다양한 중합 방법으로 제작한 간접 수복물용 복합레진의 굴곡 강도

김동연,박진영,강후원,김지환,김웅철,Kim, Dong-Yeon,Park, Jin-Young,Kang, Hoo-Won,Kim, Ji-Hwan,Kim, Woong-Chul 대한치과기공학회 2018 대한치과기공학회지 Vol.40 No.2

Purpose: The aim of this study is to evaluate composite resins of indirect restorations for testing of flexural strength according to various polymerization methods. Methods: Specimen was produced a total of 40 to 10 per each group with a length 25 mm, width 2 mm, thickness 2 mm using a Teflon zig. The polymerization groups were classified into four groups. The first group proceeded with light curing only(LC group). The second group proceeded with light and heat curing(LHC group). The third group proceeded with air press and light curing(ALC group). The fourth group proceeded with air press, light and heat curing(ALHC group). Each prepared group was evaluated by flexural strength test. Statistical analysis was performed by one-way ANOVA. Post-test was performed with Tukey test. Results: The lowest in the ALC group was 119.18 MPa and the highest in the ALHC group was 168.15 MPa. There were statistically significant differences. Conclusion : The composite resin of the indirect restoration is recommended to heat curing along with the air press.

광중합용 DLP 프린터로 제작한 전악 인공치아의 UV-C 초음파 세척에 따른 체적 안정성 평가

김동연,이광영,Kim, Dong-Yeon,Lee, Gwang-Young 대한치과기공학회 2021 대한치과기공학회지 Vol.43 No.3

Purpose: The purpose of this study was to compare the dimension safety evaluation between a general ultrasonic cleaner and an ultrasonic cleaner equipped with UV-C (ultraviolet-C). Methods: An edentulous model was prepared. A denture base and an occlusal rim were fabricated, and scanning was performed. After scanning, a denture base and full arch artificial teeth were designed. The full arch artificial teeth were printed using a three-dimensional printer (n=10). The residual resin was washed with alcohol and then scanned (reference data). The printed specimens were classified and cleaned using a general ultrasonic cleaner (GU group) and an ultrasonic cleaner equipped with UV-C (UC group). After each washing, a rescan was performed (scan data). Reference data and scan data were superimposed using overlapping software. Data were statistically analyzed using the Mann-Whitney test (α=0.05). Results: In the deviation values of full arch artificial teeth, the GU group showed a high deviation of 18.02 ㎛ and the UC group showed a low deviation of 15.02 ㎛. The two groups demonstrated a statistically significant difference (p<0.05). Conclusion: Full arch artificial teeth prepared using photopolymerized resin were deformed according to the temperature of water generated in the ultrasonic cleaner. It is judged that there is no deformation according to the UV-C ultrasonic cleaner.

3D 프린팅용 광 중합 수지의 두께에 따른 수축 비교

김동연,김재홍,Kim, Dong-Yeon,Kim, Jae-Hong 대한치과기공학회 2021 대한치과기공학회지 Vol.43 No.1

Purpose: To perform a comparative study on curing shrinkage according to the thickness of photopolymerization resin. Methods: Stainless steel molds of 2, 4, and 6 mm heights were prepared. The 2, 4, and 6 mm-height molds were classified as the 2H, 4H, and 6H groups, respectively. A photopolymerization resin was injected into the stainless steel mold. Photopolymerization was carried out using a photopolymer machine. During photopolymerization, the wavelength and intensity of 400~405 nm were set to 10, the highest intensity among 1~10. Photopolymerization was performed for 30 min per specimen (each group=10). The inner and outer areas of the specimen were measured. The data were analyzed using one-way ANOVA and Kruskal-Wallis H test (α=0.05). Results: In terms of the inner and outer diameters of the photopolymerization resin specimen, the 2H group contracted the most, whereas the 6H group contracted the least. A statistically significant difference was found between the groups (p<0.05). Conclusion: The amount of light irradiation of the photopolymerization resin must be adjusted according to the thickness.

헥사메틸렌테트라민 농도에 따른 수산화니켈 입자의 특성 분석 및 의사커패시터 응용

김동연,정영민,백성호,손인준,Kim, Dong Yeon,Jeong, Young-Min,Baek, Seong-Ho,Son, Injoon 한국분말재료학회 (*구 분말야금학회) 2019 한국분말재료학회지 (KPMI) Vol.26 No.3

Ni hydroxides ($Ni(OH)_2$) are synthesized on Ni foam by varying the hexamethylenetetramine (HMT) concentration using an electrodeposition process for pseudocapacitor (PC) applications. In addition, the effects of HMT concentration on the $Ni(OH)_2$ structure and the electrochemical properties of the PCs are investigated. HMT is the source of amine-based $OH^-$ in the solution; thus, the growth rate and morphological structure of $Ni(OH)_2$ are influenced by HMT concentration. When $Ni(OH)_2$ is electrodeposited at a constant voltage mode of -0.85 V vs. Ag/AgCl, the cathodic current and the number of nucleations are significantly reduced with increasing concentration of HMT from 0 to 10 mM. Therefore, $Ni(OH)_2$ is sparsely formed on the Ni foam with increasing HMT concentration, showing a layered double-hydroxide structure. However, loosely packed $Ni(OH)_2$ grains that are spread on Ni foam maintain a much greater surface area for reaction and result in the effective utilization of the electrode material due to the steric hindrance effect. It is suggested that the $Ni(OH)_2$ electrodes with HMT concentration of 7.5 mM have the maximum specific capacitance (1023 F/g), which is attributed to the facile electrolyte penetration and fast proton exchange via optimized surface areas.

DLP 프린터로 출력한 임시의치용 전악 인공치아의 후경화에 따른 변형 분석

김동연,이광영,Kim, Dong-Yeon,Lee, Gwang-Young 대한치과기공학회 2021 대한치과기공학회지 Vol.43 No.2

Purpose: This study aimed to analyze deformation according to post-curing of complete arch artificial teeth for temporary dentures printed with a digital light processing (DLP) printer. Methods: An edentulous model was prepared and an occlusal rim was produced. The edentulous model and occlusal rim were scanned using a model scanner. A complete denture was designed using a dental computer-aided design, and the denture base and artificial tooth were separated. Ten complete arch artificial teeth were printed using a 3D printer (DLP). Complete arch artificial teeth was classified into the following three groups: a group no post-curing (NC), a group with 10 minutes post-curing (10M), and a group with 20 minutes post-curing (20M). Specimens were scanned using a model scanner. The scanned data were overlapped with the reference data. Statistical analysis was performed using one-way ANOVA analysis of variance, Kruskal-Wallis test, and Mann-Whitney U test (α=0.05). Results: Regarding the overall deviation of complete arch artificial teeth, the NC group showed the lowest mean deviation of 111.13 ㎛ and the 20M group showed the highest mean deviation of 131.03 ㎛. There were statistically significant differences among the three groups (p<0.05). Conclusion: The complete arch artificial tooth showed deformation due to post-curing. In addition, the largest shrinkage deformation was observed at 10 minutes of post-curing, whereas the least deformation was observed at 20 minutes.

반응표면분석법을 이용한 차가버섯의 초음파 추출공정 최적화

김동연,텅후이,최용희,Kim, Dong-Yeon,Teng, Hui,Choi, Yong-Hee 경북대학교 농업과학기술연구소 2012 慶北大農學誌 Vol.30 No.2

본 연구에서는 항암효과가 뛰어난 차가버섯의 초음파 추출 공정 최적화를 위해 반응표면 분석법으로 모니터링하여 최적 추출 조건을 설정하였다. 중심합성계획법에 따라 추출 시간($X_1$), 에탄올 농도($X_2$), 추출 온도($X_3$)을 요인변수로 하고 추출 수율($Y_1$), 총 페놀함량($Y_2$), 총 플라보노이드함량($Y_3$), 갈색도($Y_4$)를 종속변수로 하여 시행 하였다. 실험 결과 추출 수율은 에탄올 농도와 추출 온도에 영향을 받음을 알 수 있었다. 안장점에서 추출 조건이 추출 시간 20.47min($X_1$), 에탄올 농도 42.85%($X_2$), 추출 온도 $69.57^{\circ}C$($X_3$)일 때, 최대값 18.02%로 나타났다. 총 페놀함량 또한 에탄올 농도와 추출 온도에 영향을 크게 받았다. 최대값은 71.57mg GAE/g으로 나타났으며 이때의 추출 조건은 추출시간 21.60min($X_1$), 에탄올 농도 45.19%($X_2$), 추출 온도 $69.68^{\circ}C$($X_3$)로 나타났다. 총 플라보노이드함량은 추출 온도의 영향을 받은 것으로 나타났고 안장점에서 추출 조건은 추출 시간 22.53min($X_1$), 에탄올 농도 46.37%($X_2$), 추출온도 $69.56^{\circ}C$($X_3$)였고 최대값은 35.98mg RE/g으로 예측되었다. 갈색도는 추출 시간, 에탄올 농도, 추출 온도 이 세가지 조건 모두에 영향을 크게 받았다. 안장점일 때의 추출시간 22.00min($X_1$), 에탄올 농도 46.89%($X_2$), 추출 온도 $69.71^{\circ}C$($X_3$)의 조건에서 최대값이 예측되었다. 앞에서 얻은 결과들을 바탕으로 contour map을 분석한 결과 추출시간 21.50min, 에탄올 농도 44.87%, 추출 온도 $69.64^{\circ}C$의 최적 추출 조건이 예측되었다. This study was conducted to monitor the yields of useful substances extracted from Inonotus obliquus. Optimization of ultrasonic-assisted extraction process was carried out by using response surface methodology under different extraction conditions. A central composite design was applied to investigate the effects of independent variables such as extraction time ($X_1$), ethanol concentration ($X_2$) and extraction temperature ($X_3$) on dependent variables such as soluble solid yield ($Y_1$), total phenol contents ($Y_2$), total flavonoid contents ($Y_3$) and browning color($Y_4$). Soluble solid yield was affected by ethanol concentration and extraction temperature. The maximum soluble solid yield was 18.02% at 20.47 min ($X_1$), 42.85% ($X_2$) and $69.57^{\circ}C$ ($X_3$) in saddle point. Total phenol contents were highly affected by ethanol concentration and extraction temperature. The maximum total phenol contents were 71.57mg GAE/g at 21.60min ($X_1$), 45.19% ($X_2$), $69.68^{\circ}C$ ($X_3$). The electron donating ability was affected by extraction temperature and extraction time. Total flavonoid contents were affected by only extraction temperature. The maximum total flavonoid contents were 35.98 mg RE/g at 22.53min ($X_1$), 46.37% ($X_2$), $69.56^{\circ}C$ ($X_3$) in saddle point. The browning color was highly affected by extraction time, ethanol concentration and extraction temperature. The maximum browning color was at 22.00 min ($X_1$), 46.89% ($X_2$), $69.71^{\circ}C$ ($X_3$) in saddle point. As a result, the optimum extraction conditions were predicted; extraction time of 21.50 min, ethanol concentration of 44.87% and extraction temperature of $69.635^{\circ}C$.

치과 3D 프린팅용 자외선 경화 레진에 광원의 두 가지 파장에 따른 경화 및 항온수조 침적에 따른 변형률의 비교 분석

김동연,이광영,강후원,양천승,Kim, Dong-Yeon,Lee, Gwang-Young,Kang, Hoo-Won,Yang, Cheon-Seung 대한치과기공학회 2020 대한치과기공학회지 Vol.42 No.3

Purpose: This study aimed to analyze the shrinkage and expansion strain of ultraviolet (UV)-cured resin according to the wavelength of the light source and compare the shrinkage and expansion. Methods: We prepared the mold with according to the ISO 4049 specimen. The size of the circle in the mold was prepared with a height of 6.02 mm and a diameter of 4 mm. UV-curable resin for three-dimensional (3D) printing was injected into the circular mold. The control group was irradiated with a wavelength of 400~405 nm using UV-curing equipment (400 group), and the experimental group was irradiated with a wavelength of 460~465 nm (460 group). Both groups were produced ten specimens. The produced specimen was first measured with a digital micrometer. After the first measurement, the specimen was immersed in a constant temperature water bath for 15 days, after which the second measurement was performed, and the third measurement was taken after 30 days. The measured values were analyzed using the independent sample t-test (α=0.05). Results: In the non-immersion water tank, the contraction was 0.9% in the 400 group and 1.3% in the 460 group. In the constant temperature bath, the expansion was high at -0.4% in the 400 group for 15 days, and the smallest expansion was -0.03% for the 400 group for 30 days. There were significant differences between the two groups (p<0.05). Conclusion: The 400 group had a lower UV resin specimen strain than the 460 group. Therefore, it is recommended to use the wavelength required by the UV-curing resin.

타문화권 환자 진료(방글라데시-1편)

김동연,Kim, Dong-Yeon 연세대학교 의과대학 2005 의학교육논단 Vol.7 No.2

영암-강진 일원 변성사질암의 SHRIMP U-Pb 저어콘 연대

김동연,최성자,이기욱,Kim, Dong-Yeon,Choi, Sung-Ja,Yi, Keewook 대한자원환경지질학회 2015 자원환경지질 Vol.48 No.4

영암-강진 일대에는 변성사질암으로 구성된 시대미상 용암산층, 설옥리층, 서기산층으로 명명된 지층들이 발달하고 있으며, 이들은 서로 상이한 지층으로 기재되어 있다. 그리고, 이들 지층들은 선캠브리아의 갈두층, 상부고생대의 송지층군으로 재정립되었다. 본 연구에서는 변성사질암의 퇴적시기를 규명하고, 서로 달리 명명된 지층간의 층서 관계를 정립하기 위해 SHRIMP 저어콘 U-Pb 연대 측정을 실시하였다. 연대측정결과, 약 1.87Ga의 연대가 가장 우세하게 나타나고, 가장 젊은 연령은 약 246-265 Ma로 변성사질암의 퇴적시기가 후기 페름기 내지 전기 트라이아스기이다. 그러므로, 영암-강진일대 용암산층, 설옥리층, 서기산층의 변성사질암은 삼척탄전의 고한층-동고층 혹은 녹암층, 호남탄전의 천운산층에 대비되는 상부고생대 평안층군의 최상부층이다. 본 연구지역의 변성사질암은 모두 고생대 평안층군에 해당되므로, 기존에 정의되었던 선캠브리아 갈두층 혹은 페름기 송종층 등은 더 이상 의미가 없다. 그러므로 '갈두층'과 '송종층' 층명 대신에 기존 5만 도폭의 층명을 그대로 사용하거나, 상부고생대 '이질암' 혹은 '사질암'으로 사용할 것을 제안한다. The metapsammite distributed in the Yeongam-Gangjin area had been classified into age-unknown Yongamsan Formation, Seologri Formation and age-unknown Seogisan Formation, and these formations are reported as each other different formations. These formations have been renamed Precambrian Galdu or Permian Songjong Formations. In this study, we present detrital zircon SHRIMP U-Pb age data from the metapsammite to examine deposition time and stratigraphy. The analyzed U-Pb zircon ages dominantly reveal Paleoproterozoic ages of ca. 1.87Ga and the youngest detrital grains are constrained by the age of 246-265 Ma. The youngest age indicates late Permian or early Triassic for the deposition time. Therefore, the metapsammite in the Yeongam-Gangjin area is considered to be the upper formation of the late Paleozoic Pyeongan Group which is correlated with the Gohan-Donggo Formations or Nokam Formation of the Samcheock coal field and the Cheonunsan Formation of the Hwasun coal field. The metapsammite of the study area is the late Paleozoic Pyeongan Group by the zircon age rather than Precambrian Galdu and Permian Songjeong Formations are no longer meaningful. Therefore, we propose the upper Paleozoic 'metapelite' and 'metaspammite', or original formation name defined by 1:50,000 geological maps, instead of Galdu and Songjeong Formations.

치과 3D 프린팅용 광중합 시간에 따른 중합도 비교

김동연,이광영,Kim, Dong-Yeon,Lee, Gwang-Young 대한치과기공학회 2022 대한치과기공학회지 Vol.44 No.3

Purpose: The purpose of this study is to analyze the depth according to curing using photocurable resin for dental three-dimensional printing. Methods: A stainless mold with a height of 4 mm was prepared. Ultraviolet (UV) polymerization resin was injected into the mold. Photocuring was then performed for 5 minutes using a photopolymerizer, and the height was measured using a digital measuring instrument (first group). Second, light polymerization was also performed outside the mold for 5 minutes, and the height was measured using a digital measuring instrument. Third, light polymerization was further performed for 5 minutes, and the height was measured using a digital measuring instrument. Statistical analysis was performed with the Kruskal-Wallis test, which is a nonparametric test (α=0.05). Results: The third group had the largest measurement length, whereas the first group had the smallest. However, the difference between groups was not statistically significant (p>0.05). The color of the first group was different from that of the second and third groups. Conclusion: All of the 4-mm-thick photocured specimens had a curing reaction, but the part that was not directly irradiated with UV did not show its original color.