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김민진 ( Min Jin Kim ),이경범 ( Gyeong Beom Yi ),유준 ( Jay Liu ) 한국화학공학회 2013 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.51 No.6
혼합냉매를 사용하여 천연가스를 액화하는 혼합냉매공정(Mixed refrigerant cycle, MRC)은 공정이 간단하고 장치비가 적게 들며 운전 또한 용이하여 널리 채택되고 있는 공정이다. MRC에서 중요한 기술 중 하나는 혼합냉매를 선택하고 최적의 혼합비를 결정하는 것이다. 본 연구에서는 일반적인 MRC에서 혼합냉매와 혼합냉매의 혼합비가 공정의 성능에 미치는 효과를 살펴보았다. 이를 위해 통계적 기법 중 실험계획법의 하나인 혼합물 설계와 반응 표면법을 이용하여 전체 공정의 에너지 소비가 최소가 되게 하는 최적의 냉매를 선택하고 그 혼합비를 결정하였다. 여러 냉매와 혼합비에 따른 MRC 공정의 모사는 Aspen HYSYS를 사용하였으며 혼합물설계와 반응 표면법은 Minitab을 사용하였다. 연구결과 냉매로는 methane (C1), ethane (C2), propane (C3)과 nitrogen (N2)가 선택되었으며 에너지 소비를 최소화하는 혼합비(몰 비) 또한 구할 수 있었다. A mixed refrigerant cycle (MRC) has been widely used in liquefaction of natural gas because it is simple and easily operable with reasonable equipment costs. One of the important techniques in MRC is selection of a refrigerant mixture and decision of its optimum mixing ratio. In this work, it is examined whether mixture components (refrigerants) and their mixing ratio influence performance of general MRC processes. In doing this, mixture design and response surface method, which are well-known statistical techniques, are used to find optimal mixture refrigerants and their optimal mixing ratio that minimize total energy consumption of the entire liquefaction process. A MRC process using several refrigerants and various mixing ratios is simulated by Aspen HYSYS and mixture design and response surface method are implemented using Minitab. According to the results, methane (C1), ethane (C2), propane (C3) and nitrogen (N2) are selected as best mixture refrigerants and the determined mixture ratio (mole ration) can reduce total energy consumption by up to 50%.
오승택(Seung-taek Oh),이호생(Ho-saeng Lee),이경범(Gyeong-Beom Yi),윤정인(Jung-in Yoon),이상규(Sang-gyu Lee) 대한설비공학회 2009 대한설비공학회 학술발표대회논문집 Vol.2009 No.-
In this paper, two different types of natural gas liquefaction process are simulated and designed for secure a competitiveness in the industry of natural gas liquefaction plant. These processes are based on basic cascade process, and one of these is improved with two staged intercooler and the other is modified two staged intercooler. These processes are compared characteristics of performance with basic process. COP of cascade process with two staged intercooler and modified two staged intercooler showed about 13.74% and 21.64% higher than basic process, and yield efficiency of modified process improved comparing with the basic process by 25.93% lower specific power, respectively.