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M.J. Goh,M. Kyotani,K. Akagi 한국물리학회 2006 Current Applied Physics Vol.6 No.5
We synthesized novel mesogenic axially chiral binaphthyl derivative by substituting phenyl-cyclohexyl (PCH) moieties into 2, 20,6 and 60 positions of binaphthyl rings. The binaphthyl derivative showed the highest twisting power ofbM = 381.87 l m. 1, when0.05 mol% of the chiral dopant was added into a mixture of PCH302 and PCH304. The helical pitches of N*-LC varied from270 to 350 nm with changes of the concentration of the chiral dopant from 1.5 to 1.0 mol%. These helical pitches are smallerone-tenth than those (25l m) observed in the N*-LC containing di-substituted binaphthyl derivatives. This indicates that the pres-ent N*-LC including tetra-substituted binaphthyl derivatives is feasible for much higher twisted asymmetric reaction eld. It is ofinterest that the polyacetylene lm synthesized in the N*-LC with helical pitch of 270 nm showed highly screwed brils, but notthe bundle of bril. This is due to the fact that the helical pitch of 270 nm is smaller than the diameter of the bundle of bril. Thissituation might depress the formation of the bundle of bril. The brillar morphology without the bundle of brils should make it much easier to evaluate electromagnetic properties of the screwed fibril.
T. Matsushita,M.J. Goh,M. Kyotani,K. Akagi 한국물리학회 2006 Current Applied Physics Vol.6 No.5
Polyacetylene lms with vertically aligned bril morphology were synthesized in homeotropic nematic LC (N-LC) solvent, byusing a magnetic eld of 5 T as an external perturbation. Next, helical polyacetylene lms with vertically aligned and screwed brilmorphology were synthesized in macroscopically aligned chiral nematic LC (N.-LC) under magnetic eld. Scanning electron micro-graph (SEM) indicated that the lengths of brils from the substrate were 520l m, depending on polymerization time, acetylenepressure and catalyst concentration.
Yang, Seung Jae,Im, Ji Hyuk,Nishihara, Hirotomo,Jung, Haesol,Lee, Kunsil,Kyotani, Takashi,Park, Chong Rae American Chemical Society 2012 JOURNAL OF PHYSICAL CHEMISTRY C - Vol.116 No.19
<P>The hydrogen adsorption isotherms of six metal–organic frameworks (MOFs) and three microporous carbons, measured at 77 K (up to 1 bar) and 298 K (up to 100 bar), have been systematically examined for correlations with their pore characteristics. From the obtained correlations, H<SUB>2</SUB> adsorption was found to occur preferentially in ultrafine pores at both 77 K (≤1 bar) and 298 K (100 bar), irrespective of the adsorbent. This represents the first experimental evidence that ultrafine pores in MOFs improve the efficiency of H<SUB>2</SUB> adsorption at 298 K and at high pressures, indicating that that the low H<SUB>2</SUB> storage capacities of reported ultrahigh microporous MOFs at 298 K result from the prominence of micropores with diameters 1–2 nm, which are inadequate at 298 K and high pressures. Furthermore, these correlations suggest strong links between the H<SUB>2</SUB> storage capacities at 77 and 298 K, which offer an easy method for predicting H<SUB>2</SUB> adsorption capacities under unapproachable conditions. This study provides guidance in the development of new MOFs or other adsorbents with an optimized H<SUB>2</SUB> storage capacity at near-ambient temperatures and a swift screening method of newly synthesized porous adsorbents.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jpccck/2012/jpccck.2012.116.issue-19/jp302304w/production/images/medium/jp-2012-02304w_0002.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/jp302304w'>ACS Electronic Supporting Info</A></P>