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        Robust Super-Repellent Anisotropic Silica Films by Emulsion-Based Sol–Gel Growth

        Yingyu Zhou,Hongling Chen 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.1

        In this paper, anisotropic SiO2 with different morphologies were synthesized through an emulsion-based one-pot method by adding various silane coupling agents. Silane coupling agents affected the growth of silica nanostructures at the oil/water interfaces. Robust super-repellent film that showed great durability under different harsh conditions were obtained by bonding the self-assembled anisotropic silica nanostructures (ASN) film to substrate by the commercial acrylic adhesive. The ¯lm switched from superhydrophobic (157.1°) to superhydrophilic (0°) after being heat-treated at 500 ℃. Further, silane treatment with addition of acid reduced the time of modification. Meanwhile, silane grafting density was improved and superhydrophobicity of calcinated ASN films was regenerated.

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