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        Co2+-coordination-assisted enhancement of mechanical and iodynamic properties of 3D graphene-based double network hydrogels for all-solid-state supercapacitors

        He Binhong,Wen Shuntao,Wen Zhiming,Liang Yan,Yang Qianxi,Zhou Minjie,Wang Wei,Wang Guo-Xiang 한국탄소학회 2024 Carbon Letters Vol.34 No.3

        This paper reports an enhanced strategy for improving the mechanical flexibility and ionic kinetic properties of a double network hydrogel based on Co2+-coordination assistance. The modified double-network hydrogel was obtained by using acrylic acid and N, N-dimethylacrylamide as monomers, adding cross-linking agents and 3D nitrogen-doped graphenes. The tensile fracture rate of the modified hydrogel was 1925% and its tensile strength was 1696 kPa. In addition, the hydrogel exhibited excellent ionic dynamics, and its application to an all-solid-state supercapacitor was able to achieve a specific capacitance of up to 182.8 F g−1. The supercapacitor exhibited an energy density of 34.2 Wh kg−1, even when operating at a power density of 5 kW kg−1, highlighting its significant potential for practical applications.

      • KCI등재

        Emergy analysis-based study of the sustainable development of Kunming’s urban eco-economic system

        Li Hui,Cao Lei,Chen Youbin,Qiu Huiyi,Huang Xue,Guo Wanqi,Wang Shuntao,Sheng Weiguo,Zhou Yilu,Xu Qing 서울시립대학교 도시과학연구원 2023 도시과학국제저널 Vol.27 No.2

        We studied Kunming’s urban eco-economic system’s evolution from 2009 to 2018, using the emergy theory and method; with the entropy evaluation method, we analyzed the system’s natural, social and economic subsystems to know its sustainable development capacity. The results show that the system’s emergy structure has clearly improved, and its renewable resources’ emergy has been rationally employed. The environment load ratio, after reaching its peak in 2011, has been decreasing, and the environment stress has becoming lower year by year, as is conducive to sustainable development. Its eco-economic system, however, is highly dependent on the internal resources; its emergy self-sufficiency ratio indicates that it does not see sufficient utilization of imported emergy and feels excessive stress on its internal resources. It witnesses relatively high emergy intensity. The current population is about twice of its renewable resources’ population carrying capacity, and its dramatically growing population is presenting even high pressure on its social subsystems. This indicates that the living standard per capita in Kunming is lower than the national average. All of these factors will hinder the sustainable development of Kunming’s urban eco-economic system. Our analysis of attribute classification shows that it is more appropriate to calculate the tourist revenue by taking into account export emergy. At the same time, the analysis results of sustainable development emergy indexes obtained by ESI, EISD, euehi, euehi’ and entropy method are compared, which shows that the entropy method is able to better reflect the dynamic changes of the sustainable development capacity of its urban eco-economic system because it introduces all indicators of social, economic and natural subsystems for evaluation. In a word, sustainable development capacity represents the outcome of tradeoff and coordination of the three subsystems of society, economy and nature, and we can formulate corresponding strategies based on the above research findings.

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