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Mina Neghabi,Abbas Behjat,Bi Bi Fatemeh Mirjalili,Leila Zamani 한국물리학회 2013 Current Applied Physics Vol.13 No.1
One of the porphyrin derivatives, meso-tetraphenylporphyrin (TPP), has been synthesized and examined as an emitter material (EM) for efficient fluorescent red organic light-emitting diodes (OLEDs). By inserting a tungsten oxide (WO3) layer into the interface of anode (ITO) and hole transport layer N,N0-Di-[(1-napthyl)-N,N0-diphenyl]-(1,10-biphenyl)-4,40-diamine (NPB) and by using fullerene (C60) in contact with a LiF/Al cathode, the performance of devices was markedly improved. The current densityevoltageeluminance (JeVeL) characterizations of the samples show that red OLEDs with both WO3 and C60 as buffer layers have a lower driving voltage and higher luminance compared with the devices without buffer layers. The red OLED with the configuration ITO/WO3 (3 nm)/NPB (50 nm)/TPP (60 nm)/BPhen (30 nm)/C60 (5 nm)/LiF (0.8 nm)/Al (100 nm) achieved the high luminance of 6359 cd/m2 at the low driving voltage of 8 V. At a current density of 20 mA/cm2, a pure red emission with CIE coordinates of (0.65; 0.35) is observed for this device. Moreover, a power efficiency of 2.07 lm/W and a current efficiency of 5.17 cd/A at 20 mA/cm2 were obtained for the fabricated devices. The study of the energy level diagram of the devices revealed that the improvement in performance of the devices with buffer layers could be attributed to lowering of carrier-injecting barrier and more balanced charge injection and transport properties.
Mina Neghabi,Abbas Behjat 한국물리학회 2012 Current Applied Physics Vol.12 No.2
Organic light emitting diodes (OLEDs) of ITO/PEDOT:PSS/TPD:Alq3:C60/Al with different C60 concentrations (0e6.0 wt.%) have been fabricated. The physical parameters including electrical and optical properties of the samples have been measured by Luminanceecurrentevoltage (LeIeV) characteristics and optical absorbance. The currentevoltage characteristics indicate that field-emission tunneling injection dominates in the diodes at high applied voltages. It is found that with increasing the concentration of C60,the injection barrier for holes slightly reduces and the hole’s mobility increases over two orders of magnitude. Also, electroluminescence enhances with the presence of C60 in the blend; optimum current efficiency occurs at 3 wt% C60. The method provides a simple way of increasing the efficiency of OLEDs.