솔-젤법에 의한 $SiO_2-ZrO_2$계 무반사 박막의 제조

김병호,홍권,남궁장,Kim, Byong-Ho,Hong, Kwon,Namkung, Jang 한국세라믹학회 1995 한국세라믹학회지 Vol.32 No.5

In order to reduce reflectance of soda-lime glass having average reflectance of 7.35% and refractive index of 1.53, single (SiO2), double (SiO2/20SiO2-80ZrO2), and triple (SiO2/ZrO2/75SiO2-25ZrO2) layers were designed and fabricated on the glass substrate by Sol-Gel method. Stble sols of SiO2-ZrO2 binary system for antireflective (AR) coatings were synthesized with tetraethyl orthosilicate (TEOS) and zirconium n-butoxide as precursors and ethylacetoacetate (EAcAc) as a chelating agent in an atmosphere environment. Films were deposited on soda-lime glass at the withdrawal rates of 3~11 cm/min using the prepared polymeric sols by dip-coating and they were heat-treated at 45$0^{\circ}C$ for 10 min to obtain homogeneous, amorphous and crack-free films. In case of SiO2-ZrO2 binary system, refractive index of film increased with an increase of ZrO2 mol%. Designed optical constant of films could be obtained through varying the withdrawal rate. In the visible region (380~780nm), reflectance was measured with UV/VIS/NIR Spectrophotometer. Average reflectances of the prepared single-layer [SiO2 (n=1.46, t=103nm)], double-layer [SiO2 (n=1.46, t=1-4nm)/20SiO2-80ZrO2 (n=1.81, t=82nm)], and triple-layer [SiO2 (n=1.46, t=104nm)/ZrO2 (n=1.90, t=80nm)/75SiO2-25ZrO2 (n=1.61, t=94 nm)] were 4.74%, 0.75% and 0.38%, respectively.

졸-겔 세라믹 코팅에 의한 스테인레스강의 내산화 및 내식성 향상에 관한 연구;(I) 지르코니아 졸의 합성 및 박막의 제조

김병호,홍권,신동원,Kim, Byong-Ho,Hong, Kwon,Shin, Dong-Won 한국세라믹학회 1994 한국세라믹학회지 Vol.31 No.9

Stable zirconia sol was prepared from zirconium butoxide Zr(OC4O9)4 as a precursor and ethylacetoacetate(EAcAc) or diethylene glycol(DEG) as a chelating agent under ambient agent under ambient atmosphere by Sol-Gel process. The sythesized sol was coated on 304 stainless steel substrate by dip coating, thereafter zirconia film could be obtained by heat-treatment at $600^{\circ}C$. The characteristics of coating film were determined by FT-IR, XRD, and ellipsometion peak represented Zr-O-Zr bonding of tetragonal phase was shown at 470cm-1. Crystallization of zirconia gel and film from amorphous state to tetragonal phase started at 40$0^{\circ}C$, and then transformed into monoclinic phase around $700^{\circ}C$. Zirconia film coated on 304 stainless steel substrate showed relatively low porosity of 16% when it was coated with 0.4M zirconia sol and thereafter heat-treated at 80$0^{\circ}C$ and the film was densified continuously up to 90$0^{\circ}C$. The zirconia film of 10 nm thick acted as a protective layer against oxidation up to $700^{\circ}C$.

능성어, Epinephelus septemfasciatus의 번식생물학적 연구 I. HCG 처리에 의한 배란유도

김병호,김경민,이영돈,송춘복,노섬,Kim, Byong-Ho,Kim, Kyong-Min,Lee, Young-Don,Song, Choon Bok,Rho, Sum 한국양식학회 1997 韓國養殖學會誌 Vol.10 No.1

이 실험은 능성어의 친어관리와 종묘생산을 위한 연구의 일환으로 HCG 처리에 의한 난의 성숙과 배란유도를 알아보고자 행하였다. 제주대학교 해양연구소와 한라수산에서 1996년 6월에서 8월에 걸쳐 300-400 g, 1,500-2,000 g, 2,500-4,000 g 되는 능성어를 대상으로 하여 HCG를 500-1,000 IU/kg 체중농도로 2-3회 처리하였다. 이들의 생식소 발달은 일반적인 paraffin 절편법에 의하여 haematoxylin과 eosin으로 비교염색하여 조사하였다. 체중 300-400 g, 1,500-2,000 g, 2,500-3,200 g 되는 능성어에 HCG를 500-1,000 IU/kg 체중농도로 2-3회 처리한 결과 생식소는 난원세포군, 20~$30\mu$m 내외의 어린 난모세포를 가지고 있었다. 그러나 체중 3,400-4,000 g 되는 능성어에 HCG 1,000 IU/kg 농도로 2회 처리한 결과 난경 ~$800\mu$m되는 건강한 난과 퇴행란이 배란되었다. 체중 4,000 g 개체에서 배란된 난수는 4,252개 였으며, 이 중에서 건강한 난은 20.8%, 퇴행란은 79.2%였다. 그리고 생식소내에는 배란 흔적과 함께 난경 ~$50\mu$m전후의 주변인기 난모세포, 20~$30\mu$m의 어린 난모세포들이 차지하고 있다. The experiment was conducted to understand the effect of HCG upon ovulation induction and egg maturation in the sevenband grouper, Epinephelus septemfasciatus, as a part of the research for its resources management and seed production. Three different size groups of sevenband groupers showing 300~400g, 1,500~2,000g and 2,500~4,000g, were collected from June to August, 1996. They were treated two or three times with HCG (500~1,000 IU/kg). Gonadal development of the sevenband groupers were examined using the paraffin section method and then stained with haematoxylin and eosin. When smaller groups of sevenband grouper having 300~400g, 1,500~2,00g and 2,500~3,200g in weight were treated two or three time with HCG 9500~1,000 IU/g), their gonads contained oogonia, oocytes with the size of 20~30${\mu}{\textrm}{m}$, and stroma tissues. However, in case of two HCG treatments with a dosage of 1,000 IU/kg on sevenband groupers of 3,400~4,000g, both healthy eggs of $800\mu$m in diameter and regressing eggs were ovulated. A sevenband grouper of 4,000g obvulated 4,252 eggs in total. Of these, healthy and regressing eggs turned out to be 20.8% and 79.2%, respectively. In addition, previtellogenic oocytes of around $50\mu$m, oocytes of 20~$30\mu$m, and ovulation trace were also observed in the gonad.

축력과 반복수평력을 받는 콘크리트 충전 내진 각형강관 기둥의 휨거동 특성

김병호,심현주,최병정,이은택,Kim, Byung-Ho,Shim, Hyun-Ju,Choi, Byong-Jeong,Lee, Eun-Taik 한국강구조학회 2011 韓國鋼構造學會 論文集 Vol.23 No.3

최근 CFT(Concrete Filled Steel Tube) 부재는 뛰어난 구조성능으로 인하여 그 사용범위가 확대되고 있다. 본 연구에서는 축력과 반복수평력을 받는 콘크리트 충전 내진 각형강관 기둥의 연성을 평가하는 실험을 수행하였다. 내진 각형강관은 SN400B 후판재를 냉간 프레스 성형하여 2개의 ㄷ자로 절곡한 후 기둥 폭의 중앙에서 2-seam 용접하는 방식으로 제작하였다. 강관의 폭두께비, 축력비, 가력방법을 변수로 총 8개의 실험체를 제작하여 실험을 수행하였고, 축하중과 반복수평력을 가력하기 위하여 2대의 액츄에이터가 사용되었다. 실험결과를 통해 기둥의 휨내력, 변형능력 및 에너지소산능력을 평가하였으며, 반복수평력에 대한 기둥의 연성거동 또한 평가되었다. Today there is a growing range of applications for Concrete-Filled Steel Tube (CFT) member because of its superior performance. Ductility estimation test of concrete-filled seismic resistant steel tubular columns, subjected to axial and cyclic lateral load, was carried out in this study. Seismic resistant steel tubes are manufactured using SN400B plates by a two-seam welding at center of the column width for cold press-formed shape plates of two pieces. A total of eight specimens were manufactured and tested with the parameters of width-thickness ratio of steel tubular column, axial load ratio, and loading conditions to act axial and cyclic lateral load two dynamic actuators were used. From test results, flexural strength, deformation capacity, energy dissipation capacity, and ductility behavior of columns were analyzed.

鹽基性炭酸알루미늄 알칼리金屬 化合物의 合成

김병호,Byong Ho Kim 대한화학회 1977 대한화학회지 Vol.21 No.1

알루민산나트륨과 알루민산칼륨 용액에 $CO_2$가스 吹入法에 의해 $NaAlCO_3(OH)_2\;(Dawsonite)와\;KAlCO_3(OH)_2$를 合成하였다. 이 反應은 80 ∼ $90^{\circ}C$에서 $Na_2O/Al_2O_3,\;K_2O/Al_2O_3$의 몰比가 各 各 6∼8, 8∼10인 알루민산알칼리 용액중에 $CO_2$가스를 吹?하여 達成되었다. 알루민산알칼리 용액중에 $HCO_3^-$이 多量 存在하며 알루미나가 平衡固相으로서 Boehmite로 存在할 때 高純度의 Dawsonate와 $KAlCO_3(OH)_2$가 生成된다는 것을 알았다. 이런 條件下에서 合成된 Dawsonite와 $KAlCO_3(OH)_2$의 示性式은 赤外線吸收스펙트럼 分析結果 各各 $NaAlO(OH)HCO_3와\;KAlO(OH)HCO_3$로 나타내는 것이 妥當하다고 생각된다. 또 電子顯微鏡觀察로부터 Dawsonite는 纖維狀結晶, $KAlCO_3(OH)_2$는 針狀結晶으로 되어 있다는 것을 알았다. A method of synthesizing $NaAlCO_3(OH)_2$ (Dawsonite) and $KAlCO_3(OH)_2$, was investigated by blowing $CO_2$ gas into sodium and potassium aluminate solutions. The reactions were accomplished at a temperature of 80 to $90^{\circ}C$, while $CO_2$ gas was blowing into the solutions which the molar ratios of $Na_2O/Al_2O_3,\;and\;K_2O/Al_2O_3$ were 6 to 8 and 8 to 10, respectively. It was observed that highly purified Dawsonite and $KAlCO_3(OH)_2$ are produced when Alumina is present in Boehmite at an equilibrium solid phase with a large amount of $HCO_3^-$ in the solutions. The rational formulas of Dawsonite and $KAlCO_3(OH)_2$synthesized under the conditions should be expressed as $NaAlO(OH)HCO_3\;and\;KAlO(OH)HCO_3$, respectively, by IR analysis. In addition, electron microscopic observation also indicated that Dawsonite in a fibrous crystal and $KAlCO_3(OH)_2$ in a needleshaped crystal.

졸-겔법에 의한 강유전성 PZT 박막의 제조;(I) 킬레이팅 에이전트를 이용한 안정화 PZT 졸의 합성 및 박막의 제조

김병호,홍권,조홍연,Kim, Byong-Ho,Hong, Kwon,Cho, Hong-Yeon 한국세라믹학회 1994 한국세라믹학회지 Vol.31 No.7

Stable PZT coating sol was prepared using chelating agent, ethylacetoacetate(EAcAc) by sol-gel processing under ambient atmosphere. Through FT-IR spectrum analysis on solution of each reaction step, formation of metal complex was confirmed and prepared PZT sol was stable over several months. Through TG-DTA, XRD, FT-IR spetrum analysis of PZT gel powder, it was understood that the addition of EAcAc could reduce the transition temperature to ferroelectric phase, due to the increased homogeneity by matching the hydrolysis and condensation rates by chelation. Single perovskite phase was obtained by the heat-treatment at 54$0^{\circ}C$ for 30 min. The film was coated on ITO-coated glass substrate by dip coating method. After heat-treatment, PZT thin film had thickness in the range of 20~130 nm. The maximum dielectric constant of its thin film at room temperature and 1 kHz was 128.

[展望] 自動車用 뉴세라믹스의 開發動向

김병호(Byong Ho Kim) 한국자동차공학회 1987 오토저널 Vol.9 No.4

농수산물 유통정보망 발전에 관한 연구

김병호 ( Byong Ho Kim ) 한국축산경영학회 1988 韓國畜産經營學會誌 Vol.4 No.1

능성어, Epinephelus septemfasciatus의 번식생물학적 연구 Ⅰ. HCG 처리에 의한 배란유도

김병호(Byong-Ho Kim),김경민(Kyong-Min Kim),이영돈(Young-Don Lee),송춘복(Choon Bok Song),노섬(Sum Rho) 한국수산과학회 양식분과 1997 韓國養殖學會誌 Vol.10 No.1

식품수요분석에서 소비자 표준 단위에 관한 고찰

김병호 ( Byong Ho Kim ) 건국대학교 동화와번역연구소(구 건국대학교 중원인문연구소) 1988 동화와 번역 Vol.7 No.-