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Hydroxyethyl Methacrylate와 Methyl Methacrylate의 첨가량 변화가 수분산 폴리우레탄-아크릴 혼성 용액의 물성에 미치는 영향
김병석 ( Byung Suk Kim ),유병원 ( Byung Won Yoo ),이명구 ( Myung Goo Lee ),변태강 ( Tae Gang Byun ),송기창 ( Ki Chang Song ) 한국화학공학회 2012 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.50 No.4
Waterborne polyurethane dispersions (PUD) were synthesized from isophorone diisocyanate (IPDI), polycarbonate diol (PCD) and dimethylol propionic acid (DMPA) as starting materials. Subsequently, waterborne polyurethane- acrylic hybrid solutions were prepared by reacting the PUD with different amounts of the mixture of acrylate monomers, HEMA (2-hydroxyethyl methacrylate) and MMA (methyl methacrylate). As a result, the average particle size of waterborne polyurethane-acrylic hybrid solutions was increased with increasing the addition amounts of acrylate monomers. Also, the prepared coating films from waterborne polyurethane-acrylic hybrid solutions showed better abrasion resistance and chemical resistance than those of pure PUD.
Aminopropyl Triethoxysilane과 아크릴 단량체를 이용한 Silylated Acrylic Polyurethane Dispersion의 제조
김병석 ( Byung Suk Kim ),윤동구 ( Dong Gu Yun ),유병원 ( Byung Won Yoo ),이명구 ( Myung Goo Lee ),변태강 ( Tae Gang Byun ),송기창 ( Ki Chang Song ) 한국화학공학회 2012 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.50 No.4
Waterborne polyurethane dispersion (PUD) was synthesized by capping the NCO groups of polyurethane prepolymers, prepared from isophorone diisocyanate, polycarbonate diol and dimethylol propionic acid, with aminopropyl triethoxysilane (APS), Subsequently, silylated acrylic polyurethane dispersion was synthesized by reacting the PUD with the mixture of acrylate monomers, 2-hydroxyethyl methacrylate and methyl methacrylate, The average particle size of silylated acrylic polyurethane dispersion, measured by the dynamic light scattering method, was increased from 39.0 nm to 399.8 nm by increasing the addition amounts of APS. Also, the pencil hardness of coating films of silylated acrylic polyurethane dispersion was enhanced from B grade to F grade with increasing APS content.