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Chuah, Chong Yang,Li, Wen,Samarasinghe, S.A.S.C.,Sethunga, G.S.M.D.P.,Bae, Tae-Hyun Elsevier 2019 Microporous and mesoporous materials Vol.290 No.-
<P><B>Abstract</B></P> <P>HKUST-1 nanocrystals with large accessible surface areas and high porosity were functionalized with amine groups and incorporated into polymer matrices to form mixed-matrix membranes for application in CO<SUB>2</SUB> capture. This gas permeation study reveals that pristine HKUST-1 nanocrystals are able to increase the gas permeabilities of polymer membranes with no noticeable effect on CO<SUB>2</SUB>/N<SUB>2</SUB> selectivity as a result of their high porosity and large pore dimensions. Contrarily, 20 wt% amine-functionalized HKUST-1 can improve the CO<SUB>2</SUB>/N<SUB>2</SUB> selectivity of polymer membranes by as much as 38%. As shown in a detailed analysis of the diffusivity-solubility, the amine-functionalized HKUST-1 suppressed N<SUB>2</SUB> solubility and diffusivity but enhanced CO<SUB>2</SUB> diffusivity. This resulted in an increased CO<SUB>2</SUB>/N<SUB>2</SUB> perm-selectivity. Meanwhile, the pristine HKUST-1 nanocrystals increased the diffusivity and solubility of both species in a non-selective manner. These results indicate the feasibility of tuning the CO<SUB>2</SUB> separation performance of mixed-matrix membranes by introducing amine functionality into the filler.</P> <P><B>Highlights</B></P> <P> <UL> <LI> HKUST-1 and amine-functionalized HKUST-1 nanocrystals were successfully synthesized. </LI> <LI> HKUST-1 nanocrystals improved CO<SUB>2</SUB> permeability with no effect on CO<SUB>2</SUB> selectivity. </LI> <LI> Amine-functionalized HKUST-1 enhanced CO<SUB>2</SUB>/N<SUB>2</SUB> selectivity and CO<SUB>2</SUB> permeability. </LI> <LI> Amine-functionalized HKUST-1 suppressed N<SUB>2</SUB> solubility and diffusivity substantially. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>