지속가능경영을 위한 ISO 요구사항 기반 정량적 협력업체 평가모델 구축 _반도체 공정에 한하여

유제영,이익모,황용우,김영운,Yu, Je-Young,Lee, Ik-Mo,Hwang, Yong-Woo,Kim, Young-Woon 대한안전경영과학회 2019 대한안전경영과학회지 Vol.21 No.2

The government announced that it would ask the contractors not only the supplier but also the contractors to take the same responsibilities if they did not observe industrial accident safety measures from 2019. The semiconductor manufacturing process belongs to the representative disaster industry group in which the facility is directly located inside a closed space called clean room. According to previous studies, the semiconductor industry group used checklists for safety management of their suppliers. This study has developed a model for assessing suppliers by constructing a quantitative checklist item through the risk assessment methodology, laws and regulations. The evaluation model of the supplier set up through this study becomes the safety management standard in the semiconductor industry. Furthermore, it is applied to the partner companies in the operation of ISO 14001, 45001, I would like to apply it as a measure of performance management for CSR (Corporate Social Responsibility).

Effect of Bases ( Amines and Phosphines ) on the Hydrogenolysis Reaction of CFC -113a by RhCl(PPh3)3

조욱재,이익모,김훈식,박건유 ( Ook Jae Cho,Ik Mo Lee,Hoon Sik Kim,Kun You Park ) 한국공업화학회 1995 한국공업화학회 연구논문 초록집 Vol.1994 No.1

불균일 촉매를 이용한 CFC-113a$(CF_3CCl_3)$의 액상 가수소 분해 반응

조욱재,이익모,김홍곤,김훈식,Jo, Uk Jae,Lee, Ik Mo,Kim, Hong Gon,Kim, Hun Sik 대한화학회 1994 대한화학회지 Vol.38 No.9

여러가지 불균일 촉매$(Rh/Al_2O_3,\;Pd/C,\;Ni,\;Al_2O_3,\;Active\;carbon)$를 이용하여 CFC-113a의 가수소 분해반응을 액상과 기상에서 각각 조사하였다. 액상반응에서는 각 촉매에 따라 반응성은 차이가 났지만, 95% 이상의 높은 선택성으로 $HCFC-123(CF_3CHCl_2)$을 주었다. 특히 $Al_2O-3$가 액상반응에서 상당히 높은 반응성과 선택성을 보인 것은 주목할 만하다. 기상반응의 경우, 전이금속이 포함된 촉매(Pd/C, Pt/C)를 사용하였을 때에는 과수소화물인 $HCFC-133a(CF_3CH_2Cl)$와 HFC-143a(CF_3CH_3)$가 생성되었다. 한편, 액상반응에서 활성을 보이던 $Al_2O_3$는 기상반응에서는 거의 반응성을 보이지 않았다. $Al_2O_3$의 경우 용매로 THF를 사용하였을 경우에는 비교적 부반응 없이 깨끗하게 반응이 진행되었지만, MeOH를 사용하였을 때는 용매로 부터 $CH_3OCH_3$과 $CH_3CH_2OCH_3$ 등이 생성되면서 가수소 분해반응이 진행되었다. 따라서 액상반응에서는 용매의 역할이 중요한 것으로 해석하였다. Hydrogenolysis reactions of CFC-113a catalyzed by various heterogeneous catalysts $(Rh/Al_2O_3,\;Pd/C,\;Ni,\;Al_2O_3,\;Active\;carbon)$ were investigated in the liquid and gas phases. In the liquid phase reaction, different catalysts showed different activities, but all catalysts used gave high selectivities toward HCFC-123 over 95%. It was noticeable that the neutral $Al_2O_3$ showed both a high activity and a selectivity in the liquid phase reaction. In the gas phase reaction, transition metals on carbon(Pd/C, Pt/C) were so active for hydrogenolysis of CFC-113a that they even catalyzed the production reaction of overhydrogenated compounds such as $HCFC-133a(CF_3CH_2Cl)\;and\;HFC-143a(CF_3CH_3)$. $Al_2O_3$, which showed the high activity in the liquid phase reaction, did not show a remarkable activity. When $Al_2O_3$ was used in the liquid phase reaction, the hydrogenolysis of CFC-113a proceeded without any side products in THF. However, the same reaction in MeOH produced side products, such as $CH_3OCH_3\;and\;CH_3CH_2OCH_3$ from solvent. Based on this result, including heterogeneous catalysts, it was concluded that the solvent played an important role in the liquid phase reaction.

액화수소 충전스테이션에서 VCE로 인한 피해영향평가에 관한 연구

이수지(Suji Lee),천영우(Young Woo Chon),이익모(Ik Mo Lee),황용우(Yong Woo Hwang) 한국가스학회 2017 한국가스학회지 Vol.21 No.5

전세계적으로 수소 충전 스테이션 구축에 많은 투자와 지원을 하고 있는 실정이다. 그러나 수소는 폭발범위가 넓고 확산이 빠른 기체이다. 본 연구에서는 액화수소를 취급하는 소규모~대규모 충전스테이션을 대상으로, 사고시 발생하는 VCE로 인한 피해영향범위를 산출하고, 프로빗 모델을 통해 주변의 인적, 물적 피해를 예측하였다. 더불어, 벤트스택 끝단에서 발생 가능한 Jet fire를 시나리오로 선정하여 최적 높이를 설정하였다. 피해영향범위는 관심과압 6.9kPa을 기준으로 하여, 소규모 저장시설의 경우 8.24m, 중규모 14.10m, 대규모 22.38m이다. 폐출혈로 인한 인체 피해는 소규모와 중규모가 각각 50m, 대규모 100m였으며, 구조물 손상에 따른 피해는 소규모 200m, 중규모 300m 및 대규모 500m이다. 벤트스택의 최적높이는 소규모 4.7m, 중규모 8.8m 및 대규모 16.9m이다. Hydrogen charging station was invested and supported around the world. In this study, the extent of damage caused by VCE in the charging station handling liquefied hydrogen was calculated, and the human and material damage was estimated through the Probit model. In addition The optimal height of vent stack for low temperature hydrogen was set. The damage range is 8.24m in small scale, 14.10m in medium scale, and 22.38m in large scale based on interest overpressure 6.9kPa. In case of death due to pulmonary hemorrhage, 50m of the small and medium scale and 100m of the large scale were injured. Structural damage was 200m in small scale, 300m in medium scale and 500m in large scale. The optimum height of the vent stack is 4.7 m in small scale, 8.8 m in medium scale and 16.9 m in large scale.

누출특성을 통한 폭발위험장소 선정방법의 개선에 대한 연구

김대연,천영우,이익모,황용우,Kim, Dae-Yeon,Chon, Young-Woo,Lee, Ik-Mo,Hwang, Yong-Woo 대한안전경영과학회 2017 대한안전경영과학회지 Vol.19 No.2

Classify of explosion hazardous areas must be made at the site where flammable materials are used. This reason is that it is necessary to manage ignition sources in of explosion hazardous areas in order to reduce the risk of explosion. If such an explosion hazard area is widened, it becomes difficult to increase the number of ignition sources to be managed. The method using the virtual volume currently used is much wider than the result using CFD(Computational Fluid Dynamics). Therefore, we tried to improve the current method to compare with the new method using leakage characteristics. The result is a realistic explosion hazard if the light gas is calibrated to the mass and the heavy gas is calibrated to the lower explosion limit. However, it is considered that the safety factors should be taken into account in the calculated correction formula because such a problem should be considered as a buffer for safety.

누적독성부하 산정을 통한 주민소산 전환시점 선정에 관한 연구 -인천지역을 중심으로-

이은지,한만형,천영우,이익모,황용우,Lee, Eun Ji,Han, Man Hyeong,Chon, Young Woo,Lee, Ik Mo,Hwang, Yong Woo 한국안전학회 2020 한국안전학회지 Vol.35 No.6

With the development of the chemical industry, the chemical accident is increasing every year, thereby increasing the risk of accidents caused by chemicals. The Ministry of Environment provides the criteria for determining shelter-in-place or outdoor evacuation by material, duration of accident, and distance from the toxic substance leak. However, it is hard to say that the criteria for determining the transition point are not clear. Transition point mean the time that evacuation method is switched from shelter-in-place to outdoor evacuation. So, the purpose of this study was to calculate appropriate transition point by comparing the cumulative toxic load. Namdong-gu in Incheon Metropolitan City was finally selected as the target area, considering the current status of the population of Incheon Metropolitan City in 2016 and the statistical survey of chemicals in 2016. The target materials were HCl, HF, and NH₃. Modeling was simulated by ALOHA and performed assuming that the entire amount would be leaked for 10 min. Residents' evacuation scenarios were assumed to be shelter-in-place, immediate outdoor evacuation, and outdoor evacuation at an appropriate time after shelter-in-place. Based on the above method, the appropriate transition point from residents located in A(800 m away), B(1,200 m away), C(1,400 m away) and D(2,200 m away) was identified. In HCl, appropriate transition point was after 15 min, after 16 min, after 17 min, after 20 min in order by A, B, C and D. In HF, appropriate transition point was before 1 min or after 16 min, before 4 min or after 19 min, before 5 min or after 20 min, before 14 min or after 26 min in order by A, B, C and D. In NH₃, appropriate transition point at A was before 4 min or after 16. Others are not in chemical cloud. This study confirmed the transition point to minimize the cumulative toxic load can be obtained by quantitative method. Through this, it might be possible to select evacuation method quantitatively that cumulative toxic load are minimal. In addition, if the shelter-in-place is maintained without transition to outdoor evacuation, the cumulative toxic load will increase more than outdoor evacuation. Therefore, it was confirmed that actions to reduce the concentration of chemicals in the room were necessary, such as conducting ventilation after the chemical cloud passed through the site.

FDS 및 Pathfinder를 이용한 노인의료복지시설의 피난시간 산정

전인범(In-Beom Jeon),이익모(Ik-Mo Lee ),황용우(Yong-Woo Hwang),천영우(Young-Woo Chon) 한국위험물학회 2018 한국위험물학회지 Vol.6 No.1

Currently, the number of elderly people aged 65 or older in Korea is increasing steadily, reaching 14.3 %. As the number of elderly people increases, the number of elderly welfare facilities such as nursing homes is also increasing, and the number of elderly welfare facilities has increased to 75,708 in 2016 from 50,517 in 2003. In November 2010, a fire occurred at an elderly care center in Pohang city, and There were 17 deaths and 10 injured. Since then National Fire Safety Code have been significantly strengthened. However, accidents of evacuees such as medical welfare facilities for the elderly are continuously occurring. Now, Institutional research on evacuation planning is underway in many areas. we calculated the evacuation time (ASET : Available Safe Egress Time) according to presence or absence of fire facilities and the evacuation time (RSET : Required safe egress time) associated with the type of building in the elderly medical welfare facilities. In this study, fire facilities, which are essential for elderly medical welfare facilities, are operated for efficient evacuation by using Pyrosim and Pathfinder for sofa in living facilities (elderly medical welfare facilities) And whether they can evacuate. The conclusion was that normal operation of fire facilities and additional building considerations (such as ramps and exit widths) could be identified for evacuation of non-durable patients.

Rutheniumhydridonitrosyl 착물을 이용한 불포화 유기화합물의 수소화 반응

박미영,김영중,조욱재,이익모,Park, Mi Young,Kim, Young Joong,Cho, Ook Jae,Lee, Ik Mo 대한화학회 1996 대한화학회지 Vol.40 No.6

Hydridonitrosyl complex의 촉매 활용 가능성과 반응 mechanism을 조사하기 위하여 $RuH(NO)(PPh_3)_3$와 RuH(NO)(etp)에 의한 ketone과 aldehyde의 수소화 반응을 연구하였다. 이 촉매들은 ketone과 aldehyde의 수소화 반응에 대하여 촉매 활성을 보이고 있으며, 활성은 기질의 입체장애 및 전자적 요인에 의존하고 있다. 즉, 입체 장애가 적을수록 촉매의 활성이 증가하며, 전자적 요인의 효과는 ketone의 경우 carbonyl carbon의 부분양전하의 양이 증가할수록, aldehyde의 경우는 carbonyl group의 double bond character가 강할수록 반응성이 증대되는 방향으로 나타나고 있다. 이러한 결과는 ketone과 aldehyde의 반응 mechanism이 다름을 반영하고 있다. 한편, RuH(NO)(etp)와 과잉의 $PPh_3$ 존재하에서 $RuH(NO)(PPh_3)_3$가 촉매 활성을 보이고 있음은 NO ligand의 결합방식의 변화를 통한 반응경로가 존재함을 확인하고 있다. 과잉의 $PPh_3$는 촉매와의 몰비가 변함에 따라 작용의 변화(ligand의 해리 방지 ${\rightarrow}$ 염기 ${\rightarrow}$ ligand)가 나타나며 촉매 활성에 영향을 미치고 있다. 이러한 결과를 이해하기 위하여 각 촉매에 대한 반응 mechanism을 제시하였다. 한편, 동일한 기질에 있어서 RuH(NO)(etp)의 활성은 항상 $RuH(NO)(PPh_3)_3$에 비하여 낮았으며 이는 주로 착물의 구조차이에 기인한 것으로 해석되며, 경쟁반응에 있어서는 olefin의 수소화 반응이 carbonyl group의 수소화 반응보다 선택적으로 진행되고 있다. Catalytic hydrogenation of ketones and aldehydes by RuH(NO)$L_3$ ($L_3$: $PPh_3$, PhP($CH_2CH_2PPh_2$)$_2$(etp)) was investigated to examine the reaction mechanism and the competence of hydridonitrosyl complexes as catalysts for organic synthesis. RuH(NO)$L_3$ showed catalytic activity for the hydrogenation and the activities of catalysts were dependent on the steric and electronic factors. The less the steric demands of the substrates become, the more activity the catalysts show. For the electronic effect, the more the partial positive charge on the carbonyl carbon atom in ketones becomes and the more the double bond character of carbonyl group in aldehydes becomes, the more active the catalysts are. These results reflect the difference of reaction mechanisms of two substrates, ketones and aldehydes. Catalytic activities of RuH(NO)(etp) and RuH(NO)($PPh_3$)$_3$ in the presence of extra $PPh_3$ toward hydrogenation showed the existence of a reaction pathway accompanied with the change of the bonding modes of NO ligand. The roles of excess $PPh_3$ change with increase of the mole ratio of $PPh_3$ to catalysts; prevention of ligand dissociation from comlexes → bases → ligands. The activity of RuH(NO)(etp) was lower than that of RuH(NO)($PPh_3$)$_3$ toward the hydrogenation of the same substrates mainly due to the structural difference. These catalysts showed the selectivity toward olefin hydrogenation over carbonyl groups in the competitive reaction.

냉동제조 시설의 암모니아 누출사고 위험 분석

강수진(Su-Jin Kang),이익모(Ik-Mo Lee),문진영(Jin-Young Moon),천영우(Young-Woo Chon) 한국가스학회 2017 한국가스학회지 Vol.21 No.1

국내 냉동제조시설에서 암모니아 누출사고가 여전히 발생하고 있음을 볼 수가 있다. 암모니아는 가연성가스 및 독성가스이므로 사고 발생할 때 인체와 생태계에 큰 피해를 일으킬 수 있다. 국내 냉동제조시설의 암모니아 사고유형을 파악한 후 사고시나리오를 선정하여 피해범위를 산정하고 사고 빈도와 위험도를 분석하여 사고 피해를 최소화하는 대책 수립이 필요하다. 본 연구에서는 정량적 위험성 평가(QRA: quantitative risk assessment)의 분석 방법에 따라 암모니아 냉동시스템의 리시버 탱크에 대한 위험도를 분석하였다. 시나리오 분석 조건은 화학물질관리법에서 정하는 ‘사고시나리오 선정에 관한 기술지침’ 및 미국 화학공정안전센터(CCPS: center for chemical process safety)의 가이드라인에 따라 정하였다. DVN사의 SAFETI 프로그램을 활용하여 시나리오에서 선정된 모든 사고 영향범위를 산정하고 빈도 분석을 통하여 리시버 탱크에 대한 위험도를 도출하였다. 빈도 값은 사건수 분석(ETA: event tree analysis)기법과 Part count 기법을 활용하였다. 연구 결과 암모니아 냉동시스템의 개인적 위험도는 7.71E-04/yr으로 도출되었으며, 사회적 위험도 1.17E-03/yr으로 도출되었다. 도출된 위험도는 국제 화재방지협회 (NFPA: national fire protection association)의 ALARP (as low as reasonably practicable) 범위를 적용하여 위험도의 적합성을 확인하였으며, 본 연구에서 제안한 위험도 산정 방법이 사고 피해 최소화 방안을 모색하는데 활용된다면 보다 좋은 결과가 도출될 것으로 판단된다. Recently, ammonia leak occurred frequently in the domestic refrigeration manufacturing facilities. Ammonia caused great damage to the environment and human health in the event of an accident as combustible gases and toxic gases. After considering the types of ammonia accidents of domestic refrigeration manufacturing facilities and selected accident scenarios and to analyze the risk analysis through Impact range estimates and frequency analysis and there was a need to establish measures to minimize accident damage. In this study, depending on the method of analysis quantitative risk assessment we analyzed the risk of the receiver tank of ammonia system. Scenario analysis conditions were set according to the ‘Technical guidelines for the selection of accident scenario’ under the chemicals control act and Guidelines for chemical process quantitative risk analysis of center for chemical process safety. The risk estimates were utilized for consequence analysis and frequency analysis by SAFETI program of DNV, event tree analysis methodology and part count methodology. The individual risk of ammonia system was derived as 7.71E-04 / yr, social risk were derived as 1.17E-03 / yr. The derived risk was confirmed to apply as low as reasonably practicable of the national fire protection association and through risk calculation, it can be used as a way to minimize accidents ammonia leakage accident damage.

컨테이너 터미널 옥외저장소에서의 액면화재에 대한 피해영향 평가

황만웅(Man Woong Hwang),이익모(Ik Mo Lee),황용우(Yong Woo Hwang),천영우(Young Woo Chun) 한국방재안전학회 2016 한국방재안전학회 논문집 Vol.9 No.2

약항만 옥외저장소는 포장위험물의 수출입을 위해 컨테이너 터미널 특정 공간에 마련된 장소로, 옥외저장소 간 보유공지 기준을 완화하여 사고발생 시 피해확대 우려가 가중되고 있다. 본 연구에서는 탱크 컨테이너로부터 인화성 액체 누출로 인한 액면화재를 모사함으로써 복사열에 대한 피해영향을 분석하였다. 그 결과 임계손상기준에 따른 복사열 도달거리가 현행 보유 공지 기준을 상회하는 것으로 분석되었으며, 인접 컨테이너가 early pool fire에 지속적으로 노출될 경우 단시간 내 구조적 손상 가능성이 있는 것으로 평가되었다. 본 연구는 컨테이너 터미널에서의 적절한 옥외저장소 간 보유공지 기준을 마련하는데 도움이 될 수 있을 것으로 판단된다. Domestic harbor yard storage facilities are a place specifically located in a container terminal for import and export of packaged dangerous goods, and due to the recent relaxed criteria for the secured open area, concerns for the extended damage upon accidents are increasing. In this study, the impact of damages by radiant heat was analyzed through a simulation of a pool fire caused by the leakage of flammable liquids from a tank container. As a result, it was analyzed that the distance of radiant heat according to threshold damage levels was beyond the current criteria of the secured open area, and the structural damage of adjacent containers could happen within a very short time if they were exposed to the early pool fire continuously. It is considered that this study will be helpful in preparing the proper criteria for the secured open area between yard storage facilities in a container terminal.