홍천산 모나자이트의 가성소다 분해 및 침출

김준수,윤호성,김성돈,김철주,이진영,Kim Joon-Soo,Yoon Ho-Sung,Kim Sung-Don,Kim Chul-Joo,Lee Jin-Young 한국자원리싸이클링학회 2004 資源 리싸이클링 Vol.13 No.4

본 연구에서는 국내 홍천산 모나자이트 정광의 가성소다 분해 및 분해산물의 염산 침출에 대한 처리조건을 확립하고자 하였다. 분해 반응의 조건은 입자크기의 -200 mesh 이하이면 적절하였고, 반응온도 $460^{\circ}C$부근에서 원활한 분해가 이루어 졌으며, 가성소다 첨가량은 NaOH/TREO mole ratio 6정도가 효과적이다. 또한 침출반응의 조건은 염산농도 8N 및 반응온도 $80^{\circ}C$이상이 침출에 적절하였으며, 반응시간 2시간 및 광액 농도 10%가 효과적이다. 그리고 최적조건하에서 모나자이트의 분해 침출율은 90%이상이였고, 부산물 형태로 인산소다 화합물은 효과적으로 회수하였으며, 희토류 원소별 분리에 적합한 시료용액을 조제하였다. In this study, treatment conditions for monazite concentrate in Hong-Cheon area deposit were studied with NaOH fritting decomposition and HCl leaching experiments. At condition of NaOH fritting decomposition, it was appropriate to adopt particle size of -200 mesh monazite, reaction temperature of about $460^{\circ}C$ and NaOH/TREO mole ratio of 6. In case of HCl leaching for decomposed product, it was appropriate to use hydrochloric acid of above 8N with leaching temperature of above $80^{\circ}C$, leaching time of 2 hrs and pulp density of about 10%. A rate of decomposition and leaching for monazite was above 90% under optimum conditions. Sodium phosphate compound was effectively recovered from NaOH decomposed solution, and mixed rare earth chloride solution was prepared with HCl leaching of decomposed product.

호주산 저품위 동광의 부유선별에 관한 특성조사

김준수,김우진,황하,김명준,김완태,Kim, Joon Soo,Kim, Woo Jin,Hwang, Ha,Kim, Myong Jun,Kim, Wantae 한국자원리싸이클링학회 2016 資源 리싸이클링 Vol.25 No.6

본 연구의 목적은 호주산 저품위 동광을 부유선별하여 정광으로 회수하고자 할 때, 최적의 부유선별 조건을 얻고자 하는데 있다. 본 연구에서는 저품위 동광의 파분쇄 및 분급에 의해 선별에 적절한 입자크기의 시료를 얻은 다음, 이를 대상으로 부유선별 시 포수제, 활성제, 억제제의 첨가량 및 광액의 pH 변화가 부선효율에 미치는 영향을 조사함으로써 품위가 향상된 정광을 얻고자 하였다. 본 연구실험결과 얻은 최적의 부유선별 조건은 광액산도 pH9.0, 활성제 500 g/t $CuSO_4{\cdot}5H_2O$, 포수제 500 g/t K.E.X, 억제제 1500 g/t $Na_2SO_3$, 광액농도는 25 wt.% 이었다. 최적조건하에서 얻은 정광중의 동 품위 및 회수율은 각각 4 wt.%와 65 wt.% 정도이었고 대부분 철 성분을 함유한 광물 이었다. The purpose of this study is to obtain an optimum condition of the concentrate by floatation using Australian low grade copper ore of suitable particle size by crushing, grinding and sizing. The effect of the dosage of collector, activator, depressant and change of acidity on the floatation was investigated. The floatation conditions comprising of pH 9.0 acidity, 500g/t $CuSO_4{\cdot}5H_2O$ activator, 500g/t K.E.X. collector, 1500g/t $Na_2SO_3$ depressant and 25wt.% plup density were optimized. Grade and recovery of copper in the concentrate obtained by froth floatation under optimum conditions were 4wt.% and 65wt.% respectively.

쿠싱병에 대한 경접형동접근법의 내분비학적 결과

김준수,김창진,하상수,김정훈,이정교,권병덕,홍성관,이기업,이봉재,김용재,최충곤,이호규,Kim, Joon Soo,Kim, Chang Jin,Ha, Sang Soo,Kim, Jung Hoon,Lee, Jung Gyo,Kwun, Byung Duk,Hong, Sung Kwan,Lee, Ki Up,Lee, Bong Jae,Kim, Yong Jae,Choi, Choo 대한신경외과학회 2001 Journal of Korean neurosurgical society Vol.30 No.5

Objective : We analyzed the clinical and endocrinological results of the transsphenoidal microsurgery for ACTH secreting pituitary adenomas. Marerials and Methods : From October 1995 to August 2000, 18 patients underwent transsphenoidal microsurgery for Cushing's disease. We analyzed the surgical results of 17 patients, one patient who was previously operated from other hospital was excluded. Age of the patients were 18 to 61 years old(mean 37.7), male to female ratio was 1 : 3.3, and follow-up period was 3 to 50 months(mean 20.3). The selection of candidates for transsphenoidal exploration was based on endocrinologic criteria. Magnetic resonance imaging was the preferred radiologic test. Selective inferior petrosal sinus sampling of adrenocorticotropic hormone futher refined the diagnosis when endocrinologic and radiologic procedures were not definitive. Results : Results of the preoperative endocrinological test were : level of serum ACTH 29.4 to $225{\mu}g/dL$(mean $93.88{\mu}g/dL$) ; serum cortisol 11.9 to $47.5{\mu}g/dL$(mean $27.49{\mu}g/dL$) ; 24-hour urine free cortisol 235 to $1019{\mu}g/day$(mean $571.0{\mu}g/day$). Inferior petrosal sinus sampling for ACTH was performed in 11 patients and all were confirmed by Cushing's disease and we could predict the laterality of the tumor in 9 of 11 patients. We performed transsphenoidal selective adenomectomy in 5 patients, adenomectomy and subtotal hypophysectomy in 2 patients, adenomectomy and partial hypophysectomy in 9 patients, and in the remaining one patient, hemihypophysectomy followed by total hypophysectomy due to remission failure. Fifteen of 17 patients(88.2%) showed endocrinological remission. Glucocorticoid replacement therapy was performed in all the patients who showed remission for 1 to 24 months(mean 5.9 months), and 6 patients received steroid over 6 months. Conclusion : We conclude that the direct demonstration of a tumor in the pituitary gland by MRI is the most important and definitive diagnostic tool and the location of a mass should be confirmed with increased level of ACTH by the inferior petrosal sinus sampling. Transsphenoidal microsurgery is effective treatment modality for Cushing's disease and the immediate postoperative evaluation of the surgical resection of the tumor is very important. The patients should show hypocortisolism, decreased, subnormal serum ACTH and cortisol levels and 24-hours urine free cortisol. We performed 18 transsphenoidal microsurgery for Cushing's disease in 17 patients and 15 patients(88.2%) showed endocrinological remission.

선형경제에서 순환경제로의 전환

김준수,전연수,전정혁,조재영,Kim, Joon Soo,Jun, Yun-Su,Jun, Jung Hyuk,Cho, Jai Young 한국자원리싸이클링학회 2021 資源 리싸이클링 Vol.30 No.3

Currently, there is a drain of natural resources, environmental contamination, generation of waste, and problems of the earth's climate by CO₂ emissions according to mass production and overconsumption of mankind. It is effectuated by a linear economy that involves manufacturing products, use, and waste repeatedly; there is no guarantee in the lives of humans and the future of the globe if we do not find alternative proposals. For a sustainable developing society and to overcome the present global problems, we must successively change to a circular economy from a linear economy. The circular economy has the concept of an extended value chain in recovery, reuse, remanufacturing, and recycling, instead of discarding after the use of manufactured goods. New business models of circular economy have been realized to save the earth ecology and sustainable developing society in serious recognition of the linear economy system. New business models are established by creating a vision and developing a program, and by renovating technology, law, and financial support through a worldwide government policy.

펄스 corona 배향된 비선형광학 고분자박막의 제2 고조파발생

김준수,이종하,이황운,김상열,원영희,Kim, Jun-Soo,Lee, Jong-Ha,Lee, Hwang-Un,Kim, Sang-Youl,Won, Young-Hee 한국광학회 2002 한국광학회지 Vol.13 No.4

The molecular orientational dynamics of the nonlinear optical(NLO) side-chain polymer N-(4-nitrophenyl)-(L)-prolinol-poly (pphenylene terephthalates) have been studied using nonlinear optical responses as measured by second harmonic generation (SHG). A new pulsed corona poling is used to orient the NLO chromophores and the polymer segments into the noncentrosymmetric structure required to obtain the SHG signal. By corona poling of negative high voltage pulses with variable repetition rates (between 0.5 and 10 ㎑) at temperature between 25$^{\circ}C$ and 80$^{\circ}C$, well below and about the glass transition temperature 70$^{\circ}C$, the side-chain chromophores and the polymer chain contour rearrange themselves and create the domain structure observed by atomic force microscopy(AFM). The pulsed corona voltage enhances the orientational ordering of the NLO chromophores and also significantly influences the growth of SHG signal and the improved relaxation behavior after the poling field is removed, reducing the visible damage to the polymer film dramatically. This new pulsed corona poling experiment gave direct in situ evidence that the NLO chromophore and the polymer backbone undergo anisotropic rearrangement during the poling process. 비선형광학(NLO) 곁가지형 고분자계 N-(4-nitrophenul)-(L)-prolinol-poly (p-phenylene terephthalates)로 제작된 박막의 분자 배향거동을 제2 고조파발생(SHG)의 비선형광응답을 사용하여 연구하였다. 새로운 펄스 corona 배향 방법으로 NLO 발색단과 고분자 줄기를 비중심대칭 구조로 배향시켜 SHG 신호를 발생시켰다. 유리전이온도 70$^{\circ}C$를 중심으로 25$^{\circ}C$에서 80$^{\circ}C$까지 온도영역에서 반복율을 0.5 ㎑에서 10 ㎑까지 변화시키면서 인가한 펄스 고압으로 corona 배향한 결과로 곁가지 발색단과 고분자 주사슬이 스스로 재 정렬하여 형성한 구역구조를 원자간력 현미경(AFM)으로 관측하였다. 펄스 corona 전압 인가로 NLO 발색단 배향도가 증가되고, 동시에 고분자박막의 가시적손상을 획기적으로 줄이면서 SHG 신호가 증대되었으며 배향 후 이완거동도 개선되었다. 이 새로운 펄스 corona 배향 실험으로 NLO 발색단 및 고분자 주사슬이 배향과정에서 비등방으로 재배열하는 현상을 in situ로 입증할 수 있었다.

정제된 의미정보와 시소러스를 이용한 동형이의어 분별 시스템

김준수,옥철영,Kim Jun-Su,Ock Cheol-Young 한국정보처리학회 2005 정보처리학회논문지B Vol.12 No.7

Word Sense Disambiguation(WSD) is one of the most difficult problem in Korean information processing. We propose a WSD model with the capability to filter semantic information using the specific characteristics in dictionary dictions, and nth added information, useful to sense determination, such as statistical, distance and case information. we propose a model, which can resolve the issues resulting from the scarcity of semantic information data based on the word hierarchy system (thesaurus) developed by Ulsan University's UOU Word Intelligent Network, a dictionary-based toxicological database. Among the WSD models elaborated by this study, the one using statistical information, distance and case information along with the thesaurus (hereinafter referred to as 'SDJ-X model') performed the best. In an experiment conducted on the sense-tagged corpus consisting of 1,500,000 eojeols, provided by the Sejong project, the SDJ-X model recorded improvements over the maximum frequency word sense determination (maximum frequency determination, MFC, accuracy baseline) of $18.87\%$ ($21.73\%$ for nouns and inter-eojeot distance weights by $10.49\%$ ($8.84\%$ for nouns, $11.51\%$ for verbs). Finally, the accuracy level of the SDJ-X model was higher than that recorded by the model using only statistical information, distance and case information, without the thesaurus by a margin of $6.12\%$ ($5.29\%$ for nouns, $6.64\%$ for verbs). 단어 의미 중의성 해소는 자연언어처리 분야에 매우 중요한 부분이다. 본 논문에서는 사전 뜻풀이 특성을 이용해 기존의 의미정보를 정제하고 유용한 정보인 확률정보, 거리정보 및 격정보 등을 추가한 WSD 모델을 제안하였으며, 사전을 기반으로 구축된 "울산대학교 어휘 지능망(UOU-Word Intelligent Network: U-WIN)" 상의 단어 계층적 구조(시소러스)를 이용하여 의미정보의 자료 부족 문제를 해소하는 모델을 제시하였"다. "21세기 세종 계획"에서 제공하는 150만 어절 규모의 의미 태그 말뭉치를 대상으로 한 실험에서 최다 빈도 의미 결정(Maximum Frequence Class, MFC, 정확률 베이스라인)에 비해 $18.97\%$(명사 $21.73\%$, 동사 $17.11\%$) 정확률 향상을 보였으며, 기존의 확률 가중치와 어절 거리 가중치를 이용한 모델에 비해서는 $10.49\%$(명사 $8.84\%$, 동사 $11.51\%$)의 정확률 향상되었다. 또한 시소러스를 사용하지 않고 확률정보, 거리정보, 격정보 만을 이용한 모델에 비해 $6.12\%$(명사 $5.29\%$, 동사 $6.64\%$) 높은 정확률을 보였다.

사용 후 태양광 실리콘 모듈의 리싸이클링

김준수,조재영,이재경,박아름,박진혁,윤현목,전연수,Kim, Joon Soo,Cho, Jae Young,Lee, Jae Kyung,Park, Areum,Park, Jin Hyuk,Yun, Hyun Mok,Jun, Yun-Su 한국자원리싸이클링학회 2019 資源 리싸이클링 Vol.28 No.5

Recently, it is increasing a amount of installized solar-cell rapidly, and waste Solar cell module are generated in according to the reduction of efficiency largely. Therefore, it is concerned at the environmental problems and recycling of valuable materials, greatly. The treatment processes of end-of-life photovoltaic modules are composed the disassembly of Aluminum frames, separation of Tempered glass, removal of Ethylene Vinyl Acetate and recovery of valuable Metals. For the efficient recycling, we are considered to the treatment technology seriously. And we are proposed on the general opinions according to the developing technology, EPR (Extended Producer Responsibility) problems and promotion plans for the activation of recycling industry.

대구시 자생 모감주나무군락의 종조성, 구조 및 동태

김준수,조준희,김학윤,조현제,Kim, Jun-Soo,Cho, Joon-Hee,Kim, Hak-Yun,Cho, Hyun-Je 한국산림과학회 2019 한국산림과학회지 Vol.108 No.2

대구광역시에 자생하고 있는 모감주나무군락의 종조성과 구조 그리고 개체군 동태를 파악하기 위하여 2018년 7월에 자생 임분 3곳을 선정하여 식물사회학적 식생조사와 매목조사를 실시하였다. 야외에서 수집된 식생 및 매목조사 정보를 바탕으로 종조성에 의한 군락 유형을 구분하고 그 유형별 계층구조, 구성 종의 상대 중요치, 생활형 조성, 종다양성, 그리고 개체군 구조 등을 분석, 비교하였다. 군락 유형은 참느릅나무-좀목형아군락, 광대싸리아군락, 그리고 사위질빵군락 등 3개 유형이 구분되고 그 식생단위체계는 1개 군락군, 2개 군락, 그리고 2개 아군락으로 정리되었다. 계층구조는 교목층의 높은 식피율(85% 이상)에 비하여 초본층은 10%이하로 매우 낮은 경향이었다. 구성종의 상대중요치(MIV)는 교목층 94.3, 아교목층 81.6, 관목층 75.5, 그리고 초본층 60.0으로 모든 식생 층위에서 모감주나무가 절대적으로 높게 나타났다. 종다양도(H')는 군락 유형 간 큰 차이가 있었는데 사위질빵군락(2.062)이 광대싸리아군락(0.547)에 비해 약 4배정도 높게 나타났다. 생활형 조성의 중심체계(휴면형-지하기관형-산포기관형-생육형)는 전체적으로 '$MM-R_5-D_4{\cdot}D_2-e$'로 나타났으나 군락 유형 간에는 산포기관형에 있어서 다소 차이를 보였다. 모감주나무군락의 개체군 구조는 3개 군락 유형에서 모두 어린 개체의 밀도가 높고 크기가 큰 개체의 밀도가 낮은 역J자형의 모양을 나타내고 현재의 하층식생을 구성하고 있는 식물 중 모감주나무 개체군을 대체할 만한 식물종이 없으므로 지속적 유지가 가능한 개체군으로 판단되었다. To understand the floristic composition, vegetation structure, and population dynamics of Koelreuteria paniculata communities, which are native to Daegu, South Korea, a field survey was conducted in July 2018 using phytosociological and complete enumeration methods. Based on information on vegetation and trees of >5 cm diameter at breast height collected during the field survey, we classified the community types by species composition and analyzed their vegetation strata, relative importance value (MIV), life forms, species diversity, and population structure. The community was divided into the following three types: Ulmus parvifolia-Vitex negundo var. incisa subcommunity, Securinega suffruticosa subcommunity, and Clematis apiifolia community. The vegetation unit system was organized into one community group, two communities, and two subcommunities. Vegetation coverage of the tree layer was >85%, while the herbaceous layer was <10%. MIV of K. paniculata appeared to be extremely high within all vegetation strata, with 94.3 of the tree layer, 81.6 of the subtree layer, 75.5 of the shrub layer, and 60.0 of the herbaceous layer. The species diversity (H') was significantly different among the community types, and the C. apiifolia community (2.062) was approximately four times higher than the S. suffruticosa subcommunity (0.547). The overall representative life form types were "$MM-R_5-D_4{\cdot}D_2-e$,", but there were some differences in the disseminule form among the community types. The population structure of K. paniculata showed the reverse J-shaped distribution with a high density of young individuals and low density of larger individuals among all three community types, and because no plant species within the lower vegetation could replace K. paniculata, it was considered to be a sustainable population.

선박추진기용 로프절단장치의 구조 안정성 및 효용성에 관한 연구

김준수,설영윤,이두용,박기태,김태훈,최재혁,이원주,Kim, Jun-Soo,Seul, Youngyoon,Lee, Du-Yong,Park, Kitae,Kim, Tae Hun,Choi, Jae-Hyuk,Lee, Won-Ju 해양환경안전학회 2021 해양환경안전학회지 Vol.27 No.4

본 연구에서는 상용화된 로프절단장치 타입 중 국내에 가장 많이 도입되어있는 Scissor type을 대상으로 유한요소해석을 수행하여 다양한 로프 걸림 상황에서 안정성이 확보되는 적합한 구조 형태를 평가하였으며, 수조 실험 및 실선 실험을 통해 효용성을 검증하였다. 연구 결과, 로프 걸림에 의하여 프로펠러축이 회전하지 않을 경우 엔진에서 발생하는 지속적인 토크로 인하여 로프절단장치에 비틀림이 발생하고 유한요소 해석상 자유도가 구속되어 있지 않은 하부의 블레이드에서 가장 높은 변형이 발생하는 것을 확인하였다. 블레이드의 두께가 증가할수록 최대변형량은 줄어들고 최대응력은 낮아져 안전율이 증가하는 결과가 나타났으며, 동일한 블레이드 두께에서 토크의 변화량이 최대응력과 최대변형량에 미치는 영향은 로프절단장치의 외력이 미치는 위치와 무관하며 정비례하게 감소하는 것으로 나타났다. 해석 결과를 토대로 실시한 수조실험 및 실선실험 결과, 모든 조건과 환경에서 로프 및 어망이 원활하게 제거되는 것을 확인하였다. The scissor-type rope cutter is the most widely used amongst all kinds of commercially available rope cutters in Korea. In this study, we performed finite element analysis on the scissor-type rope cutter. We determined the structure of the cutter that would ensure its stable operation in various situations involving rope entanglement, and verified its effectiveness by testing it in the lab and in an actual ship. These investigations revealed that when the propeller shaft was not rotated by rope entanglement, the constant torque generated by the engine resulted in the torsion of the rope cutter and maximum deformation in the lower blade, which was not restricted by finite element analysis. With increasing blade thickness, the maximum values of deformation and equivalent stress decreased, resulting in a rise in the safety factor. At the constant blade thickness, the effect of the torque variations on the maximum equivalent stress and the maximum deformation is independent of the position of the external force of the rope cutter and decreases in direct proportion. The results of this study confirmed that the rope-cutter structure determined by analysis could lead to a hassle-free removal of ropes and fishing nets under all conditions and environments.

지식관리시스템 구축 기술 요소

김준수,Kim, Jun-Su 한국데이터베이스진흥원 1999 디지털콘텐츠 Vol.9 No.-

지식관리시스템은 2000년까지 2억명 이상의 화이트컬러 및 근로자들에 의해 사용되어 질 것이라 전망되고 있으며 기업들은 성공적인 지식관리시스템 구축에 심혈을 기울이고 있다. 많은 사례들에 볼 수 있듯이 지식관리시스템은 단순히 정보기술에 집중한 시스템이 아니다. 하지만 이 글에서는 지식관리시스템에서 중요한 역할을 담당하는 정보기술 요소에 대해 살펴본다.