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A PHOTOCHEMICAL REACTION OF DECABORANE WITH TRIMETHYLSILYLDIAZOMETHANE
Sung, Dae-Dong,Kim, Chang-Soo,Lee, Jae-Duck,Lim, Gui-Taek,Uhm, Tae-Seop,Park, Yong Tae Korean Society of Photoscience 1994 Journal of Photosciences Vol.1 No.2
The reaction of decaborane with trimethylsilyldiazomethane gives 1, 2-bis (trimethylsilyl)-1, 2-carba-closo-dodecaborane(12). This compound is similar to the icosahedral cage structure of o-carborane. This formation of the first adduct proceeds through deprotonation of the acidic center of B(9) and B(6) by intermolecular attack by the lone electron pair of the carbene, : CHSiMe$_3$. The yield of product is influenced by irradiation and thermal conditions.