가연성 액체 혼합물의 인화 위험성에 관한 연구

김주석,고재선,Kim, Ju Suk,Koh, Jae Sun 한국재난정보학회 2020 한국재난정보학회 논문집 Vol.16 No.4

연구목적: 본 연구에서는 두 물질의 혼합물(가연물+가연물)에서의 인화 위험성의 증가 또는 감소를 실험적으로 확인하고, 혼합물의 위험성을 제시하는 목적이 있기에 액체 혼합물의 인화 위험성을 실험적으로 확인하였다. 연구방법:인화점 실험방법 및 결과처리는 원유 및 석유 제품 인화점 시험 방법으로 사용되고 있는 테그밀폐식 시험방법인 KS M 2010-2008을 기준으로 실험하였다. 본 실험에 사용한 장비의 제조사는 일본의 TANAKA사에서 생산한 장비로 KS M 2010의 시험규격을 만족하는 시험장비로 인화점을 측정하였고, 점화원으로는 LP가스를, 냉각수로는 물을 사용하였다. 또한 인화점 측정시 냉각수의 온도는 약 2℃의 냉각수를 사용하여 실험을 진행하였다. 연구결과:실험결과로는 먼저 가연성+가연성 혼합물의 경우 두 물질의 인화점 차이가 크지 않으면 인화점의 변화가 거의 없었고, 두 물질의 인화점 차이가 낮으면 인화점이 높은 물질의 증가에 따라 인화점이 증가하는 경향을 보였으나, 톨루엔과 메탄올의 경우, 혼합물에서 인화점이 낮은 물질보다 더 낮은 인화점을 보였다. 또한 도료용 희석제의 경우, 혼합물로 이루어져서 그 물질의 인화점을 예상하기가 쉽지 않았지만 실험적으로 측정해 본 결과 -24℃~7℃사이로 측정되었다. 결론: 본 연구에서의 결과는 기존의 위험물안전관리법에서의 위험물 판정 기준에 대한 세부 내용의 실효성 확보 및 위험물 판정의 신뢰성 및 재현성 확보를 목적으로 인화성 혼합물에 대한 실험적 연구를 통해서 혼합물에 대한 위험성 판단 기준을 제시하였고, 향후 소방현장에서 단속되는 인화성 액체 대한 실험적 판정 기준에 대한 참고적인 자료를 제공할 수 있을 것이다. 또한 본 연구로 시험방법별 차이 실험에 대한 노하우를 축적한다면 위험물의 위험성 평가 연구에 있어 기초 자료이자 위험물 판정 관한 연구의 기반으로 활용될 수 있기를 기대한다. Purpose: In this study, the risk of flammability of a liquid mixture was experimentally confirmed because the purpose of this study was to confirm the increase or decrease of the flammability risk in a mixture of two substances (combustible+combustible) and to present the risk of the mixture. Method: Flash point test method and result processing were tested based on KS M 2010-2008, a tag sealing test method used as a flash point test method for crude oil and petroleum products. The manufacturer of the equipment used in this experiment was Japan's TANAKA. The flash point was measured with a test equipment that satisfies the test standards of KS M 2010 with equipment produced by the company, and LP gas was used as the ignition source and water as the cooling water. In addition, when measuring the flash point, the temperature of the cooling water was tested using cooling water of about 2℃. Results: First of all, in the case of flammable + combustible mixtures, there was little change in flash point if the flash point difference between the two substances was not large, and if the flash point difference between the two substances was low, the flash point tended to increase as the number of substances with high flash point increased. However, in the case of toluene and methanol, the flash point of the mixture was lower than that of the material with a lower flash point. Also, in the case of a paint thinner, it was not easy to predict the flash point of the material because it was composed of a mixture, but as a result of experimental measurement, it was measured between -24℃ and 7℃. Conclusion: The results of this study are to determine the risk of mixtures through experimental studies on flammable mixtures for the purpose of securing the effectiveness of the details of the criteria for determining dangerous goods in the existing dangerous goods safety management method and securing the reliability and reproducibility of the determination of dangerous goods Criteria have been presented, and reference data on experimental criteria for flammable liquids that are regulated in firefighting sites can be provided. In addition, if this study accumulates know-how on differences in test methods, it is expected that it can be used as a basis for research on risk assessment of dangerous goods and as a basis for research on dangerous goods determination.

바이오디젤 혼합물의 인화 및 연소 위험성에 관한 연구

김주석,고재선,Kim, Ju Suk,Ko, Jae Sun 한국재난정보학회 2021 한국재난정보학회 논문집 Vol.17 No.1

연구목적: 본 연구의 목적은 현재 대체연료로 사용하고 있는 바이오디젤과 일반디젤 혼합물의 위험성을 장비별(태그방식과 펜스키마르텐 방식) 시험방식에 따른 인화점 및 연소점의(밀폐, 오픈) 차이를 비교 분석, 측정함으로서 혼합물의 위험성을 확인하고, 화학물질의 위험성 평방법을 확립하여 화재원인 물질의 감식과 감정에 참고 자료로 활용하고자 함이다. 연구방법: 인화점 실험 방법 및 결과 처리는 원유 및 석유 제품 인화점 및 연소점 시험방법으로 사용되고 있는 테그밀폐식 및 펜스키마텐스식 시험방법인 ASTM 및 KS M mode를 기준으로 실험하였다. 본 실험에 사용한 장비의 제조사는 일본의 TANAKA사에서 생산한 장비로 KS M 2010의 시험규격을 만족하는 시험장비로 인화점 및 연소점을 측정하였고, 바이오디젤과 일반디젤 혼합물의 시험방식에 따른 인화점(밀폐, 오픈) 차이를 확인하고, 바이오디젤과 일반디젤 혼합물의 발화점을 기존의 디젤과의 비교 발화위험성을 비교 분석하였다. 연구결과: 실험결과를 살펴보면 먼저 혼합물의 인화 위험성에 대한 실험 결과 분석으로 인화점이 64.5℃인 일반 디젤을 기준으로 했을 때 바이오디젤이 70% 함유된 물질의 인화점은 약 92℃로 확인되었고, 가솔린과 바이오디젤 또는 바이오디젤 혼합물을 합성했을 때 인화점이 낮아지는 경향을 확인할 수 있었다. 아울러 인화점과 연소점의 차이는 약 20~30℃정도로 분석되었고, 소량의 가솔린 또는 메탄올의 혼합시 인화점은 낮아지나, 연소점은 기존의 혼합물의 연소점과 유사하다는 것을 확인하였다. 결론: 본 연구에서는 기존의 위험물안전관리법렬상의 위험물 판정 기준에 대한 세부내용의 실효성 확보 및 위험물 판정의 신뢰성 및 재현성 확보를 목적으로, 인화성 혼합물에 대한 실험적 연구를 통해서 혼합물에 대한 위험성 판단기준을 확인, 소방현장에서 단속되는 인화성 액체 대한 실험적 판정 기준에 대한 참고적인 자료를 제공할 수 있을 것이다. 또한 향후 본 연구로 시험방법별 실험에 대한 노하우를 축적한다면 위험물의 위험성 평가 연구에 있어 기초 자료이자 위험물 판정에 관한 연구의 기반으로 활용될 수 있기를 기대한다. Purpose: The purpose of this study is to determine the dangers of biodiesel and general diesel mixtures currently used as alternative fuels by equipment (tag method and penski Marten method) and to determine the difference between flash point and combustion point (closed, open) according to test methods. It is intended to be used as a reference material for identification and evaluation of firecausing substances by confirming the risk of mixtures by comparative analysis and measurement, and establishing a risk assessment method for chemical substances. Method: Flash point test method and result treatment were tested based on ASTM and KS M mode, which are tag sealing and pen schematense test methods used as flash point and combustion point test methods for crude oil and petroleum products. The manufacturer of the equipment used in this experiment was a test equipment that satisfies the test standards of KS M 2010 with equipment produced by TANAKA of Japan. The flash point and combustion point were measured, and the flash point according to the test method of biodiesel and general diesel mixture ( Closed, open), and the ignition point of a mixture of biodiesel and general diesel was compared and analyzed for ignition risk compared with conventional diesel. Results: Looking at the experimental results, first, as an analysis of the risk of flammability of the mixture, the flash point of a substance containing 70% biodiesel was found to be about 92℃ based on general diesel with a flash point of 64.5℃, and gasoline and biodiesel or When the biodiesel mixture was synthesized, it was confirmed that the flash point tends to decrease. In addition, the difference between the flash point and the combustion point was analyzed as about 20 ~ 30℃, and when a small amount of gasoline or methanol was mixed, the flash point was lowered, but it was confirmed that the combustion point was similar to that of the existing mixture. Conclusion: In this study, in order to secure the effectiveness of the details of the criteria for judging dangerous materials in the existing Dangerous Materials Safety Management Act, and to secure the reliability and reproducibility of the judgment of dangerous materials, we confirm the criteria for judging the risk of the mixture through an experimental study on flammable mixtures. It will be able to provide reference data for experimental criteria for flammable liquids that are regulated in the field. In addition, if this study accumulates know-how on experiment by test method, it is expected that it can be used as a basis for research on risk assessment and research on dangerous goods.

미래형 우주 마을 설계에 관한 연구

김주석(Ju-Suk Kim),방재훈(Jae Hoon Bang),김인식(In Sik Kim) 한국통신학회 2017 한국통신학회 학술대회논문집 Vol.2017 No.1

하천폭의 국부적 축소 및 확대에 따른 수리특성 연구

최한규(Choi Han Kuy),김주석(Kim Ju Suk),백효선(Baek Hyo Sun) 강원대학교 산업기술연구소 2007 産業技術硏究 Vol.27 No.1

This research investigated the way of generating the flowing of water in case of artificial fluctuation of river width by the unidimensional numerical analysis in order to reconstruct vertical and expanse features of flowing, and the problem of existing numerical analysis in accordance with local enlargement and reduction of river through hydraulic model experiments with results of numerical analysis. The result revealed that when the local section change in the same river is exist, it showed 0.93m in the case of no change of local section in the hydraulic model experiments and numerical analysis, however, it presented 1.645m on the occasion of local section changes in the hydraulic model experiments and numerical analysis, In other words, there was a significant difference in the existing numerical analysis, when there was a local section change. As a result of the experimental section for the enlargement and reduction of local river width, due to the sensitive change for fluctuation of flood discharge, there was a significant difference between numerical analysis and hydraulic model experiments. In addition, the result of comparison between the enlargement and reduction of local river width confirmed that the result of numerical analysis with hydraulic model experiments showed larger generation of deviation in case of enlargement of section than in case of reduction of section.

수리모형과 수치해석을 통한 하천폭의 국부적 축소 및 확대에 따른 수리특성 연구

백효선(Beak Hyo-Sun),김주석(Kim Ju-Suk),백경원(Beak Kyung-Won),최한규(Choi Han-Kuy) 대한토목학회 2007 대한토목학회 학술대회 Vol.2007 No.10

농촌노인의 복지향상을 위한 마을회관의 공간활용방안(2) - 마을회관 대안에 대한 노인의 평가 -

오찬옥,최병숙,박선희,김주석,Oh, Chan-Ohk,Choi, Byung-Sook,Park, Sun-Hee,Kim, Ju-Suk 한국주거학회 2008 한국주거학회 논문집 Vol.19 No.4

The study was intended to suggest the design alternatives and guidelines of village community center as a common living space for the elderly in rural area. First, two design alternatives were derived from the previous research which examined the conditions and old persons' needs of village community center. Then, the design guidelines were proposed on the basis of the previous research and the elderly's evaluation for those two alternatives. The subjects were 85 old residents who were more than 60 years old and lived in rural area in Gyungnam. The interview was carried out using a questionnaire, models, and isometrics of two alternatives. The subjects evaluated positively both of two alternatives. The design guidelines of village community center were derived as follows: Both of two alternatives can be used as a model of village community center. The dining and living space in the center should be opened and large. Both of indoor and outdoor toilet should be arranged in village community center. Also, each toilet for man and woman should be separated.

하천폭의 국부적 축소 및 확대에 따른 수리특성 연구

최한규,김주석,백효선 江原大學校 産業技術硏究所 2007 産業技術硏究 Vol.27 No.B

This research investigated the way of generating the flowing of water in case of artificial fluctuation of river width by the unidimensional numerical analysis in order to reconstruct vertical and expanse features of flowing, and the problem of existing numerical analysis in accordance with local enlargement and reduction of river through hydraulic model experiments with results of numerical analysis. The result revealed that when the local section change in the same river is exist, it showed 0.93m in the case of no change of local section in the hydraulic model experiments and numerical analysis, however, it presented 1.645m on the occasion of local section changes in the hydraulic model experiments and numerical analysis, In other words, there was a significant difference in the existing numerical analysis, when there was a local section change. As a result of the experimental section for the enlargement and reduction of local river width, due to the sensitive change for fluctuation of flood discharge, there was a significant difference between numerical analysis and hydraulic model experiments. In addition, the result of comparison between the enlargement and reduction of local river width confirmed that the result of numerical analysis with hydraulic model experiments showed larger generation of deviation in case of enlargement of section than in case of reduction of section.