development of glass-ceramic from incinerator fly ash with a large content of Cl and its physical property was evaluated. In the process, water washing as a pre-treatment before melting the fly ash was used to remove large amount of Cl component in the ash and to reduce melting temperature. As a result, glass was obtained at below $100^{\circ}C$ compared to the melting temperature before washing the ash. Also, internal crystallization occurred under single stage heat treatment (at $850-950^{\circ}C$ for 20-340min) without adding other materials into the ash. It was shown that the glass-ceramic was composed of four crystals, diopside, anorthite, akermanite, and unknown phase. Hardness of 8.3GPa was found in the glass-ceramic, which is a high value compared to reported others. Thus, the present process suggests that a good glass-ceramic produced from an incinerator ash could be applicable for structural materials in terms of economic and environmental points.