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Kim, Jong-Hyung,El-Khouly, Mohamed E.,Araki, Yasuyuki,Ito, Osamu,Kay, Kwang-Yol The Chemical Society of Japan 2008 Chemistry letters Vol.37 No.5
<P>Photoinduced processes of a newly synthesized subphthalocyanine–diazobenzene–fullerene triad have been studied by the time-resolved spectroscopic techniques. On photo-excitation of subphthalocyanine (SubPc) moiety, the fluorescence quenching of SubPc was observed, suggesting the energy-transfer process from singlet excited energy of the light-harvesting SubPc to C<SUB>60</SUB> through diazobenzene. This finding is confirmed by the nanosecond transient absorption of the triplet excited state of C<SUB>60</SUB>.</P>
Fukuzumi, Shunichi,Saito, Kenji,Ohkubo, Kei,Khoury, Tony,Kashiwagi, Yukiyasu,Absalom, Mark A.,Gadde, Suresh,D'Souza, Francis,Araki, Yasuyuki,Ito, Osamu,Crossley, Maxwell J. Royal Society of Chemistry 2011 Chemical communications Vol.47 No.28
<P>Multiple photosynthetic reaction centres have successfully been constructed using supramolecular complexes of zinc porphyrin dendrimers [D(ZnP)<SUB><I>n</I></SUB>: <I>n</I> = 4, 8, 16] with fulleropyrrolidine bearing a pyridine ligand (C<SUB>60</SUB>py). Efficient energy migration occurs completely between the ZnP units of dendrimers prior to the electron transfer with increasing the generation of dendrimers to attain an extremely long charge–separation lifetime.</P> <P>Graphic Abstract</P><P>Efficient energy migration occurs more efficiently between the ZnP units of dendrimers prior to the electron transfer with increasing the generation of dendrimers to attain an extremely long charge–separation lifetime. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c1cc11725d'> </P>