SHS 공정에 의해 제조된 Mo_xW_1-xSi₂ 발열체의 열화메커니즘

이동원,이상헌,김용남,이성철,구상모,오종민,Lee, Dong-Won,Lee, Sang-Hun,Kim, Yong-Nam,Lee, Sung-Chul,Koo, Sang-Mo,Oh, Jong-Min 한국전기전자재료학회 2017 전기전자재료학회논문지 Vol.30 No.10

The degradation mechanism of $Mo_xW_{1-x}Si_2$ ultrahigh-temperature heating elements fabricated by self-propagating high-temperature synthesiswas investigated. The $Mo_xW_{1-x}Si_2$ specimens (with and without post-annealing) were subjected to ADTs (accelerated degradation tests) at temperatures up to $1,700^{\circ}C$ at heating rates of 3, 4, 5, 7, and $14^{\circ}C/min$. The surface loads of all the specimen heaters were increased with the increase in the target temperature. For the $Mo_xW_{1-x}Si_2$ specimens without annealing, many pores and secondary-phase particles were observed in the microstructure; the surface load increased to $23.9W/cm^2$ at $1,700^{\circ}C$, while the bending strength drastically reduced to 242 MPa. In contrast, the $Mo_xW_{1-x}Si_2$ specimens after post-annealing retained $single-Mo_xW_{1-x}Si_2$ phases and showed superior durability after the ADT. Consequently, it is thought that the formation of microcracks and coarse secondary phases during the ADT are the main causes for the degraded performance of the $Mo_xW_{1-x}Si_2$ heating elements without post-annealing.

화학기상응축법으로 제조된 철 나노분말의 산화저항에 관한 연구

이동원,유지훈,배정현,장태석,김병기,Lee Dong-Won,Yu Ji-Hun,Bae Jeoung-Hyun,Jang Tae-Suk,Kim Byoung-Kee 한국분말야금학회 2005 한국분말재료학회지 (KPMI) Vol.12 No.3

In order to prevent the oxide formation on the surface of nano-size iron particles and thereby to improve the oxidation resistance, iron nanoparticles synthesized by a chemical vapor condensation method were directly soaked in hexadecanethiol solution to coat them with a polymer layer. Oxygen content in the polymer-coated iron nanoparticles was significantly lower than that in air-passivated particles possessing iron-core/oxide-shell structure. Accordingly, oxidation resistance of the polymer-coated particles at an elevated temperature below $130^{\circ}C$ in air was $10\~40$ times higher than that of the air- passivated particles.

서양의 역사적인 지도제작법의 발달 과정과 수학적 지식의 상호 영향 관계를 통해 본 직교좌표계

이동원,Lee, Dong Won 한국수학사학회 2012 Journal for history of mathematics Vol.25 No.4

역사적인 지도제작법에 나타난 좌표계와 수학적 직교좌표계의 발전 과정을 비교하면서 위치를 표시하는 직교좌표계는 수학의 해석기하학과는 상관없이 인간 본연에 내재되어 있었던 공간지각능력의 일환으로 발전되어 왔음을 주장한다. 지도제작법의 발전이 해석기하학의 발명 전후 삼각함수, 로그, 기하학, 미적분학, 통계학 등 수학의 여러 분야와 상호 영향을 미치지만 원점의 표시나 음수 좌표의 사용과 같은 수학적 직교좌표계 자체에 대한 발전은 데카르트의 논문 발표 후 100여년 이상 지난 후에 이루어지는 점, 해석기하학을 발명하는데 공헌한 대부분의 수학자들이 당대의 문제 해결에 집중하면서 직교좌표계에 대한 수학적 설명없이 자연스럽게 사용하였던 점을 바탕으로 이런 결론을 얻는다. By comparing the development history of rectangular coordinate system in Cartography and Mathematics, we assert in this manuscript that the rectangular coordinate system is not so much related to analytic geometry but comes from the space perceiving ability inherent in human beings. We arrived at this conclusion by the followings: First, although the Cartography have much influenced to various area of Mathematics such as trigonometry, logarithm, Geometry, Calculus, Statistics, and so on, which were developed or progressed around the advent of analytic geometry, the mathematical coordinate system itself had not been completely developed in using the origin or negative axis until 100 years and more had passed since Descartes' publication. Second, almost mathematicians who contributed to the invention of rectangular coordinate system had not focused their studying on rectangular coordinate system instead they used it freely on solving mathematical problem.

슬개골 내측 추벽의 양동이 손잡이형 파열 - 증례 보고 -

이동원,하정구,김진구,Lee, Dhong Won,Ha, Jeong Ku,Kim, Jin Goo 대한정형외과스포츠의학회 2011 대한정형외과스포츠의학회지 Vol.10 No.2

슬관절의 추벽은 정상적인 구조물로 인식되고 있으나 외상, 반복적인 손상 등과 같은 유발 인자에 의해 비후되면서 탄력성을 소실하고 병적인 추벽으로 변하면서 증상을 일으키게 된다. 슬개골 내측 추벽 증후군은 슬내장의 주요한 원인으로 이에 대한 많은 연구가 이루어지고 여러 문헌에서 보고되어 왔으나 추벽의 양동이형 손잡이형 파열에 대한 보고는 극히 드물다. 저자들은 슬개골 내측 추벽의 양동이 손잡이형 파열에서 관절경적으로 절제한 증례를 보고하는 바이다. The medial patellar plica may cause symptoms when it becomes thickened and fibrotic because of direct trauma or repetitive sporting activities. The medial plica syndrome has been noticed as one of major causes of internal derangement and well documented in the articles. A few cases of the bucket handle tear of the medial plica are described in liteartures. To our knowledge, however, there have never been reported about it in domestic literatures. We present a case of the bucket handle tear of the medial plica resected by arthroscopic surgery with a review of the relevant articles.

지주막하출혈에 의한 뇌기저동맥의 형태학적 변화에 미치는 양격산화탕(凉膈散火湯)의 효과

이동원,이원철,Lee, Dong-Won,Lee, Won-Chul 대한한의학회 1999 대한한의학회지 Vol.20 No.2

The present study was performed to investigate the effect of Yangkyuksanhoa-tang on the morphological changes of the basilar artery after experimentally induced subarachnoid hemonrrhages(SAH). Yangkyuksanhoa-tang has been used freguently for cerebrovascular accident Sprague Dawley rats weighing between 350-400 g were used. The 6 normal rats and 24 SAH elicited rats were used, The SAH induced by injection of the fresh autologus heart blood (0.3-0.4 ml) into the cisterna magna through the posterior atlanta-occipital membrane, Sample group was given 3.3 ml/kg/day of Yangkyuksanhoa-tang extracts for 2 days after SAH. The experimental animals were killed at 48hrs after SAH. The morphological changes of the arterial walls were examined by light and electron microscopy. Following are the obtained results: 1. In SAH elicited rats, the size of the lumen in basilar artery was diminished by about 45% and the thickness of arterial wall was increased by about 82%. In SAH elicited rats with Yangkyuksanhoa-tang treatment, the size of the lumen in basilar artery was merely diminished by about 18% and the thickness of arterial wall was merely increased by about 19%. 2. In light microscopic examination, the endothelium was swollen into a cuboid shape and the layer of smooth muscle was increased in the basilar artery of SAH elicited rats. In SAH elicited rats with Yangkyuksanhoa-tang treatment, the size of the lumen in basilar artery was enlarged and the thickness was decreased than in SAH elicited rats. The endothelium was flattened into a squamous shape and the layer of smooth muscle was decreased more than in SAH elicited rats. 3. In electron microscopic examination, the endothelial cells with fragmentation nuclei were changed into a cuboid shape and the internal elastic lamina were folded at the basilar artery of SAH elicited rat. The nuclei of smooth muscle cells were changed into a round or crumpled shape. The length of smooth muscle was shorten and thickness was increased. But all kinds of morphologic changes were diminished in SAH elicited rats with Yangkyuksanhoa-tang treatment. Conclusion : Yangkyuksanhoa-tang extracts were effective to treat cerebral vasospasm after experimentally induced subarachnoid hemorrhage in rats.

화학기상응축공정에 의한 WS₂ 나노입자의 합성 및 특성평가

이동원,김주형,올레그토로츠코,윤중열,김병기,Lee, Dong-Won,Kim, Ju-Hyeong,Tolochko, O.,Yun, Jung-Yeul,Kim, Byung-Kee 한국분말야금학회 2008 한국분말재료학회지 (KPMI) Vol.15 No.4

Nano-sized tungsten disulfide ($WS_2$) powders were synthesized by chemical vapor condensation (CVC) process using tungsten carbonyl ($W(CO)_6$) as precursor and vaporized pure sulfur. Prior to the synthesis of tungsten disulfide nanoparticles, the pure tungsten nanoparticles were produced by same route to define the optimum synthesis parameters, which were then successfully applied to synthesize tungsten disulfide. The influence of experimental parameters on the phase and chemical composition as well as mean size of the particles for the produced pure tungsten and tungsten disulfide nanoparticles, were investigated.

탄탈륨 산화물의 마그네슘 가스환원에 의한 탄탈륨 금속분말 제조

이동원,Lee, Dong-Won 한국분말야금학회 2018 한국분말재료학회지 (KPMI) Vol.25 No.5

Metallic tantalum powder is manufactured by reducing tantalum oxide ($Ta_2O_5$) with magnesium gas at 1,073-1,223 K in a reactor under argon gas. The high thermodynamic stability of magnesium oxide makes the reduction reaction from tantalum oxide into tantalum powder possible. The microstructure after the reduction reaction has the form of a mixture of tantalum and magnesium oxide, and the latter could be entirely eliminated by dissolving in weak hydrochloric acid. The powder size in SEM microstructure for the tantalum powder increases after acid leaching in the range of 50-300 nm, and its internal crystallite sizes are observed to be 11.5 to 24.7 nm with increasing reduction temperatures. Moreover, the optimized reduction temperature is found to be 1,173 K as the minimum oxygen concentration is approximately 1.3 wt.%.

ITER 일차벽의 Cu/SS Mock-up에 대한 고열부하 시험

이동원,배영덕,홍봉근,이종혁,박정용,정용환,Lee, D.W.,Bae, Y.D.,Hong, B.G.,Lee, J.H.,Park, J.Y.,Jeong, Y.H. 한국진공학회 2006 Applied Science and Convergence Technology Vol.15 No.3

ITER (International Thermonuclear Experimental Reactor) 조달용 일차벽의 제조 건전성을 검증하기 위해서, 일차벽을 구성하는 Cu/SS mock-up을 제작하여 고열부하 시험을 수행하였다. Cu/SS mock-up은 CuCrZr과 SS316L이 사용되었으며, 두 금속은 $1050^{\circ}C$, 150 MPa의 조건에서 고온등방가압법 (HIP, Hot Isostatic Pressing) 과정을 통해 접합되었다. 시험에 사용된 고열부하 장치는 일본 원자력연구소의 JEBIS (JAEA Electron Beam Irradiation Stand)를 이용하였으며, 시험 조건은 FEM 코드인 ANSYS 해석을 통해 결정하였다. 시험은 $5MW/m^2$의 고열부하를 15초간 인가하고, 30초간 냉각하는 방법으로 수행되었으며, 시험 종료 후 얻어진 시험결과와 해석결과가 잘 일치함을 확인하였다. In order to verify the integrity of the first wall (FW) of the International Thermonuclear Experimental Reactor (ITER), the fabricated Cu/SS mock-up is tested in the JAEA Electron Beam Irradiation Test Stand (JEBIS). To fabricate the Cu/SS mock-up, CuCrZr and 316L authentic stainless steel (SS316L) are used for Cu alloy and steel, respectively The hot isostatic pressing (HIP) is used as a manufacturing method with a $1050^{\circ}C$ and 150 MPa. The high heat flux (HHF) test is performed using an electron beam with a heat flux of $5MW/m^2$ and a cycle of 15-sec on time and 30-sec off time. The temperature measurement in the HHF test shows good agreement with the results obtained from ANSYS code analysis, which is used for determining the HHF test conditions.

러시아 티타늄계 고융점 화합물 분말합성 신기술

이동원,김병기,Lee, Dong-Won,Kim, Byeong-Gi 재료연구소 2004 機械와 材料 Vol.16 No.1

마그네슘환원에 의한 지르코늄-티타늄 합금분말 합성

이동원,박근태,임태수,이혜문,유지훈,Lee, Dong-Won,Park, Geun-Tae,Lim, Tae-Soo,Lee, Hye-Moon,Yu, Ji-Hun 한국분말야금학회 2011 한국분말재료학회지 (KPMI) Vol.18 No.4

Zr-Ti alloy powders were successfully synthesized by magnesium thermal reduction of metal chlorides. The evaporated and mixed gasses of $ZrCl_4+TiCl_4$ were injected to liquid magnesium and the chloride components were reduced by magnesium leading to the formation of $MgCl_2$. The released Zr and Ti atoms were then condensed to particle forms inside the mixture of liquid magnesium and magnesium chloride, which could be dissolved fully in post process by 1~5% HCl solution at room temperature. By the fraction-control of individually injected $ZrCl_4$ and $TiCl_4$ gasses, the final compositions of produced alloy powders were changed in the ranges of Zr-0 wt.%~20 wt.%Ti and their purity and particle size were about 99.4% and the level of several micrometers, respectively.