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        Carbon Paper-Supported NiCo/C–N Catalysts Synthesized by Directly Pyrolyzing NiCo-Doped Polyaniline for Oxygen Reduction Reaction

        Zhongliang Deng,Qingfeng Yi,Yuanyuan Zhang,Huidong Nie,Guang Li,Liang Yu,Xiulin Zhou 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.1

        In this study, we report the findings that the C–N composites containing Ni and Co (Ni1Co1/C–N, Ni3Co1/C–N, Ni6Co1/C–N, Ni9Co1/C–N, Ni10Co0/C–N and Ni0Co10/C–N) can be produced by direct pyrolysis of the NiCo-doped polyaniline (PANI) precursors in N2 atmosphere at 800 ℃ and show efficient electroactivity for oxygen reduction reaction (ORR) in alkaline media. Distribution and compositions of the catalysts were characterized by SEM, TEM, EDS and XRD techniques. The catalysts were loaded on carbon paper to prepare gas diffusion electrodes, in which electrocatalytic activity for ORR in alkaline media was investigated by voltammetric techniques. The ORR current density on these carbon paper-supported NiCo/C–N catalysts exhibits a linear increase with the negative shift of ORR potential. The ORR onset potential is around 0.2 V (versus Ag/AgCl) in alkaline media. Among the prepared catalysts, the catalyst Ni6Co1/C–N presents the largest ORR current density, which is 68.5 mA cm -2@-0.8 V (versus Ag/AgCl) in alkaline media. Moreover, Ni6Co1/C–N catalyst also presents good electrocatalytic activity stability for ORR.

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        Fabrication and application of silicalite-1 and TS-1 hollow fibers with polyethylene imine (PEI) fibers as substrates

        Zhongliang Sun,Yongming Zhang,Xiangyun Deng,Jianbao Li,Chunrong Xiong 한국공업화학회 2012 Journal of Industrial and Engineering Chemistry Vol.18 No.1

        Silicalite-1 and titanium containing silicalite-1 (TS-1) hollow fibers were fabricated with polyethylene imine (PEI) fibers as substrates. The acid treated PEI fibers were positively charged and can be effectively coated with silicalite-1 or TS-1 nanocrystals from their colloidal solution. The adsorbed silicalite-1 or TS-1 nanocrystals grew up and became more compact upon two days of vapor phase Ostwald ripening in autoclave. Silicalite-1 and TS-1 hollow fibers were obtained after calcination at 400 8C in air. The shell thickness of the hollow fibers is 1 mm. Hydroxylation of phenol with H2O2 was investigated over TS-1based catalysts in order to compare influences of nanocrystals composed macrostructure and Al2O3binder on the catalytic activities.

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        A Hybrid of Smartphone Camera and Basestation Wide-area Indoor Positioning Method

        ( Jichao Jiao ),( Zhongliang Deng ),( Lianming Xu ),( Fei Li ) 한국인터넷정보학회 2016 KSII Transactions on Internet and Information Syst Vol.10 No.2

        Indoor positioning is considered an enabler for a variety of applications, the demand for an indoor positioning service has also been accelerated. That is because that people spend most of their time indoor environment. Meanwhile, the smartphone integrated powerful camera is an efficient platform for navigation and positioning. However, for high accuracy indoor positioning by using a smartphone, there are two constraints that includes: (1) limited computational and memory resources of smartphone; (2) users` moving in large buildings. To address those issues, this paper uses the TC-OFDM for calculating the coarse positioning information includes horizontal and altitude information for assisting smartphone camera-based positioning. Moreover, a unified representation model of image features under variety of scenarios whose name is FAST-SURF is established for computing the fine location. Finally, an optimization marginalized particle filter is proposed for fusing the positioning information from TC-OFDM and images. The experimental result shows that the wide location detection accuracy is 0.823 m (1σ) at horizontal and 0.5 m at vertical. Comparing to the WiFi-based and ibeacon-based positioning methods, our method is powerful while being easy to be deployed and optimized.

      • Fe<sub>3</sub>O<sub>4</sub> magnetic nanoparticles provide a novel alternative strategy for Staphylococcus aureus bone infection

        Youliang, Ren,Jin, Yang,Jinghui, Zhang,Xiao, Yang,Lei, Shi,Dajing, Guo,Yuanyi, Zheng,Haitao, Ran,Zhongliang, Deng,Lei, Chu Techno-Press 2022 Advances in nano research Vol.13 No.6

        Due to its biofilm formation and colonization of the osteocyte-lacuno canalicular network (OLCN), Staphylococcus aureus (S.aureus) implant-associated bone infection (SIABI) is difficult to cure thoroughly, and may occur recurrently subsequently after a long period dormant. It is essential to explore an alternative therapeutic strategy that can eradicate the pathogens in the infected foci. To address this, the polymethylmethacrylate (PMMA) bone cement and Fe3O4 nanoparticles compound cylinder were developed as implants based on their size and mechanical properties for the alternative magnetic field (AMF) induced thermal ablation, The PMMA mixed with optimized 2% Fe<sub>3</sub>O<sub>4</sub> nanoparticles showed an excellent antibacterial efficacy in vitro. It was evaluated by the CFU, CT scan and histopathological staining on a rabbit 1-stage transtibial screw model. The results showed that on week 7, the CFU of infected soft tissue and implants, and the white blood cells (WBCs) of the PMMA+2% Fe<sub>3</sub>O<sub>4</sub>+AMF group decreased significantly from their controls (p<0.05). PMMA+2% Fe<sub>3</sub>O<sub>4</sub>+AMF group did not observe bone resorption, periosteal reaction, and infectious reactive bone formation by CT images. Further histopathological H&E and Gram Staining confirmed there was no obvious inflammatory cell infiltration, neither pathogens residue nor noticeably burn damage around the infected screw channel in the PMMA+2% Fe<sub>3</sub>O<sub>4</sub>+AMF group. Further investigation of nanoparticle distributions in bone marrow medullary and vital organs of heart, liver, spleen, lung, and kidney. There were no significantly extra Fe<sub>3</sub>O<sub>4</sub> nanoparticles were observed in the medullary cavity and all vital organs either. In the current study, PMMA+2% Fe<sub>3</sub>O<sub>4</sub>+AMF shows promising therapeutic potential for SIABI by providing excellent mechanical support, and promising efficacy of eradicating the residual pathogenic bacteria in bone infected lesions.

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