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차세대 리튬이차전지를 위한 산화물 고체전해질의 연구동향
강병우(Byoungwoo Kang),박희택(, Heetaek Park),우승준(Seungjun Woo),강민석(Minseok Kang),김아빈(Abin Kim) 한국세라믹학회 2018 세라미스트 Vol.21 No.4
Since the electrification of vehicles has been extended, solid-state batteries have been attracting a lot of interest because of their superior safety. Especially, polymer, sulfide, and oxide based materials are being studied as solid electrolytes, and each type of materials has advantaged and disadvantages over others. Oxide electrolytes has higher chemical and electrochemical stability compared to the other types of electrolytes. However, ionic conductivity isn’t high enough as much as that of organic liquid electrolytes. Also, there are many difficulties of fabricating solidstate batteries with oxide based electrolytes because they require a sintering process at very high temperature (above ~800 ℃). Herein, we review recent studies of solid-state batteries with oxide based electrolytes about the ionic conductivity, interfacial reactions with Li metal, and preparation of solid-state cell.