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- 저자 : Qingxi Cao (검색결과 2 건)
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Hiu Liu,Nana Xin,Qingxi Cao,Long Sha,Dezhi Sun,Shaohua Wu 한국화학공학회 2009 Korean Journal of Chemical Engineering Vol.26 No.4
The Computational fluid dynamics (CFD) code PHOENICS is applied to simulate and evaluate the combustion process within the furnace of a 1,000MW dual circle tangential firing single furnace lignite-fired ultra supercritical (USC) boiler. The dependence on overfire air (OFA) positioning on the combustion process is studied. The results show that the highest temperature appears on the upside of the burner zone close to the front wall, and the high temperature zone rises with elevated OFA positions. However, the temperature field distributions are similar despite differing OFA positions. The char content near the rear wall is higher than that near the front wall, and below the furnace arch, coal particles concentrate towards the front wall. Also with elevated OFA positions, nitrogen oxide (NOx) concentrations at the outlet fall, but char content increases. In regard to NOx emission and char burnout, the suggested optimal distance from the OFA center to the center of the uppermost primary air nozzle should be 6 meters.
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Oxidation of Zhundong subbituminous coal by Fe2+/H2O2 system under mild conditions
Shuai Chen,Wei Zhou,Mingjun Liu,Guangbo Zhao,Qingxi Cao,Bojun Zhao,Kaikai Kou,Jihui Gao 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.4
Oxidation of coal under mild conditions is effective not only to understand the macromolecular network structure of coal but also to produce useful chemicals, allowing more efficient application of coal resources. In this work, the mild oxidation of Zhundong subbituminous coal (ZS) by Fe2+/H2O2 system was carried out under various conditions, including [Fe2+]/[H2O2] molar ratio, temperature, H2O2 concentration and oxidation time. The liquid oxidation products were analyzed using gas chromatography/mass spectrometry (GC/MS), and the chemical structure changes were studied using Fourier transform infrared spectroscopy (FTIR). The results suggest that the oxidation efficiency of ZS with H2O2 is enhanced with the aid of Fe2+. The optimum conditions were determined to be [Fe2+]/[H2O2] molar ratio of 0.00453, H2O2 concentration of 3mol/L, 60 oC and 4 h according to the oxidation conversion rate. In total, 25 compounds were identified, which could be categorized as six group components. Most of them are valuedadded chemicals, and the content of benzene carboxylic acids is the highest among them, making up 29.99% of all group components in total relative content (TRC). -CH2- should be primary bridge connecting the aromatic rings, and alkylene chains linking three aromatic rings are abundant in ZS.
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