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        Fabrication of a Thermoregulating Cotton Fabric with Enhanced Flame Retardancy via Layer-by-layer Assembly

        Yunbo Chen,Xiangyu Zhu,Luying Chen,Bijia Wang,ZhiPing Mao,Xueling Feng,Xiaofeng Sui,Hong Xu 한국섬유공학회 2022 Fibers and polymers Vol.23 No.9

        The lack of thermoregulating functionality and high flammability for cotton fabrics greatly restricts theirapplication in high-performance fields. Herein, we report a versatile layer-by-layer (LBL) assembly strategy for introducing amultilayered film consisting of phase change microcapsules and ammonium polyphosphate to cotton fabric, endowing cottonwith thermoregulation and flame retardant properties. The coated fabrics were characterized based on scanning electronmicroscopy (SEM), water-vapor transmission rate (WVT), thermogravimetry (TG), differential scanning calorimetry (DSC),limiting oxygen index (LOI) and infrared thermal imaging. A fabric deposited with 20 bilayers (MCPM/APP-20) shows anappropriate WVT (50.57 g/m2·h) and improved flame retardancy with an LOI of 24.5 % and residual carbon of 34.53 %. Italso shows a melting enthalpy of 30.09 J/g, which results in a temperature difference of 6.4 °C compared with pristine cotton. The functional properties endowed by the LBL assembly are found to be reasonably durable, with the melting enthalpy andresidual carbon of MPCM/APP-20 reduced to 17.69 J/g and 19.64 %, respectively, after 30 laundering cycles. This studyprovides a convenient way to develop multifunctional cotton fabrics that can be good candidates for high-performancetextiles.

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