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진영읍,Sun Hee Kim,Hyojin Lee,송수희,Yunna Kim,우한영,이광희,서홍석 대한화학회 2007 Bulletin of the Korean Chemical Society Vol.28 No.12
New poly(cyclopenta[def]phenanthrene) (PCPP)-based conjugated copolymers, containing carbazole units as pendants, were prepared as the electroluminescent (EL) layer in light-emitting diodes (LEDs) to show that most of them have higher maximum brightness and EL efficiency. The prepared polymers, Poly(2,6-(4-(6-(N-carbazolyl)-hexyl)-4-octyl-4H-cyclopenta[def]phenanthrene)) (CzPCPP10) and Poly(2,6-(4-(6-(N-carbazolyl)-hexyl)-4-octyl-4H-cyclopenta[def]phenanthrene))-co-(2,6-(4,4-dioctyl-4H-cyclopenta[def]phenanthrene)) (CzPCPP7 and CzPCPP5), were soluble in common organic solvents and used as the EL layer in light-emitting diodes (LEDs) of configuration with ITO/PEDOT/polymer/Ca/Al device. The polymers are thermally stable with glass transition temperature (Tg) at 77-100 C and decomposition temperature (Td) at 423-457 C. The studies of cyclic voltammetry indicated same HOME levels in all polymers, although the ratios of carbazole units are different. In case of PLEDs with configuration of ITO/PEDOT/CzPCPPs/Ca/Al device, The EL maximum peaks were around 450 nm, which the turn-on voltages were about 6.0-6.5 V. The maximum luminescence of PLEDs using CzPCPP10 was over 4400 cd/m2 at 6.5 V, which all of the maximum EL efficiency were 0.12 cd/A. The CIE coordinates of the EL spectrum of PLEDs using CzPCPP10 was (0.18, 0.08), which are quite close to that of the standard blue (0.14, 0.08) of NTSC.
비닐렌기에 플루오르기를 도입한 m-SiP-PPDFV의 합성과 색 안정성에 대한 물성
진영읍,서홍석,Jin, Young-Eup,Suh, Hong-Suk 대한화학회 2010 대한화학회지 Vol.54 No.6
비닐렌기에 플루오르 치환기를 도입한 새로운 전자발광 (EL) 고분자인 poly(m-silylphenyl-p-phenylene-difluorovinylene) (m-SiP-PPDFV)는 GILCH polymerization 방법에 의해 합성된다. 이들 고분자는 단층 구조 (ITO/PEDOT/polymer/Ca:Al)의 light-emitting diodes (LEDs)에서 EL 발광층으로 사용되었다. m-SiP-PPDFV는 $\lambda_{max}$ = 452 nm 주위에서 PL 발광파장을 나타내었고, $\lambda_{max}$ = 497 nm 주위에서 녹색의 EL 발광을 나타내었다. 고분자의 current-voltage-luminance (I-V-L) 특성에서는 4.0 V 정도에서부터 소자가 작동되기 시작하였다. 고분자의 전자 친화도를 증가시키는 m-SiP-PPDFV을 얻기 위해 m-SiP-PPV의 모든 비닐렌기에 두개의 플루오르기를 도입하였고, 이로 인하여 소자 구동에서 비닐렌기의 색 안정도를 나타냈었다. PPV 유도체들에서 일어나는 비닐렌기의 산화반응을 보호하는 플루오르기는 전자 끄는 효과를 가지고 있어 소자의 색 안정도를 유지시킨다. 이번 연구로, 보다 안정화된 PPV 유도체를 얻기 위해, 플루오르기가 비닐렌기에 도입될 수 있음을 보여주고 있다. New electroluminescent polymers with fluoro groups in vinylene units, poly(m-silylphenyl-p-phenylene-difluorovinylene) (m-SiP-PPDFV) have been synthesized by GILCH polymerization. These polymers have been used as the electroluminescent (EL) layers in single layer light-emitting diodes (LEDs) (ITO/PEDOT/polymer/Ca:Al). m-SiP-PPDFV shows PL around $\lambda_{max}$ = 452 nm and green EL around $\lambda_{max}$ = 497 nm. The current-voltage-luminance (I-V-L) characteristics of the polymers show turn-on voltages of 4.0 V approximately. Two fluoro groups were introduced on every vinylene units of m-SiP-PPV to give m-SiP-PPDFV in an attempt to increase the electron affinity of the parent polymer, and the devices show an increased color stability even with vinylene units. The color stability is attributed to the electron-withdrawing effect of the fluoro groups, which protect vinylene units from oxidation in PPV derivatives. We believe that fluoro groups can be introduced in vinylene units in order to attain excellent stability of PPV derivatives.
Quenching of Water Soluble Conjugated Polymer by Electrostatic Interaction
진영읍 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.11
The water-soluble conjugated polymer with fluorescence quenching as a result of electrostatic interaction and aggregation was synthesized through Suzuki polymerization. The absorption and emission of anionic polymer (a-PFP) is blue shifted as compared with cationic polymer (c-PFP) although getting same backbone, and the absolute PL quantum efficiency of a-PFP in water is over 90% due to good solubility in aqueous solution. We anticipate that the fluorescence quenching of anionic and cationic polymers, with same conjugated backbone, could be shown in aqueous solution.
진영읍,우한영,이광희,서홍석,Jeung Hee Kang,송수희,Sung Heum Park,Jihyun Moon 대한화학회 2008 Bulletin of the Korean Chemical Society Vol.29 No.1
New PPV derivatives which contain electron-withdrawing CF3F4phenyl group, poly[2-(2-ethylhexyloxy)-5-(2,3,5,6-tetrafluoro-4-trifluoromethylphenyl)-1,4-phenylenevinylene] (CF3F4P-PPV), and poly[2-(4-(2-etylhexyloxy)-phenyl)-5-(2,3,5,6-tetrafluoro-4-trifluoromethylphenyl)-1,4-phenylenevinylene] (P-CF3F4P-PPV), have been synthesized by GILCH polymerization. As the result of the introduction of the electron-withdrawing CF3F4phenyl group to the phenyl backbone, the LUMO and HOMO energy levels of CF3F4P-PPV (3.14, 5.50 eV) and P-CF3F4P-PPV (3.07, 5.60 eV) were reduced. The PL emission spectra in solid thin film are more red-shifted over 50 nm and increased fwhm (full width at half maximum) than solution conditions by raising aggregation among polymer backbone due to electron withdrawing effect of 2,3,5,6-tetrafluoro-4-trifluoromethylphenyl group. The EL emission maxima of CF3F4P-PPV and P-CF3F4P-PPV appear at around 530-543 nm. The current density-voltage-luminescence (J-V-L) characteristics of ITO/PEDOT/polymer/Al devices of CF3F4P-PPV and P-CF3F4P-PPV show that turn-on voltages are around 12.5 and 7.0 V, and the maximum brightness are about 82 and 598 cd/m2, respectively. The maximum EL efficiency of P-CF3F4P-PPV (0.51 cd/A) was higher than that of CF3F4P-PPV (0.025 cd/A).