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        Correlation of H_2S and COS in the hot coal gas stream and its importance for high temperature desulfurization

        Jianglong Yu,Liping Chang,Wei Xie,Dehai Wang 한국화학공학회 2011 Korean Journal of Chemical Engineering Vol.28 No.4

        Thermodynamic analysis of the correlation of H_2S and COS has been carried out at the temperature range of 400-650 ℃ at which high temperature desulfurization of coal gas is usually performed. The correlation of the two sulfur species is mainly through the reaction H_2S+CO→COS+H_2. Simulated coal gas with the following composition CO 32.69%, H_2 39.58%, CO_2 18.27%, N2 8.92% and H_2S 0.47% was used in this study, and the equilibrium concentrations of the two species at different temperatures were calculated. The results of Fe-based sorbents during sulfidation were compared with calculations. It is concluded that the above reaction may reach equilibrium concentration in the presence of the Fe-based sorbents, which means the Fe-based sorbents may effectively catalyze the reaction between H_2S and CO. Because of the correlation of the two sulfur species, both can be effectively removed at high temperatures simultaneously, offering high temperature desulfurization some advantages over low temperature desulfurization processes.

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        Suppression of stray electrons in the negative ion accelerator of CRAFT NNBI test facility

        Yang Yuwen,Wei Jianglong,Xie Junwei,Gu Yuming,Xie Yahong,Hu Chundong 한국원자력학회 2023 Nuclear Engineering and Technology Vol.55 No.3

        Comprehensive Research Facility for Fusion Technology (CRAFT) is an integration of different demonstrating or testing facilities, which aim to develop the critical technology or composition system towards the fusion reactor. Due to the importance and challenge of the negative ion based neutral beam injection (NNBI), a NNBI test facility is included in the framework of CRAFT. The initial object of CRAFT NNBI test facility is to obtain a H0 beam power of 2 MW at the energy of 200e400 keV for the pulse duration of 100 s. Inside the negative ion accelerator of NNBI system, the interactions of the negative ions with the background gas and electrodes can generate abundant stray electrons. The stray electrons can be further accelerated and dumped on the electrodes or eject from the accelerator. The stray electrons, including the ejecting electrons, cause the unwanted particle and heat flux onto the electrodes and the inner components of beamline (especially the temperature sensitive cryopump). The suppression of the stray electrons from the CRAFT accelerator is carried out via a series of design and simulation works. The paper focuses the influence of different magnetic field configurations on the stray electrons and the character of the ejecting electrons.

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