http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
4-(2-Thiazolylazo)-resorcinol 을 킬레이트제로 사용한 Ni(Ⅱ)의 鹽析抽出定量
裵俊雄,李興洛,張惠榮,徐戊龍 경북대학교 1987 論文集 Vol.43 No.-
As a part of analytical application of 4-(2-thiazolylazo)-resorcinol(TAR), the extraction method with salting-out technique was applied to the determination of nickel(Ⅱ) ion in aqueous solution. After nickel(Ⅱ) was extracted from the buffered aqueous solution into accetonitrile layer as a Ni(Ⅱ)-TAR chelate by salting-out technique, the visible absorption spectrum was recorded. In this experiment ammonium sulfate was used as a salting-out reagent. The effects of amount of ammonium sulfate and extracting reagent TAR on the extractability, the relationship between pH of the aqueous phase and the extractability of Ni(Ⅱ)-TAR chelate, and the calibration curve for the determination of Ni(Ⅱ) by spectrophotometry has been evaluated. And the effects of diverse ion on the determination of Ni(Ⅱ) by this method have been investigated.
黃正儀,裵俊雄,鄭倧在,鄭在元,張景喜 慶北大學校 物理化學硏究所 1986 硏究論文集 Vol.7 No.-
치환나프톨류(4-Cl-1-Naphthol, 6-Br-2-Naphthol, 8-NH_2-2-Naphthol)의 해리상수를 온도(25∼40℃)와 압력(1∼2000 bar)을 변화시키면서 분광학적 방법으로 측정했다. 이들의 해리상수는 치환기가 들어가므로서 모두 감소했다. 이것은 치환기의 I-효과로서 설명이 가능했으며 또 온도와 압력이 증가하면 해리상수도 증가하였다. 이들 해리상수로부터 반응의 열역학적 성질을 계산하여 반응의 성질을 알아보았다. The dissociation constants of 4-Cl-1-naphthol, 6-Br-2-naphthol, 8-NH_2-2-naphthol in aqueous solution were measured by spectroscopic method in the temperature range from 25 to 40℃ and pressure up to 2000bar. The dissociation constants were decreased as the substituents were inserted in naphthol from 4.4×10 exp(-10) to 5.82×10 exp(-11) as chloride compound and 2.5×10 exp(-10) to 3.44×10 exp(-11) or 4.21×10 exp(-11) as bromine or amino compounds, respectively. This decrease can be explained with the I- or R-effects of substituents. From the dissociation constants various thermodynamic properties were claculated and discussed the characteristics of the dissociation reaction.
아세토니트릴 용매 중에서 Copper-1,5,9,13-Tetrathiacyclohexadecane 착물의 전기화학적 거동과 그 분석적 응용
徐戊龍,李富永,崔明子,裵俊雄,朴泰明 慶尙大學校 기초과학연구소 1992 基礎科學硏究所報 Vol.8 No.-
비수용매인 아세토니트릴 중에서 Cu(Ⅱ)dhk 1,5,9,13-tetrathiacyclohexadecane[16-ane-S_4]의 착물에 대한 전기화학적 거동으로서 직류폴라로그램과 미분펄스폴라로그램으로부터 환원전류의 유형과 가역성을 조사하고, 이들 화합물의 분석적 응용으로서 수용액에 있는 Cu(Ⅱ) 이온을 염석추출법으로 정량하였다. 또한 아세토니트릴 용매 중에서 착물의 안정도상수를 구하고, 분석적 응용으로 수용액 중의 Cu(Ⅱ)를 염석추출법으로 정량하기 위하여 추출 조건 곧 킬레이트와 염석제의 효과, pH 범위를 구하고 또한 Cu(Ⅱ)이온을 정량하는데 있어서의 검량성과 공존이온 효과를 조사하였다. 실험결과로부터 환원 과정은 비가역적이었으며 환원전류는 확산지배적임을 알았다. 또한 아세토닐트릴 용매 중에서 착물의 log K_f 값은 3.51이었으며 Cu(Ⅱ) 이온을 정량하는데 있어서 공존하는 이온의 영향을 별로 받지 않아 선택성이 좋았으며 본 실험방법에 의한 정량한계는 60ppb 이었다. The electrochemical behaviors and analytical application of copper-1,5,9,13-tetrathiacyc-lohexadecane[16-ane-S_4] complex in acetonitrile(AN) solution have been investigated by the use of Dc polarogaphy and differential pulse polarography. Thus the formation constant of copper complex was 10^3.51. Copper (Ⅱ) ion was found to form complex of 1-to-1 composition with [16-ane-S_4]. In addition, reduction step was irreversible and the reduction current was diffusin controlled. And the effect of concentration of the salting-out reagent and chelating agent and pH of aqueous phase on the determination of copper(Ⅱ) was investigated and diverse ion effect was discussed. By salting-out extraction technique, we can be determined until the concentration of cooper (Ⅱ) of 60 ppb.
Email Spam Filtering Based on the MNMF Algorithm
Zun-xiong Liu,Shan-shan Tian,Zhi-qiang Huang,Jiang-wei Liu 보안공학연구지원센터 2016 International Journal of Security and Its Applicat Vol.10 No.1
Content-based email spam filtering is a challenging problem in which emails are often represented as high-dimensional data. This paper proposes an approach to email spam filtering based on max-margin semi-NMF (MNMF). MNMF combines the ideas of semi-NMF and max-margin and performs dimension reduction and classification simultaneously. In MNMF, we employ the same approach as Semi-NMF to update the coefficient matrix (while the other parameters are fixed) instead of quadratic programming. Simulation experiments were performed on two public Chinese email corpuses. The results show that MNMF is much faster and performs much better than support vector machine (SVM) classifiers that use features extracted by principal component analysis or linear discriminant analysis, and the MNMF method also outperforms SVM classification schemes in combination with feature extractions based on NMF and Semi-NMF
Zun Liang Chuan,Sayang Mohd Deni,Soo-Fen Fam,Noriszura Ismail 한국기상학회 2020 Asia-Pacific Journal of Atmospheric Sciences Vol.56 No.1
The reliability and accuracy of a risk assessment of extreme hydro-meteorological events are highly dependent on the quality of the historical rainfall time series data. However, missing data in a time series such as this could result in lower quality data. Therefore, this paper proposes a multiple-imputation algorithm for treating missing data without requiring information from adjoining monitoring stations. The proposed imputation algorithms are based on the M-component probabilistic principal component analysis model and an expectation maximisation algorithm (MPPCA-EM). In order to evaluate the effectiveness of the MPPCA-EM imputation algorithm, six distinct historical daily rainfall time series data were recorded from six monitoring stations. These stations were located at the coastal and inland regions of the East-Coast Economic Region (ECER) Malaysia. The results of analysis show that, when it comes to treating missing historical daily rainfall time series data recorded from coastal monitoring stations, the 2-component probabilistic principal component analysis model and expectation-maximisation algorithm (2PPCA-EM) were found to be superior to the single- and multiple-imputation algorithms proposed in previous studies. On the contrary, the single-imputation algorithms as proposed in previous studies were superior to the MPPCA-EM imputation algorithms when treating missing historical daily rainfall time series data recorded from inland monitoring stations.
An ABS-FRE algorithm for solving systems of fuzzy relation equations
Zun-Quan Xia,Fang-Fang Guo 한국전산응용수학회 2004 Journal of applied mathematics & informatics Vol.15 No.-
The general scheme of an algorithm, called an ABS-FRE al-gorithm, for solving systems of fuzzy relation equations (systems of FRE)via the ABS algorithms is presented. As special cases, two particular algo-rithms for obtaining the greatest and minimal solutions of systems of FREare described. Several new operations used in this scheme are given, forinstance, operators∨and ∧, called quasi-inverses of operators∨and ∧,respectively, etc.