http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Parambadath, Surendran,Mathew, Aneesh,Kim, Su Yeon,Park, Sung Soo,Ha, Chang-Sik International Union of Pure and Applied Chemistry 2018 Pure and Applied Chemistry Vol.90 No.5
<P><B>Abstract</B></P><P>The direct removal of arsenate (AsO<SUB>4</SUB><SUP>3−</SUP>) and chromate (CrO<SUB>4</SUB><SUP>2−</SUP>) from water were achieved using a Fe<SUP>3+</SUP>-bis-ethylenediamine complex-bridged periodic mesoporous organosilica with a 20% organosilane content (Fe-EDPMO-20). The bridged Fe<SUP>3+</SUP>-bis-ethylenediamine complex was introduced to the pore wall of the PMO by combining the pre-complexation and co-condensation processes. N,N′-bis[3-(triethoxysilyl)propyl]ethylenediamine (TESEN) and tetramethyl orthosilicate (TMOS) as silica precursors were used with cetyltrimethylammonium bromide (CTABr) as a surfactant under basic conditions for the preparation of highly ordered Fe-EDPMO-20. Transmission electron microscopy, X-ray diffraction, and N<SUB>2</SUB>adsorption-desorption measurements confirmed that the Fe-EDPMO-20 had an ordered hexagonal p6mm mesostructure. The material had a Brunauer-Emmett-Teller surface area of 734 m<SUP>2</SUP>g<SUP>−1</SUP>, pore diameter of 2.6 nm, and pore volume of 0.61 cm<SUP>3</SUP>g<SUP>−1</SUP>. UV-vis and X-ray photoelectron spectroscopy confirmed that Fe<SUP>3+</SUP>was embedded in the coordination site by the nitrogen atoms from ethylenediamine. The adsorption efficiencies of arsenate and chromate ions by Fe-EDPMO-20 were examined as a function of pH, stirring time, amount of adsorbent, and initial concentration of metal ion solution. The maximum adsorption for arsenate and chromate were 156 and 102 mg g<SUP>−1</SUP>within 6 and 24 h, respectively, at pH 4.</P>
Singh, N. Jiten,Lee, Han Myoung,Suh, Seung Bum,Kim, Kwang S. International Union of Pure and Applied Chemistry 2007 Pure and Applied Chemistry Vol.79 No.6
<P>For the design of functional molecules and nanodevices, it is very useful to utilize nanorecognition (which is governed mainly by interaction forces such as hydrogen bonding, ionic interaction, π-H/π-π interactions, and metallic interactions) and nanodynamics (involving capture, transport, and release of electrons, photons, or protons). The manifestation of these interaction forces has led us to the design and realization of diverse ionophores/receptors, organic nanotubes, nanowires, molecular mechanical devices, molecular switches, enzyme mimetics, protein folding/unfolding, etc. In this review, we begin with a brief discussion of the interaction forces, followed by some of our representative applications. We discuss ionophores with chemo-sensing capability for biologically important cations and anions and explain how the understanding of hydrogen bonding and π-interactions has led to the design of self-assembled nanotubes from calix[4]hydroquinone (CHQ). The binding study of neutral and cationic transition metals with the redox system of hydroquinone (HQ) and quinone (Q) predicts what kind of nanostructures would form. Finally, we look into the conformational changes between stacked and edge-to-face conformers in π-benzoquinone-benzene complexes controlled by alternating electrochemical potential. The resulting flapping motion illustrates a promising pathway toward the design of mobile nanomechanical devices.</P>
Korotcenkov, Ghenadii,Gulina, Larisa B.,Cho, Beongki,Brinzari, Vladimir,Tolstoy, Valery P. International Union of Pure and Applied Chemistry 2014 Pure and Applied Chemistry Vol. No.
<P><B>Abstract</B></P><P>The ability of successive ionic layer deposition (SILD) technology to synthesize gold clusters on the surface of tin(IV) oxide and indium(III) oxide films is discussed. It was shown that during the process, concentration of active sites that are capable of absorbing gold ions, and the size of the gold particles thus formed, may be controlled by both concentration of the solutions used and the number of SILD cycles. Thus, SILD methodology, employing separate and multiple stages of adsorption and reduction of adsorbed species, has considerable potential for customizing the properties of the deposited metal nanoparticles. In particular, it is shown that during the deposition of gold nanoparticles on the surface of tin(IV) oxide and indium(III) oxide films by SILD methodology, conditions can be realized under which the size of gold nanoclusters may be controllably varied between 1-3 nm and 50 nm. A model is proposed for the formation of gold clusters during the SILD process.</P>
The effect of acceptor-substituted alkynes in gold-catalyzed intermolecular reactions
International Union of Pure and Applied Chemistry 2014 Pure and Applied Chemistry Vol. No.
<P><B>Abstract</B></P><P>Alkynes substituted with electron-withdrawing groups participated in various intermolecular reactions with olefin substrates, including [4 + 2] annulation of propiolic acids, intermolecular metathesis-type reaction and carboalkoxylation involving allylethers.</P>
Amide I IR probing of core and shell hydrogen-bond structures in reverse micelles
Lee, Jooyong,Jeon, Jonggu,Kim, Min-Seok,Lee, Hochan,Cho, Minhaeng International Union of Pure and Applied Chemistry 2014 Pure and Applied Chemistry Vol. No.
<P><B>Abstract</B></P><P>The properties of<I>N</I>-methylacetamide (NMA) molecules encapsulated in the reverse micelles (RMs) formed by anionic surfactant aerosol OT (AOT), are studied with vibrational spectroscopy and computation. Vibrational spectra of the amide I′ mode of the fully deuterated NMA-<I>d</I><SUB>7</SUB>show gradual increase of peak frequencies and line broadening as the size of RMs decreases. Analyses of the spectral features reveal the presence of three states of NMA-<I>d</I><SUB>7</SUB>that correspond to NMA located in the core of water phase (absorption frequency of 1606 cm<SUP>-1</SUP>) and two types of interfacial NMA near the surfactant layer (1620 and 1644 cm<SUP>-1</SUP>). In larger RMs with water content<I>w</I><SUB>0</SUB>= [D<SUB>2</SUB>O]/[AOT] ≥ 10, only the first two states are observed, whereas in smaller RMs, the population of the third state grows up to 25 % at<I>w</I><SUB>0</SUB>= 2. These results indicate the general validity of the two-state core/shell model for the confined aqueous solution of NMA, with small modifications due to the system-dependent solute-interface interaction. However, simulations of small RM systems with<I>w</I><SUB>0</SUB>≤ 15 show continuous variations of the population, frequency shifts, and the solute-solvent interaction strengths at solute-interface distance less than 4 Å. Thus, the distinction of solute core/shell states tends to be blurred in small RMs but is still effective in interpreting the average spectroscopic observables.</P>