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      • KCI등재후보

        SYNTHESIS AND CHARACTERIZATION OF A HIGHLY CRYSTALLINE NOVEL MESOPOROUS C- AND N-CODOPED TiO2 NANOPHOTOCATALYST

        SRINIVASAN ANANDAN,YASURO IKUMA,KATSUYOSHI KAKINUMA,KOICHI NIWA 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2008 NANO Vol.3 No.5

        Here we report, for the first time, the synthesis of highly crystalline novel mesoporous carbon/nitrogen (C/N)-codoped TiO2 (MCNT) using ethylene diamine and carbon tetrachloride as the source for nitrogen and carbon, KIT-6 as the template, and titanium tetraisopropoxide as the TiO2 source. The obtained material has been unambiguously characterized by various sophisticated techniques. XRD and TEM analysis revealed that the MCNT material possesses highly crystalline 3D structure with a continuous network of mesoporous channels as well as structure corresponding to TiO2. UV-DRS analysis indicated that light absorption shifted to lower energy and stronger absorption in the visible light region. XPS revealed that C and N were doped effectively and C or N dopants might be present in the chemical environment of Ti–O–N or Ti–O–C. It has been found that the material is highly crystalline and possesses high surface area, pore volume and uniform pore size distribution. Owing to its textural characteristics, it could be useful for various applications, such as photocatalysis, fuel cells, bulky biomolecule adsorption and nanotechnology.

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