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      • Constrained State Estimation via Projection based Optimized Parameters UKF

        Yuanyuan Liu,Jingbiao Liu,Zhiwei He 보안공학연구지원센터 2016 International Journal of Hybrid Information Techno Vol.9 No.11

        The unscented Kalman filter (UKF) has become a popular method for nonlinear state estimation during the last decade. However, the conventional UKF may not be suitable for real-world applications with state constrains that stem from physical definitions, physical laws or model restrictions. A UKF based method with optimized parameters was proposed in this paper to handle state constraints via the projection of sigma points. In the proposed method, the generated sigma points that violate the state constraints were projected onto the constraint boundary first. The three free parameters of the UKF, i.e., α ,β ,κ , were then optimized using a Gaussian process optimization (GPO) method. Simulations indicate that the proposed optimized UKF algorithm with the projection of sigma points can handle constrained state estimation problem effectively and efficiently.

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        State of Charge Estimation for Li-Ion Batteries Based on an Unscented H-Infi nity Filter

        Yuanyuan Liu,Tiantian Cai,Jingbiao Liu,Mingyu Gao,Zhiwei He 대한전기학회 2020 Journal of Electrical Engineering & Technology Vol.15 No.6

        The state of charge (SOC) of lithium-ion batteries refl ects their remaining capacity. Accurate estimation of SOC helps battery safety and is benefi cial to the effi cient management of batteries. The charging and discharging processes of lithium-Ion batteries are very complicated, and it is diffi cult to obtain accurate SOC estimation results. Therefore, it is important to study improved algorithms for SOC estimation for this nonlinear non-Gaussian battery system. In this paper, we propose an unscented H-infi nity fi lter (UHF) based SOC estimation method, which combines the advantages of both the unscented Kalman fi lter (UKF) and the H-infi nity fi lter (HF). The UKF propagates the sigma points through the nonlinear system and does not need the fi rst-order linear approximation of the system equation, while the HF can suppress the non-Gaussian noise in the system to the greatest extent. The proposed UHF based SOC estimation algorithm is verifi ed and evaluated in the battery management system, and further optimized in practical problems. Experimental results show that the proposed UHF based algorithm can perform accurate SOC estimation for lithium-ion batteries, and is superior to the UKF based SOC estimation.

      • Covalent Confinement of Sulfur Copolymers onto Graphene Sheets Affords Ultrastable Lithium-Sulfur Batteries with Fast Cathode Kinetics

        Ma, Junpeng,Fan, Jingbiao,Chen, Shang,Yang, Xinyue,Hui, Kwun Nam,Zhang, Hongwen,Bielawski, Christopher W.,Geng, Jianxin American Chemical Society 2019 ACS APPLIED MATERIALS & INTERFACES Vol.11 No.14

        <P>Lithium-sulfur (Li-S) batteries have received significant attention due to the high theoretical specific capacity of sulfur (1675 mA h g<SUP>-1</SUP>). However, the practical applications are often handicapped by sluggish electrochemical kinetics and the “shuttle effect” of electrochemical intermediate polysulfides. Herein, we propose an in-situ copolymerization strategy for covalently confining a sulfur-containing copolymer onto reduced graphene oxide (RGO) to overcome the aforementioned challenges. The copolymerization was performed by heating elemental sulfur and isopropenylphenyl-functionalized RGO to afford a sulfur-containing copolymer, that is, RGO-<I>g</I>-poly(S-<I>r</I>-IDBI), which is featured by a high sulfur content and uniform distribution of the poly(S-<I>r</I>-IDBI) on RGO sheets. The covalent confinement of poly(S-<I>r</I>-IDBI) onto RGO sheets not only enhances the Li<SUP>+</SUP> diffusion coefficients by nearly 1 order of magnitude, but also improves the mechanical properties of the cathodes and suppresses the shuttle effect of polysulfides. As a result, the RGO-<I>g</I>-poly(S-<I>r</I>-IDBI) cathode exhibits an enhanced sulfur utilization rate (10% higher than that of an elemental sulfur cathode at 0.1C), an improved rate capacity (688 mA h g<SUP>-1</SUP> for the RGO-<I>g</I>-poly(S-<I>r</I>-IDBI) cathode vs 400 mA h g<SUP>-1</SUP> for an elemental sulfur cathode at 1C), and a high cycling stability (a capacity decay of 0.021% per cycle, less than one-tenth of that measured for an elemental sulfur cathode).</P> [FIG OMISSION]</BR>

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