가변 부피 view cell을 이용한 메탄올/CO₂및 아세토나이트릴/CO₂기-액 상평형

임교빈,유종훈 수원대학교 산업기술연구소 2004 산업기술연구소논문집 Vol.19 No.-

The phase behavior of Methanol/CO₂ systems was investigated previously by a number of researchers. However, the entire composition range at moderate temperatures was not mapped in a single study Furthermore, extensive acetonitrile/CO₂ vapor-liquid phase information has not been reported. The goals of this research were twofold: (1) to demonstrate the accuracy and precision of visual observation for vapor-liquid phase boundary determination using a high-pressure, variable-volume view cell with the methanol/CO₂ system relative to the data available, and (2) to examine phase behaviors of methanol/CO₂ and acetonitrile/CO₂, commonly used binary fluids for supercritical fluid chromatography and extraction, from 0~1.00 mole fraction CO₂ and over a 25~100℃ temperature range. The results for methanol/CO₂ were found to be very comparable to the literature values.

직장 네티즌들의 인터넷 여행사 이용실태에 관한 연구

차석빈,김종문,우경식 한국문화관광학회 2000 문화관광연구 Vol.2 No.1

The development of internet environment in the society caused the travel industry to proceed into the internet business competitively. However, a little research has been conducted on the netizens' behavior in the internet travel businesses. This study attempted to address the behavioral aspects related to the internet use for salaried men visiting internet travel agencies(ITA). Research findings are as follows: 1)Netizens seemed not to invest much time in searching travel-related sites. Major purposes of their visiting ITA were acquiring travel information, hotel/condominium reservation, package product reservation, etc. 2) They thought the provision of travel information, protection of private information, and internet connecting speed important in purchasing travel product through internet. 3) They revealed high intention to visit ITA, but low to purchase goods. However, netizens who had experience of purchasing goods show higher intention to visit or purchase than those who did not visit ITA even one time.

한국인에서 DXS7132 유전좌와 GATA31D10 유전좌의 다형성에 관한 연구

안종성,장영길,이숭덕,신창호,이윤성,이정빈 大韓法醫學會 2000 대한법의학회지 Vol.24 No.1

The validation study for two STR loci on X-chromosome, DXS7132 and GATA31D10, was done including allelic distribution and frequency of each allele to use these results for individual identification and paternity testing. For 496 unrelated Koreans, above two STR loci were amplified simultaneously using duplex PCR amplification method. The amplified products were analyzed by polyarylamide gel electrophoresis followed by silver staining. In male DXS7132 locus revealed 7 different alleles ranging from 276bp to 300bp. The largest allele was consisted of 14 repetition of [TCTA] unit and took 0.3417. The allele 15 followed next as 0.3165 and allele 13 as 0.1726. In female general distribution was same except one allele, allele 18 was found additionally. The heterozygosity was 0.7706 and 23 different genotypes were found. Polymorphism information content(PIC) was 0.727. Two cases of mutation were noted in DXS7132 locus In both male and femal 7 different alleles were noted in GATA31D10 locus and the alleles ranged from 195bp to 231bp. The allele 15(199bp) took the majority of all as 0.825. The other alleles showed rather relatively low frequency. The heterozygosity was 0.2385 and 11 different genotypes were found. PIC was 0.2521, and no mutation was noted in GATA31D10 locus. Considering these two loci together, 22 different halpotype were noted.

거대고리 착이온 (NiL²)의 낮은 스핀상태(D)와 높은 스핀상태(O)간의 평형

卞鍾轍,韓性彬 제주대학교 1989 논문집 Vol.29 No.-

물, 아세토니트릴, 아세톤 및 니트로메탄에서 Ni(Ⅱ)-tetraamine 착물의 화학평형을 분광착이온의 낮은 스핀(??) 구조와 높은 스핀(??) 구조간의 평형이 니트로메탄을 제외한 물, 아세토니트릴, 아세톤 용액에서 나타났다. 각 용액에서 온도와 〔NaClO₄〕가 증가할수록 이 반응의 평형상수는 감소하였다. 각 용매에서 반응엔탈피와 반응엔트로피는 착물의 전자 스펙트럼에 대한 온도의 영향을 분석하므로써 결정하였다. ??구조인 triplet 화학종의 형성시, 아세토니트릴과 아세톤 용액에서 반응엔탈피(???)와 반응엔트로피(???)는 각각 1.26, 1.32, 그리고 25.01, 54.90이었다. The chemical equilibria of Ni(Ⅱ) - tetraamine(tetraamine = L,2,12 -dimethyl - 3,7,11,17-tetraazabicyclo - 11,3,1-heptadeca-1(17), 2,11,13,15-pentaene) complex ion in water, acetonitrile, acetone and nitromethane were investigated using spectrophotometric method, respectively. The equilibria between low-spin(??) and high-spin(??) structures of Ni-tetraamine complex ion were presented in water, acetonitrile and acetone, but not in nitromethane. The equilibrium constants, the reaction enthalpies and the reaction entropies were determined from analysis of the temperature dependence of the electronic spectra. The formation of the triplet species (??) was found to be exothermic. The solvent and electrolyte spectra. The formation of the triplet species (??) was found to be exothermic. The solvent and electrolyte effects on the equilibrium constants could be explained by the dielectric constants of solvents and the reaction entropries.

국내에서 채집한 진드기에서 중합효소연쇄반응을 이용한 라임병균 및 Ehrlichiosis 원인체의 검출

김종배,엄용빈,박성언,박상욱,김영미,송혜원,안준환 THE KOREAN SOCIETY FOR BIOMEDICAL LABORATORY SCIEN 1998 Journal of biomedical laboratory sciences Vol.4 No.2

국내에서 채집한 진드기의 라임병 및 ehrlichiosis원인체 보균 상태를 조사하기 위하여 총 516마리 (Ixodes spp. 22마리, Haemaphysalis spp. 494마리)의 ixodid 진드기를 봄과 가을에 걸쳐 강원도 고산지대 일원에서 채집하였다. 수집한 진드기에서 DNA를 추출 ·정제한 후 추출한 DNA를 template로 이용하여 , Borrelia burgdorferi sensu lato 및 Ehrlichia spp.에 특이하게 반응하도록 제작한 primer를 이용한 중합효소연쇄반응 (polymerase chain reaction, PCR)을 실시하였으며, 이 결과를 oligonucleotide probe를 사용한 southern blotting을 통하여 다시 확인하였다. 총 516마리의 진드기중 B.garinii sensu lato DNA 양성 인 진드기는 68(13.2%)마리 (B. burgdorferi sensu stricto,2; B. afzelii,1; B. garinii,33; B.tanukii,8; B.turdae, 4)로 나타났으며 이 중 37 (7.2%)마리의 진드기 는 southern blot analysis에서도 양성으로 확인되었다. 또한 101 (19.2%)마리의 진드기가 Ehrlichia spp.에 대한 PCR에서 양성 이었으나, 이들 중 25 (4.8%)마리 만이 southern blot analysis에서 양성으로 확인되었다. 그러나 사람의 병인체로 추정 되는 human granulocytic ehrlichiosis (HGE) agent DNA를 보균한 진드기는 확인되지 않았다. 한편 라임병균과 ehrlichiosis원인체를 동시에 보균한 것으로 밝혀진 진드기가 3마리에서 (0.6%)확인되어,국내에서도 진드기 교상시 이들 두 가지 열성질환이 동시에 감염될 가능성이 있는 것으로 사료됨으로 진드기 매개성 열성질환에 대한 적절한 진단법 등을 보다 체계적으로 연구하여야 할 것으로 판단된다. To investigate the distribution of Borrelia Burgdorferi and human granulocytic ehrlichiosis(HGE) agent in ticks, adult ixodid ticks of Ixodes spp. and Haemaphysalis spp. were collected from the high mountain areas of Kangwon Province. Using DNAs extracted and purified in the collected ticks, polymerase chain reaction (PCR) was performed to amplify the specific nucleotide sequences of both agents. Of the 516 ticks, a total of 68 (13.2%) ticks was positive for Borrelia burgdorferi sensu lato with PCR analysis (2 for B. burgdorferi sensu stricto; 1 for B. afzelii; 33 for B. garinii; 8 for B.tanukii; 4 for B. turdae). However a little more than half of PCR-positive ticks (37/68) was found to be positive in the southern blot analysis with Bl6S oligonucleotide probe. One hundred and one (19.2%) ticks were positive for Ehrlichia spp. in PCR, and a quarter of them (25/101) was positive in southern blot with E16S oligonucleotide probe. But none of them was found to be the DNA of HGE agent. And 0.6% (3/516) ticks were positive for both of B. burgdorferi sensu lato and Ehrlichia spp. These findings might implicate the possibility of the outbreak of lyme borreliosis and ehrlichiosis in Korea, and more extensive studies may be need for the diagnosis of multiple tick-borne diseases.

[cis-Cr(III)(5,5,7,12,12,14-hexamethy1-1,4,8,11-tetraazacyclotetradecane)(L_(a))_(n)]CLO_(4)(n = 1 or 2)합성과 성질

변종철,한성빈,정덕상,임희정,한충훈 濟州大學校 師範大學 科學敎育硏究所 1995 科學敎育 Vol.12 No.1

rac-5.5.7.12.12.14-hexamethy1-1,4,8,11-tetraazacyclotetradecane hydrate : Lm·H_(2)O was prepared and separated from the corresponding meso-isomer dihydrate according to the Curtis method. The racisomer was confirmed by spectroscopic data of NMR and IR spectroscopy. To synthesize the [CrL_m(OH)₂] complex. the racemic compound purified from meso and racemic mixture was reacted with Cr(II1) salt. The complx ion species {[SrL_m(OH)_(2)]^(+): λ_(max) = 613.0(ε_(max) = 116 M^(-1)cm^(-1)), {[CrLm(OH)(H_(2)O)]^(2+) : λ_(max) = 575.0nm(ε_(max) = 133M^(-1)cm^(-1)). [CrLm(H_(2)O)_(2)]^(3+) : λ_(max) = 532.0nm (ε_(max) = 172M^(-1)cm^(-1))} obtained from pH change of [CrLm(OH)_(2)(OH)_(3)]^(+) solution were confirmed from an electron absorption spectra. The result of the distribution diagram of chemical species proves that main products in the range of solution pH ≤ 3.5 . 3.5 <pH <7, and pH ≥ 7. are [CrLm(H_(2)O)_(2)]^(3+). [CrL_(m)(OH) (H_(2)O)^(2+). and [CrL_m(OH)_(2), respectively. At P~ 2.0, we synthesized several Cr(III)-macrocyclic complexes containing various axial ligands (L_(a) : I, Br^(-), CI^(-), S_(2)O_(3)^(2-), F^(-), malonate, NCS^-, oxalate) instead of H_(2)O. [CrL_m(OH_(2))]^(3+) + L_(a) →[CrL_(m)(L_(a))_(n)]^(+)(n = 1 or 2) Cr(III)-macrocyclic complexes combined with vaious ligands on the axial position were primarily confirmed with the mass spectrum. Especially, when the axial ligands are malonate, oxalate, and S_(2)O_(3)^(2-), a possible thermal decomposition reaction and redox potential are considered as follows: ◁표삽입▷(본문을 참조하세요) As well, a spectrochemical series was drawn up on the basis of the ligand field strength obtained from electron absorption spertra of the complexes, [CrL_(m)(La)_(n)]^(p+) F^(-), CI^(-) ~Br^(-)<I^(-)<S_(2)O_(3)^(2-)<OH^(-)<H_(2)O<mal~NCS^(-) We can expect that there is three d-d transition d^(3) ion Tanabe-Sugano diagram. ◁표삽입▷(본문을 참조하세요) However, we found only two trasitions because the other transition {^(4)A_(2)_g(F)→^(4)T_lg(P) : v_(3)} is obscured by absorption arising from charge transfer transition. ◁표삽입▷(본문을 참조하세요)

競技種目別 運動選手들의 筋力에 관한 硏究

박철빈,송종국,박수연,박찬호 경희대학교 체육과학연구소 1996 體育學論文集 Vol.24 No.-

The purpose of this study was to estimate physique and muscular strength in collegiate athletes. On a sample of 70 athletes (basketball, baseball, soccer, and ice-hockey) anthropometric measurements (height, weight, bone width, circumference and skinfold thicknesses) were taken, For the measurements of muscular strength grip strength, back strength, arm flexion and leg extension strength were tested. The results of this study showed that basketball players were highest for height, weight, humorous and femur diameters, chest circumference, and calf circumference. Ice-hockey players were highest for upper arm and flexed upper arm circumferences. On the other hand ice-hockey players were lowest for height, soccer players for weight, baseball players for humerous and femur diameters, soccer players for chest circumference. For skinfold thickness baseball players (10.1mm) were highest for triceps, basketball players (14.5mm) for subscapular, ice-hockey players (13.3mm) for suprailiac and medial calf (9.0mm) skinfold thicknesses. While soccer players were lowest for triceps (8.7mm), subscapular (8.6mm), suprailiac (9.8mm) and medial calf (7.5mm) skinfold thicknesses. There were significant differences (P〈0.01) for height, weight, femur diameter, upper arm and flexed upper arm circumferences among athletes. Grip strength (left and right) was highest in baseball players (52.1kg, 50.8kg) but lowest for soccer players (42.3kg, 42.8kg). Baseball players were highest for back strength (162.0kg). On the other hand back strength was lowest in ice-hockey players (127.1kg). For arm flexion and leg extension strength (left, right) basketball players (42.0kg, 44.9kg) were highest for both strength tests. While soccer players were lowest for arm flexion strength and baseball players for leg extension strength. Ice-hockey players were highest for sit-up (59.2). Significant differences (P〈0.01) were found for grip, back, arm flexion and leg extension strength and sit-up among athletes.

최적화 기법으로 시뮬레이티드 어닐링을 이용한 위성체 구조설계

임종빈,박정선 한국항공대학교 항공우주산업기술연구소 2002 航空宇宙産業技術硏究所 硏究誌 Vol.12 No.-

본 연구에서는 인공위성 구조체에 대하여 최적화를 수행하였다. 인공위성 구조체의 최적화는 발사환경을 고려하여 제한조건과 하중 조건을 설정하였다. 또한, 보편적인 최적화 프로그램에서는 다루기 힘든 제한 조건을 고려하기 위한 방법을 모색하였다. 이 방법은 유한요소 해석 프로그램과 최적화 프로그램을 연결하여 최적화를 수행하는 것이다. 이 방법에 의하여 시뮬레이티드 어닐링을 이용한 플랫폼과 추진모듈의 최적화를 수행하였고, 유용한 정보를 얻었다. 본 연구의 결과 인공위성 구조인 플랫폼과 추진모듈의 최적화에서는 응력에 의한 조건보다는 고유진동수에 의한 제한조건이 최적화 수행에 큰 영향을 미침을 알 수 있었다. Simulated annealing algorithm (SA) is applied to optimize satellite structures. In the optimization, constraints concerned with the various space environments are considered. The algorithms are merged into a finite element analysis program for the optimization of the satellite structures. Constraints are take with respect to equivalent stresses and natural frequency and so on. Numerical optimization results from the simulated annealing provide useful fact for designing the satellite structures. The results from the SA may reach close to the optimum design. Natural frequency may play major role in optimization procedures. This research can be applied to optimization of equipment module as well as payload module of satellite and so on.

소아환자의 깊은 진정요법 하에서 근단변위 판막술을 이용한 거대협소대의 치료

김종빈,윤형배 大韓小兒齒科學會 1999 大韓小兒齒科學會誌 Vol.26 No.1

The mandibular buccal frenum is defined as a fold of mucous membrane at the posterior labial vestibule and attaches the lips and the cheeks to the alveolar mucosa, gingiva, and underlying periosteum. The buccal frenum becomes a problem when its attachment is too colse to the marginal gingiva. It may then pull on healthy gingiva, encourage plaque formation and interfere with tooth brushing. Especially, heavy buccal frenum mucogingivally results in insufficent attached gingiva, inadequate vestibular depth and high frenum attachment and also difficulty in eruption of mandibular premolar. Frenotomy, frenectomy and mucogingival surgery are used in treating heavy buccal frenum. Frenotomy with autogenous free gingival graft has been used popularly because of its stable result. But, it is difficult in younger children because of inadequate donor site, difficulty in making recipient site and behavior management. Frenotomy with apically positioned flap is considered as more efficient way for a very young child with heavy buccal frenum. Additionally, modified deep sedation with N₂O-O₂can be used as an adjunct for the effective treatment outcome. Decrease in muscle pull, adequate width of attached gingiva and increased vestibular depth can be expected from this treatment approach.

흡연에 의한 급성 호산구성 폐렴 2예

박종빈,김학렬,주현준,유태양,신성남,신정현,송정섭,황기은,김소영,양세훈,정은택 圓光大學校 醫科學硏究所 2008 圓光醫科學 Vol.23 No.2

최근 흡연을 시작한 젊은 성언에서 급성 호산구성 폐렴의 발생에 대한 증례가 보고되고 있다. 급성 호산구성 폐렴은 대개 발열을 동반하기 때문에 초기에는 감염성 폐렴으로 잘못 진단, 치료되는 경우가 많다. 아직 정확한 병태 생리 및 조직학적 소견은 밝혀져 있지 않지만 병력 청취 및 임상 양상, 방사선 소견의 관찰을 통해 급성 호산구성 폐렴을 의심하고, 진단을 위해 기관지 폐포 세척액 검사를 시행한다면 좀 더 쉽게 진단 내릴 수 있을 것이다. 본 저자들은 최근 처음 시작한 흡연에 의해 발생한 급성 호산구성 폐렴을 진단하고, 스테로이드를 투여하여 성공적으로 치료한 환자 2예를 경험하였기에 이를 문헌 고찰과 함께 보고하는 바이다. Acute eosinophilic pneumonia(AEP) is characterized by acute febrile respiratory illness associated with diffuse pulmonary infiltration and pulmonary eosinophilia. The specific etiology for acute eosinophilic pneumonia is elusive. By some investigators, cigarette smoking is suggested as a causative substance which can cause AEP. In recent, the authors experienced two cases of AEP following cigarette smoking. Both cases had characteristic features including age around 20 years, new onset smoking before occurance of AEP, diffuse infiltration on chest radiography, pulmonary eosinophilia based on bronchoalveolar lavage and acute improvement after steroid therapy. These clinical features are resemble with previous smoking induced AEP case reports. Base on these clinical features, cigarette smoking associated AEP could be diagnosed more easily.