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Catalytic Asymmetric Allylic Alkylation with A Novel P-S Bidentate Ligand
강자효,유성훈,김주인,조형근,Gang, Ja Hyo,Yu, Seong Hun,Kim, Ju In,Jo, Hyeong Geun Korean Chemical Society 1995 Bulletin of the Korean Chemical Society Vol.16 No.5
Both enantiomers of (S)-(-)-2-(diphenylphosphino)-2'-mercapto-1,1'-binaphthyl and their derivatives were obtained by synthesis from racemic 2,2'-dihydroxy-1,1'-binaphthyl and subsequent resolution. The utilities of these ligands were investigated briefly. And among these, S-methyl derivative 15 has proved to be an effective ligand for Pd-catalyzed allylic alkylation.