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        Synthesis and Solution Properties of Zwitterionic Copolymer of Acrylamide with 3-[(2-Acrylamido)dimethylammonio]propanesulfonate

        Hui Xiao,Jing Hu,Shuailin Jin,Rui Hai Li 대한화학회 2013 Bulletin of the Korean Chemical Society Vol.34 No.9

        A novel zwitterionic monomer 3-[(2-acrylamido)dimethylammonio]propanesulfonate (DMADAS) was designed and synthesized in this study. Then it was polymerized with acrylamide (AM) by free radical polymerization in 0.5 mol/L NaCl solution with ammonium persulfate ((NH4)2S2O8) and sodium sulfate (NaHSO3) as initiator. The structure and composition of DMADAS and acrylamide-3-[(2-acrylamido)- dimethylammonio]propanesulfonate copolymer (P-AM-DMADAS) were characterized by FT-IR spectroscopy, 1H NMR and elemental analyses. Isoelectric point (IEP) of P-AM-DMADAS was tested by nanoparticle size and potential analyzer. Solution properties of copolymer were studied by reduced viscosity. Antipolyelectrolyte behavior was observed and was found to be enhanced with increasing DMADAS content in copolymer. The results showed that the viscosity of P-AM-DMADAS is 5.472 dl/g in pure water. Electrolyte was added, which weakened the mutual attraction between sulfonic acid group and quaternary ammonium group. The conformation became loose, which led to the increase of reduced viscosity. The ability of monovalent and divalent cation influencing the viscosity of zwitterionic copolymer obeyed the following sequence: Li+ < Na+ < K+, Mg2+ < Ca2+ < Ba2+, and that of anion is in the order: Cl− < Br− < I−, CO3 2− > SO3 2− ≈ SO4 2−.

      • KCI등재

        Cyclic response and design procedure of a weak-axis cover-plate moment connection

        Linfeng Lu,Yinglu Xu,Huixiao Zheng,James B.P. Lim 국제구조공학회 2018 Steel and Composite Structures, An International J Vol.26 No.3

        This paper systematically investigated the mechanical performance of the weak-axis cover-plate connection, including a beam end monotonic loading test and a column top cyclic loading test, and a series of parametric studies for exterior and interior joints under cyclic loading using a nonlinear finite element analysis program ABAQUS, focusing on the influences of the shape of top cover-plate, the length and thickness of the cover-plate, the thickness of the skin plate, and the steel material grade. Results showed that the strains at both edges of the beam flange were greater than the middle's, thus it is necessary to take some technical methods to ensure the construction quality of the beam flange groove weld. The plastic rotation of the exterior joint can satisfy the requirement of FEMA-267 (1995) of 0.03 rad, while only one side connection of interior joint satisfied ANSI/AISC 341-10 under the column top cyclic loading. Changing the shape or the thickness or the length of the cover-plate did not significantly affect the mechanical behaviors of frame joints no matter in exterior joints or interior joints. The length and thickness of the cover-plate recommended by FEMA 267 (1995) is also suitable to the weak-axis cover-plate joint. The minimum skin plate thickness and a design procedure for the weak-axis cover-plate connections were proposed finally.

      • SCOPUSKCI등재

        Efficient Greedy Algorithms for Influence Maximization in Social Networks

        Lv, Jiaguo,Guo, Jingfeng,Ren, Huixiao Korea Information Processing Society 2014 Journal of information processing systems Vol.10 No.3

        Influence maximization is an important problem of finding a small subset of nodes in a social network, such that by targeting this set, one will maximize the expected spread of influence in the network. To improve the efficiency of algorithm KK_Greedy proposed by Kempe et al., we propose two improved algorithms, Lv_NewGreedy and Lv_CELF. By combining all of advantages of these two algorithms, we propose a mixed algorithm Lv_MixedGreedy. We conducted experiments on two synthetically datasets and show that our improved algorithms have a matching influence with their benchmark algorithms, while being faster than them.

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