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      • Development of eco-friendly concrete produced with Rice Husk Ash (RHA) based geopolymer

        Annadurai, Shalini,Rathinam, Kumutha,Kanagarajan, Vijai Techno-Press 2020 Advances in concrete construction Vol.9 No.2

        This paper reports the effect of Rice Husk Ash (RHA) in geopolymer concrete on strength, durability and microstructural properties under ambient curing at a room temperature of 25℃ and 65±5% relative humidity. Rice husk was incinerated at 800℃ in a hot air oven. and ground in a ball mill to achieve the required fineness. RHA was partially added in 10, 15, 20, 25, 30 and 35 percentages to fly ash with 10% of GGBS to produce geopolymer concrete. Test results exhibit that the substitution of RHA in geopolymer concrete resulted in reduced strength properties during initial curing. In the initial stage, workability of GPC mixes was affected by RHA particles due to the presence of dormant particles in it. It is evident from the microstructural study that the presence of RHA particles densifies the matrix reducing porosity in concrete. This is due to the presence of RHA in geopolymer concrete, which affects the ratio of silica and alumina, resulting in polycondensation reactions products. This study suggests that incorporation of rice husk ash in geopolymer concrete is the solution for effective utilization of waste materials and prevention of environmental pollution due to the dumping of industrial waste and to produce eco-friendly concrete.

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        Effect of Chemically Treated / Untreated Carbon Cloth: Potential Use as Electrode Materials in the Capacitive Deionization Process of Desalination of Aqueous Salt Solution

        Thamilselvan, Annadurai,Nesaraj, A Samson,Noel, Michael,James, E.J. The Korean Electrochemical Society 2015 Journal of electrochemical science and technology Vol.6 No.4

        Capacitive deionization (CDI) process is a novel approach for desalination of an aqueous salt solution. In the present study, an activated carbon cloth (ACC) is proposed as effective electrode material. Initially the carbon cloth was activated in 1 M and 8 M HNO<sub>3</sub> for 9 hours at room temperature. The untreated and chemically activated carbon cloth (ACC) electrode materials were subjected to BET surface area measurements in order to get information about their specific surface area, average pore size, total pore volume and micropore area. The above materials were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM) also. The electrochemical studies for the electrodes were done using cyclic voltammetry (CV) in 0.1 M Na<sub>2</sub>SO<sub>4</sub> medium. From the studies, it was found that resistivity of the activated carbon cloth electrodes (treated in 1 M and 8 M HNO<sub>3</sub>) was decreased significantly by the chemical oxidation in nitric acid at room temperature and its capacitance was found to be 90 F/g (1 M HNO<sub>3</sub>) and 154 F/g (8 M HNO<sub>3</sub>) respectively in 0.1 M Na<sub>2</sub>SO<sub>4</sub> solution. The capacitive deionization behavior of a single cell CDI with activated carbon cloth electrodes was also studied and reported in this work.

      • Optimization of alkaline protease production from Shewanella oneidensis MR-1 by response surface methodology

        Anbu, Periasamy,Annadurai, Gurusamy,Lee, Jiunn-Fwu,Hur, Byung-Ki John Wiley Sons, Ltd. 2009 Journal of chemical technology and biotechnology Vol.84 No.1

        <P>BACKGROUND: The proteases are among the most important groups of enzymes. Therefore, it is important to produce inexpensive and optimized media for large-scale commercial production. In the present work, three different Shewanella species were screened on skim milk agar medium for their ability to produce alkaline protease. The effects of different culture conditions were optimized for alkaline protease production by S. oneidensis MR-1 using a Box–Behnken design combined with response surface methodology (RSM).</P><P>RESULTS: Highest yield (112.90 U mL<SUP>−1</SUP>) of protease production was obtained at pH 9.0, a temperature of 30 °C, glucose (12.5 g L<SUP>−1</SUP>), tryptone (12.5 g L<SUP>−1</SUP>) and an incubation period of 36 h. A second-order polynomial regression model was used for analysis of the experiment. The experimental values were in good agreement with predicted values, with correlation coefficient 0.9996.</P><P>CONCLUSION: Carbon and nitrogen, pH, temperature and incubation period were chosen as the main factors to be used in an experimental design for optimization to produce low-cost enzymes, potentially for use on an industrial scale. A 60% increase in enzyme activity was achieved in the optimized medium compared with the original medium. Copyright © 2008 Society of Chemical Industry</P>

      • Biosynthesis of semiconductor nanoparticles by using sulfur reducing bacteria Serratia nematodiphila

        Malarkodi, C.,Rajeshkumar, S.,Paulkumar, K.,Jobitha, G. Gnana,Vanaja, M.,Annadurai, G. Techno-Press 2013 Advances in nano research Vol.1 No.2

        The synthesis of semiconductor nanoparticles is a growing research area due to the prospective applications for the development of novel technologies. In this paper we have reported the biosynthesis of Cadmium sulfide nanoparticles (CdSNPs) by reduction of cadmium sulphate solution, using the bacteria of Serratia nematodiphila. The process for the synthesis of CdS nanoparticles is fast, novel and ecofriently. Formation of the CdS nanoparticles was confirmed by surface Plasmon spectra using UV-Vis spectrophotometer and absorbance strong peak at 420 nm. The morphology of crystalline phase of nanoparticles was determined from Scanning Electron Microscopy (SEM), Energy Dispersive X-ray spectroscopy and X-ray diffraction (XRD) spectra. The average size of CdS nanoparticles was in the range of 12 nm and the observed morphology was spherical. The results indicated that the proteins, which contain amine groups, played a reducing and controlling responsibility during the formation of CdS nanoparticles in the colloidal solution. Antibacterial activity against some bacteria such as Bacillus subtilis, Klebsiella planticola. CdS nanoparticles exhibiting good bactericidal activity.

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        Uniaxial Compression Properties and Compression Fatigue Performance of Selective Laser Melted Ti–6Al–4V Cellular Structure

        Ming‑Wei Wu,Jhewn‑Kuang Chen,Mo‑Kai Tsai,Pei Wang,Tien‑Lin Cheng,Bo‑Huan Lin,Po‑Hsing Chiang,Annadurai Dhinakar 대한금속·재료학회 2022 METALS AND MATERIALS International Vol.28 No.1

        The selective laser melted (SLM) Ti–6Al–4V cellular solid is a promising material in biomedical and other applications. The mechanical properties of the SLM Ti–6Al–4V cellular material are predominantly controlled by the design of the cellular structure. The objective of this study was to investigate the uniaxial compressive properties and compressive fatigueperformance of the SLM Ti–6Al–4V cellular solid with a new cuboctahedron unit cell reinforced by four diagonal strutsand two horizontal struts along the X and Y axes. The infuences of hot isostatic pressing (HIP) on the various mechanicalproperties were also examined. The results showed a smoother stress–strain curve and fewer stress oscillations in the HIPspecimen than in the SLM specimen. The HIP process slightly decreased the yield strength of the SLM sample from 55 to52 MPa. Under uniaxial compressive stress, the SLM and HIP specimens exhibited layer-by-layer fracture and diagonalshear fracture, respectively. Furthermore, the HIP treatment signifcantly increased the fatigue performance and improved thefatigue endurance ratio at 106cycles from 0.15 to 0.35. The HIP treatment contributed to several positive efects, includingphase transformation from brittle α′ to α + β, the elimination of strut porosity and residual stress, an increase in lath size,and a better combination of strength and ductility, thereby improving the fatigue performance. The efects of stress mode onthe fracture mechanism were also clarifed using in situ observation in combination with digital image correlation.

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