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      • Recycling of EAF Dust by Semi-continuous High Kinetic Process

        Zoz H.,Kaupp G.,Ren H.,Goepel K.,Naimi-Jamal M. R. 한국분말야금학회 2006 한국분말야금학회 학술대회논문집 Vol.2006 No.1

        The horizontal high energy rotor ball mill () is used to break and activate dry solids. It is used for dry-milling and in the vertical mount for wet-milling in leaching processes. Technical electric arc furnace (EAF) dust with high contents of zinc oxide, zinc ferrite and magnetite is efficiently separated by ambient temperature leaching. The process shows promise for industrial application

      • High Performance Cements and Advanced Ordinary Portland Cement Manufacturing by HEM-refinement

        Zoz H.,Jaramillo V. D.,Tian Z.,Trindade B.,Ren H.,Chimal-V. O.,Torre S.Diaz de la 한국분말야금학회 2006 한국분말야금학회 학술대회논문집 Vol.2006 No.1

        High Energy Milling (HEM) is applied for the grinding of cement and this can lead to substantial refinement (<2μm) and mechanically activation of the powder particles. The present paper reviews the preliminary studies, explains the novel technique and suggests the route into commercial application. Particular attention is paid to wear results with an applied unit where no substantial wear was found after 4000 h of operation.

      • Stellite bearings for liquid Zn-/Al-Systems with advanced chemical and physical properties by Mechanical Alloying and Standard-PM-Route

        Zoz H.,Benz H.U.,Huettebraeucker K.,Furken L.,Ren H.,Reichardt R. 한국분말야금학회 2000 한국분말야금학회 학술대회논문집 Vol.2000 No.1

        An important business-field of world-wide steel-industry is the coating of thin metal-sheets with zinc, zinc-aluminum and aluminum based materials. These products mostly go into automotive industry. in particular for the car-body. into building and construction industry as well as household appliances. Due to mass-production, the processing is done in large continuously operating plants where the mostly cold-rolled metal-strip as the substrate is handled in coils up to 40 tons unwind before and rolled up again after passing the processing plant which includes cleaning, annealing, hot-dip galvanizing / aluminizing and chemical treatment. In the liquid Zn, Zn-AI, AI-Zn and AI-Si bathes a combined action of corrosion and wear under high temperature and high stress onto the transfer components (rolls) accounts for major economic losses. Most critical here are the bearing systems of these rolls operating in the liquid system. Rolls in liquid system can not be avoided as they are needed to transfer the steel-strip into and out of the crucible. Since several years, ceramic roller bearings are tested here [1.2], however, in particular due to uncontrollable Slag-impurities within the hot bath [3], slide bearings are still expected to be of a higher potential [4]. The today's state of the art is the application of slide bearings based on Stellite\ulcorneragainst Stellite which is in general a 50-60 wt% Co-matrix with incorporated Cr- and W-carbides and other composites. Indeed Stellite is used as the bearing-material as of it's chemical properties (does not go into solution), the physical properties in particular with poor lubricating properties are not satisfying at all. To increase the Sliding behavior in the bearing system, about 0.15-0.2 wt% of lead has been added into the hot-bath in the past. Due to environmental regulations. this had to be reduced dramatically_ This together with the heavily increasing production rates expressed by increased velocity of the substrate-steel-band up to 200 m/min and increased tractate power up to 10 tons in modern plants. leads to life times of the bearings of a few up to several days only. To improve this situation. the Mechanical Alloying (MA) TeChnique [5.6.7.8] is used to prOduce advanced Stellite-based bearing materials. A lubricating phase is introduced into Stellite-powder-material by MA, the composite-powder-particles are coated by High Energy Milling (HEM) in order to produce bearing-bushes of approximately 12 kg by Sintering, Liquid Phase Sintering (LPS) and Hot Isostatic Pressing (HIP). The chemical and physical behavior of samples as well as the bearing systems in the hot galvanizing / aluminizing plant are discussed. DependenCies like lubricant material and composite, LPS-binder and composite, particle shape and PM-route with respect to achievable density. (temperature--) shock-reSistibility and corrosive-wear behavior will be described. The materials are characterized by particle size analysis (laser diffraction), scanning electron microscopy and X-ray diffraction. corrosive-wear behavior is determined using a special cylinder-in-bush apparatus (CIBA) as well as field-test in real production condition. Part I of this work describes the initial testing phase where different sample materials are produced, characterized, consolidated and tested in the CIBA under a common AI-Zn-system. The results are discussed and the material-system for the large components to be produced for the field test in real production condition is decided. Outlook: Part II of this work will describe the field test in a hot-dip-galvanizing/aluminizing plant of the mechanically alloyed bearing bushes under aluminum-rich liquid metal. Alter testing, the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed. Part III of this project will describe a second initial testing phase where the won results of part 1+11 will be transferred to the AI-Si system. Part IV of this project will describe the field test in a hot-dip-aluminizing plant of the mechanically alloyed bearing bushes under aluminum liquid metal. After testing. the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed.

      • Highly Economic and High Quality Zinc-flake Manufacturing by High Kinetic Processing

        Ren H.,Benz H.U.,Chimal V. O.,Corral G. M.S.,Zhang Y.,Jaramillo V. D.,Zoz H. 한국분말야금학회 2006 한국분말야금학회 학술대회논문집 Vol.2006 No.1

        The present paper is a parameter study of zinc flake production using a Simoloyer CM01 horizontal high energy rotary ball mill. The manufactured flakes have a dimension in thickness (t) < 1μm and diameters (d) 5-100 μm, consequently a ratio d/t up to 200. The flake geometry is mainly controlled by the variation of process parameters such as rotary speed of the rotor, ratio of powder/ball charge, load ratio of the system, process temperature, operating model and the quantity of process control agent (PCA). The Zn flakes were characterized by SEM, tap densitometry, laser diffraction and water coverage measurement.

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