펄프 표백시 산소와 이산화염소의 영향 : 수산기 라디칼의 생성과 금속이온의 영향 The Effect of Hydroxyl Radical and Metal Ion

윤병호,조병묵,이명구 江原大學校 森林科學硏究所 1997 Journal of Forest Science Vol.13 No.-

본 논문에서는 케미루민센스와 HPLC를 사용하여 산소 표백시 수산기 라디칼의 생성과 리그닌 및 탄수화물의 분해와의 상호관련성을 밝히기 위하여 간단한 리그닌 모델화합물인 아포사이놀과 탄수화물 모델화합물인 α-D-glucopyranose와 methyl-β-D-glucopyronoside를 사용하여 연구하였다. 또한 수산기 라디칼의 생성과 금속이온과의 연관성을 검토하고 탈리그닌을 촉진함과 동시에 탄수화물의 분해를 억제하는 최적의 금속이온 농도를 조사하였다. 그 결과 금속이온의 존재가 수산기 라디칼의 형성과 탈리그닌화에 효과적인 영향을 주며, Cu^2+ > Mn^2+ > Mg^2+ > Fe^2+ 순서로 수산기 라디칼이 생성됨을 알 수 있었다. 이러한 금속이온들은 탄수화물도 분해시키는 문제가 있음을 증명하였다. 그러나 100㎛ Mg^2+를 첨가하면 수산기 라디칼의 생성이 억제됨을 알 수 있었다. 또한 Cu^2+은 탄수화물의 안정성에 나쁜 영향을 미쳤으나, 3㎛ Mn^2+을 첨가하면 놀랍게도 methyl-β-D-glucopyranoside에 대해 약간의 보호효과를 나타냄을 알 수 있었다. 이산화염소 라디칼 표백 용액 중에서는 이와 반대로 금속과 관계없이 상당한 양의 수산기 라디칼을 생성하지 않으나 이산화염소 자체의 라디칼이 리그닌만을 선택적으로 분해하였다. Hydroxyl radicals were detected and their qualitative yields were estimated by using chemiluminescence method and γ-irradiation technique in oxygen or chlorine dioxide radicals bleaching conditions. The correlation of hydroxyl radical formation and lignin model(Apocynol) or carbohydrate model(α-D-glucopyranose and methyl-β-D-g1ucopyranoside) degradation was studied in the presence of metal ion or without metal ion. The results showed that the presence of metal ions efficiently affected the formation of hydroxyl radicals in oxygen bleaching process, in the order of Cu^2+ > Mn^2+ > Mg^2+ > Fe^2+, and these metal gave also rise to the degradation of carbohydrate. But it was found that the addition of 100㎛ Mg^2+ gave an efficient protection against carbohydrate degradation and suppressed the hydroxyl radical formation under oxygen bleaching conditions. And the presence of Cu^2+ had a detrimental effect on the stability of carbohydrates, whereas the addition of 3㎛ Mn^2+ surprisingly had a small protective effect on methyl--β-D-g1ucopyranoside. In the CIO_2 radical bleaching conditions the hydroxyl radical expected to generate from water or substrates was not detected in the presence of metals.

DEA 첨가 금속 Alkoxide를 사용한 PZT 박막의 제조 및 특성 평가

윤화중,임무열,구경완,최명진 충남대학교 기초과학연구소 1994 忠南科學硏究誌 Vol.21 No.1

Lead acetate trihydrate, zirconium iso-propoxide and titanium iso-propoxide used for the starting material to fabricate PZT coating solution. Iso-metoxy-ethanol used for the solvent of the starting material. Adding diethanolamine formed the chelate compound and prevented the hydrosis of coating solution. The coating sol solution is changed to M-O-M structure polymer gel by adding H_2O, and the polymer gel has the more strong bonding force. The cross-sectional SEM micrograph of PZT thin film showed that the metal of lower electrode was silicated with SiO_2 of buffer layer. The SIMS depth profile for PZT thin film indicated that the metal of lower electrode and silicon was diffused up to the upper part of PZT thin film. For the X-RD data of PZT thin film, the thin film on Pt substrate and with Ti buffer layer had strong perovskite phase. The PZT thin films measured by Sawyer-Tower circuit showed feroelectric characteristic representating D-E hysterisis curve. The remanent polarization and coercive field of the film was 1.92 C/㎠ and 33.3kV/㎝. I-V characteristic curve showed that the leakage currents and break down voltages of PZT thin films on Ni/SiO_2/Si, Ti/SiO_2/Si, Pt/SiO_2/Si substrate was 1.43 × 10 exp (-10) A/㎠, 1.19×10 exp (-10) A/㎠, 2.28×10 exp (-10) A/㎠ and 0.334 MV/㎝, 0.33 MV/㎝, 0.11 MV/㎝ each. C-V curve indicated dielectric constant 57 The resistance antiresonance frequency of PZT film was 612 ㎒, and the resistance was 14 ㏀ at that frequency.

韓國 傳統住宅의 溫熱環境에 對한 硏究

尹在雄,金命福 효성여자대학교 새마을연구소 1988 새마을硏究論文集 Vol.8 No.-

스테로이드 치료 후 회복기의 규칙적인 운동이 쥐의 스테로이드 유발성 위축 뒷다리근에 미치는 영향

최명애,변영순,황애란,김희승,홍해숙,최스미,서화숙,이경숙,박미정,신기수,안경주,이윤경,임지회 대한기초간호자연과학회 2002 Journal of korean biological nursing science Vol.4 No.1

This study was conducted to determine whether low intensity regular exercise following steroid treatment could attenuate steroid-induced muscle atrophy. Thirty-eight Sprague-Dawley rats weighing 165~175g were divided into six groups;control group(C), dexamethasone administration group(D), sedentary after normal saline administration group(C+Se), exercise after normal saline administration group(C+Ex), sedentary group after dexamethasone administration(D+Se), exercise group after dexamethasone administration(D+Ex). Either dexamethasone(5mg/kg) or normal saline was injected for 7days accordingly. Exercise was started at 10m/min on the 10?grade treadmill and gradually increased up to 15m/min by the 7th day for 60minutes/day(20min×3). The data were analyzed by Kruskal-Wallis test and Mann-Whitney U test using the SPSS WIN 9.0 program. Body weight, muscle weight and myofibrillar protein content of both plantaris and gastrocnemius, Type I, II muscle fiber cross-sectional area of plantaris, and Type II muscle fiber cross-sectional area of gastrocnemis in D group were significantly lower than those of C group(p<.05) respectively. Hindlimb muscle weight, myofibrillar protein content of both plantaris and gastrocnemius, Type I muscle fiber cross-sectional area of soleus and Type I, II muscle fiber cross-sectional area of plantaris in D+Ex group tended to increase compared to those of D+Se group. Myofibrillar protein content of both plantaris and gastrocnemius, Type I muscle fiber cross-sectional area of plantaris in D+Ex group tended to increase compared to those of C+Se group. Based on these results, it is suggested that regular low-intensity exercise during recovery period after steroid treatment might facilitate the recovery from steroid-induced muscle atrophy.

항생제 대체제(앤타시드-100)의 급여가 젖소 송아지 육성에 미친 영향

명윤아,박덕섭,이인덕,남명수,이형석,김용국 충남대학교 농업과학연구소 2007 농업과학연구 Vol.34 No.2

This study was carried out to develope an antibiotic substitute with some feed additive ingredients; activated charcoal, microbial products( Saccharomyces cerevisiae), sodium bentonite and pyroligneous. Sixty Holstein male calves(control 30 and tested 30 calves) were assigned to one of two diets, control(containing commercial antibiotic) and treatment diet (containing antibiotic substitute) with three replicates(10 calves each). The experiment were carried out for 30 days. The daily weight gains were similar between control(1.01kg/d) and treatment groups(1.01kg/d), however feed requirement were lower for treatment calves (2.80kg) than control calves (3.24kg) (P<0.05). Also calves were more health for treatment calves than control calves for diarrhea and respiratory diseases occurrences. The ammonia concentration of feces were lower for treatment calves(2.67 ppm) than for control calves(6.33 ppm) (P<0.05). No statistical difference were found in blood substances between control and treatment calves(P>0.05). In conclusion, the calve performances were improved by substitute without commercial antibiotic additive. 본 연구는 항생제를 대체할 목적으로 동물체의 활성을 가져오는 원료로 알려져 있는 활성탄과 목초액, sodium bentonite, 홍삼박, 생균제를 선별하여 이들 원료로 구성된 항생물질 대체제를 개발하여 홀스타인 수송아지에 급여하였을 때 생산성에 미치는 효과를 규명하고자 수행하였다. 송아지의 일당증체량은 대조구(1.011kg), 처리구(l.0lkg)간에 유의적인 차이가 없었고(P>0.05), 사료 요구율은 대조구 3.24에 비하여 처리구 2.80로 처리구에서 유의적인 개선효과를 나타냈다(P<0.05). 설사 발생률은 동일하였으나 분 상태는 처리구가 양호하였고, 호흡기 질병은 처리구에서는 발생하지 않았다. 분 중 NH₃ 농도는 대조구(6.33 ppm)에 비하여 처리구(2.67 ppm)에서 뚜렷한 개선 효과를 보였고(P<0.05), 혈액 수치는 대조구와 처리구가 유사하였다. 항생물질 대체제를 급여한 처리구가 시판 항생제 첨가사료급여군(대조구)에 비하여 증체에서는 다소 낮은 성적을 나타냈지만 질병 발생 없이 유사한 성적을 낸 것은 대체물질이 가축 소화기관의 활성화, 사료의 소화율 증진 등에 영향을 나타내어 동물의 활력이 증진되므로 항생제의 사용 없이도 양질의 축산물을 생산할 수 있는 결과를 얻었다.

二成分系 非鐵金屬酸化物의 電氣抵抗에 關한 硏究 (Ⅰ)

洪允命,鄭國三 연세대학교 대학원 1976 延世論叢 Vol.13 No.2

This study was performed to investigate the electrical conductivity of some binary non-iron metallic oxides system as a function of the temperature, taking into consideration those other factors that influence the properly. In this study, measurements of electrical resistance in the composition system Al2O3-TiO2, CaO-TiO2, CaO-SiO2 and BaO-SiO22were made using, generally, dry pressed disc about 2 cm. in diameter and 5 mm thick and fired from 800℃ to 1450℃. In the CaO-SiO2 series minimum resistance was shown by the samples containing in the range of 20∼50% CaO and 80∼50% SiO2 above the 1100℃, but the resistance of TiO2 content series was decreased through all composition percentages by its reducing semiconductor. The same effect was observed in the BaO-SiO2 series and the curve of all series shows that its closely approached the Rasch and Hinrichsen relationship, having only a slightly curvature.

가족성 팔목터널 증후군 1가족례

이명종,김광국,이상암,마효일,윤준오 울산대학교 의과대학 1993 울산의대학술지 Vol.2 No.1

This is a report of familial carpal tunnel syndrome(CTS) occuring in four members of two generations of a Korean family. One of those with CTS had surgical release and its pathologic finding was nonspecific fibrotic change. The age of those affected by CTS ranged form 35 to 76 years of age. Family pedigree suggests an autosomal dominant gene. This is belived to be the first case report of familial carpal tunnel syndrome in Korea.

Paraquat 독성에 미치는 Dicumarol과 Allopurinol의 병합 투여 효과

송명화,정미숙,오순식,박재윤,차종희 조선대학교 1995 The Medical Journal of Chosun University Vol.20 No.1

Despite intensive investigation into paraquat toxicity, neither the final cytotoxic mechanism nor a clinically useful antidote has been discovered. The mechanism of paraquat cytotoxicity is also debatable, but it is generally accepted that a redox reaction occurs between reduced paraquat and molecular oxygen. The intracellular reduction of paraquat occurs by various enzymes, such as DT-diaphorase, xanthine oxidase and glutathione reductase. In present study, we investigated that the effects of allopurinol, a xanthine oxidase inhibitor, and dicumarol, a DT-diaphorase inhibitor, in paraquat-intoxicated rats. The survivals of paraquat-intoxicated rats were increased by allopurinol treatment compared to paraquat-treated control rats , but not effected by dicumarol treatment. The activity of xanthine oxidase in the liver of allopurinol-treated rats was decreased and DT-diaphorase activity in liver of dicumarol treated rats was also decreased compared to normal control rats. The contents of glutathione in liver of paraquat treated rats was decreased but in paraquat+allopurinol treated rats, the decrements of glutathione contents was reduced but in paraquat+dicumarol treated rats, liver glutathione level was not changed compared to paraquat-treated rats. These results suggest that paraquat toxicity maybe reduced by administration of allopurinol but dicumarol did not have such effects .

운동부하검사로 유발된 여성의 협심통증에 대한 예비연구

최명애,안경애,추진아,최윤식 대한기초간호자연과학회 2002 Journal of korean biological nursing science Vol.4 No.2

Purpose : Women have been often underdiagnosed and undertreated when they have as high mortality as men of ischemic heart disease, such as angina. One of the reason of women's under treatment is associated with either vague, non-traditional symptoms or longer delay in seeking professional help when they experience ischemic heart disease. This study was conducted to investigate the characteristics of women's anginal pain induced by the treadmill test and to explore the potential relationship(s) between anginal pain and other psycho-physiologic factors. Method : Of 22 female patients referred to treadmill test, 7 with positive finding participated in this study. Anginal pain in the past was analyzed by Rose questionnaire, whereas anginal pain induced by the treadmill test was identified by McGill pain scale, visual analogue scale and present pain index. Results : Women expressed more heaviness than sharp pain, and complained splitting more often than subjects in previous study that included both men and women. Pain intensity by VAS 3.64±3.94, Pain rating index was 5.14±7.29, present pain index was 1.57±1.81, duration of pain was 5.14±4.8 min. Exercise intensity was 6.0±4.63 METs, exercise duration was 364.29±141.39 sec, ST change was -2.0mm and rate of perceived exertion was 16.29±2.06. The relationships between pain intensity and pain duration, ST segment changes were significant. Correlation among pain measures was significant. Conclusion : Generalization of these pilot findings may be inappropriate, and therefore, further larger study is needed.

자전 고온 합성 반응법을 이용한 B₄C의 제조에 관한 연구

金錫胤,金明秀,金岩洙 弘益大學校 科學技術硏究所 1998 科學技術硏究論文集 Vol.9 No.2