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      • Influence of reduced graphene oxide-TiO<sub>2</sub> composite nanofibers in organic indoline DN350 based dye sensitized solar cells

        Patil, Jyoti V.,Mali, Sawanta S.,Shaikh, Jasmin S.,Patil, Akhilesh P.,Patil, Pramod S.,Hong, Chang Kook Elsevier 2019 Synthetic metals Vol.256 No.-

        <P><B>Abstract</B></P> <P>In this study, the highly efficient organic indoline DN350 based dye sensitized solar cells (DSSCs) have been fabricated using reduced graphene oxide (rGO)-TiO<SUB>2</SUB> composite nanofibers (NFs) and tested its photovoltaic properties. The influence of the rGO on the morphology, structural properties of the TiO<SUB>2</SUB> NFs have been characterized by various techniques. Our photovoltaic results revealed that the modified rGO-TiO<SUB>2</SUB> composite NFs exhibited higher power conversion efficiency (PCE) in comparison with the pristine-TiO<SUB>2</SUB> NFs. The electrochemical analysis indicated that the GO content provides more active sites results in higher dye adsorption which consequently improves the DSSCs performance. Our optimized sample containing 4 mg-rGO-TiO<SUB>2</SUB> NFs exhibited the best performance with 4.43% PCE, which is higher than the pristine-TiO<SUB>2</SUB> NFs (3.83%). Overall, this study presents the rGO-TiO<SUB>2</SUB> composite NFs as a novel strategy for enhancing the efficiency of the organic indoline DN350 based DSSCs.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Electrospun reduced graphene oxide (rGO)-TiO<SUB>2</SUB> composite nanofibers. </LI> <LI> rGO-TiO<SUB>2</SUB> composite nanofibers for organic indoline DN350 DSSCs. </LI> <LI> The 4.42% power conversion efficiency achieved for DSSC. </LI> </UL> </P>

      • KCI등재

        Spherical crystallization of ezetimibe for improvement in physicochemical and micromeritic properties

        Ashwini Patil,Yogesh Pore,Yogesh Gavhane,Shitalkumar Patil,Sachinkumar Patil 한국약제학회 2014 Journal of Pharmaceutical Investigation Vol.44 No.3

        Spherical agglomerates of ezetimibe (EZT)were prepared with hydrophilic polymers; polyvinyl pyrrolidoneK30 (PVP) and/or poloxamer 188 (poloxamer) atdrug to polymer ratios of 1:1 (w/w) by spherical crystallizationtechnique, in order to improve its physicochemicaland micromeritic properties. Three different bridging liquids;chloroform, dichloromethane and/or ethyl acetatealong with good solvent acetone and poor solvent waterwere used to form six batches of agglomerates. Initialcharacterization of all batches in terms of micromeritic andphysicochemical properties resulted in optimization of (A3,EZT:PVP:ethyl acetate) and (B3, EZT:poloxamer:ethylacetate) batches and hence further investigated for drug–polymer interaction, crystallinity and morphology usingFTIR, XRPD, DSC and SEM techniques. The resultsindicated presence of hydrogen bonding, crystallinity andspherical shape in agglomerates. Therefore, the optimizedagglomerates (B3) were directly compressed into tablet. Unfortunately, drug release from the tablet was not satisfactory,suggesting a need of disintegrant from dissolutionpoint of view. Therefore, these agglomerates were recompressedincorporating certain excipients and evaluated asper pharmacopoeia. The dissolution rate of prepared tabletwas similar to that of marketed tablet (p[0.05). It couldbe concluded that spherical crystallization could be one ofthe effective and alternative approaches for improvedperformance of EZT and its tablet formulation.

      • SCISCIESCOPUS

        Morphologically controlled electrodeposition of fern shaped Bi<sub>2</sub>Te<sub>3</sub> thin films for photoelectrochemical performance

        Patil, P.B.,Mali, S.S.,Kondalkar, V.V.,Mane, R.M.,Patil, P.S.,Hong, C.K.,Bhosale, P.N. Elsevier Sequoia 2015 Journal of Electroanalytical Chemistry Vol.758 No.-

        Bismuth telluride (Bi<SUB>2</SUB>Te<SUB>3</SUB>) thin films have been proved to be important materials for thermoelectric application. Rapid development of photovoltaic materials has raised new hopes due to directly converting sun light to electricity. We report here a simple electrochemical synthesis route for the preparation of well-defined Bi<SUB>2</SUB>Te<SUB>3</SUB> nanostructures for photoelectrochemical solar cell application. Classification of crystal structure, surface morphology and elemental composition of resulting deposits were methodically characterized by X-ray diffraction (XRD) pattern, Raman spectroscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) and its photoelectrochemical performance (PEC). The potential range and electrochemical reactions relevant to the growth of Bi<SUB>2</SUB>Te<SUB>3</SUB> thin films were studied by cyclic voltammetry (CV). Furthermore, the influence of deposition variables such as applied deposition potential and effect of different surfactants (cationic, anionic and non-ionic) on morphology, crystal orientation associated with the film growth and photoelectrochemical performance were investigated systematically. The photoelectrochemical conversion efficiency recorded for Bi<SUB>2</SUB>Te<SUB>3</SUB> is 0.083%.

      • SCISCIESCOPUS

        Fabrication of nanostructured ZnO thin films based NO<sub>2</sub> gas sensor via SILAR technique

        Patil, Vithoba L.,Vanalakar, Sharadrao A.,Patil, Pramod S.,Kim, Jin H. Elsevier Sequoia 2017 Sensors and actuators. B Chemical Vol.239 No.-

        <P><B>Abstract</B></P> <P>Zinc oxide (ZnO) thin films have been widely used as an effective gas sensor element. In the present study, nanostructured thin films of ZnO were prepared by using the simplistic and economical successive ion layer adsorption and reaction (SILAR) technique. The effects of SILAR cycles on the structural, optical, surface morphological and electrical properties of nanostructured ZnO thin films were investigated. Characterization techniques such as XRD, UV-vis, PL, FESEM, and Hall measurement were utilized to study the physical and chemical properties of the synthesized films. XRD confirms the formation of hexagonal phase structural ZnO thin films. FE-SEM analysis reveals the formation of well-dispersed ZnO nanoparticles having sizes of ∼18–40nm. The SILAR cycles play a key role in the synthesis of nanostructured ZnO thin films and it is found that, with increasing SILAR cycles, the grain size continues increasing. Optical studies confirm the presence of oxygen vacancies in synthesized ZnO thin films. Finally, the ZnO thin films were exposed to NO<SUB>2</SUB> gas with a concentration of 100ppb–200ppm and the resulting resistance transient was recorded. The nanostructured ZnO thin films synthesized at 30 SILAR cycles displays an enhancement of gas sensing performance and exhibit significantly higher responses (∼5%per ppm). Moreover, our ZnO thin-film-based gas sensor is sensitive to very low concentrations of dangerous NO<SUB>2</SUB> (100ppb). The sensitive gas sensor used to trace level NO<SUB>2</SUB> detection, synthesized via simple SILAR route proves the novelty of our work. The present report provides a new direction in fabricating nanostructured ZnO thin films for low-cost and efficient gas sensing applications.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Preparation of nanostructured ZnO by using the simplistic SILAR technique. </LI> <LI> Formation of well-dispersed ZnO nanoparticles having sizes of ∼18–40nm. </LI> <LI> The ZnO thin films were exposed to NO<SUB>2</SUB> gas with a concentration of 100ppb–200ppm. </LI> <LI> Our ZnO based gas sensor is sensitive to very low concentrations of dangerous NO<SUB>2</SUB> (100ppb). </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

      • Pethidine induced changes in ovarian follicular kinetics and biochemical parameters in albino rats

        Patil, Somanath Reddy,Patil, Saraswati B,Malashetty, Vijaykumar B Kyung Hee Oriental Medicine Research Center 2006 Oriental pharmacy and experimental medicine Vol.6 No.4

        Pethidine at the dose level of 0.5 mg and 0.75 mg/100 g body weight administered for 20 days to the cycling albino rats caused decrease in the ovarian weight and its protein content. The ovarian folliculogenesis in treated rats is hampered; as a result the follicles which are at the different stages of growth underwent regression. Therefore, the number of healthy follicles is reduced and atretic follicles increased. The elevated levels of ovarian cholesterol and decreased level of glycogen in the pethidine treated rats indicates the inhibition brought in steroidogenesis, which is dependent on pituitary gonadotrophins.

      • SCISCIESCOPUS
      • SCISCIESCOPUS

        Confinement of Ag<sub>3</sub>PO<sub>4</sub> nanoparticles supported by surface plasmon resonance of Ag in glass: Efficient nanoscale photocatalyst for solar H<sub>2</sub> production from waste H<sub>2</sub>S

        Patil, S.S.,Patil, D.R.,Apte, S.K.,Kulkarni, M.V.,Ambekar, J.D.,Park, C.J.,Gosavi, S.W.,Kolekar, S.S.,Kale, B.B. Elsevier 2016 Applied Catalysis B Vol.190 No.-

        <P>Ag3PO4 is a good photocatalyst but ubiquitously known for its photocorrosion problem during photocatalytic reaction. Therefore, stabilization of Ag3PO4 with retaining its fundamental properties has immense importance. With this motivation, we designed Ag3PO4 glass nanocomposite to resolve the problem of photocorrosion. Moreover, the effect of size quantization on photocatalytic activity has also been demonstrated by growing the cubic Ag3PO4 nanoparticles with size in the range of 3-9 nm in glass matrix via melt and quenching method. The band gap of Ag3PO4 has been tuned (2.56-2.25 eV) in glass matrix with respect to size. Considering the size tunable band gap of Ag3PO4 glass nanocomposite within visible region, it is demonstrated as a photocatalyst for hydrogen (H-2) production from copious hazardous waste H2S. The utmost H-2 production i.e. 3920.4 mu mol h(-1) g(-1) is obtained using 1 gm of Ag3PO4 glass nanocomposite powder. The apparent quantum yield for H-2 production is calculated to be 5.51% for Ag3PO4 glass nanocomposite. Interestingly, presence of plasmonic Ag was also observed in Ag3PO4 glass nanocomposite which contributes for H-2 production through enhanced light absorption, efficient charge separation and improved stability. Recycling study of sample reveals stable H-2 production efficiency and good stability of the photocatalyst. Surprisingly, catalyst can be reused many times and recovery of catalyst is possible just rinsing with distilled water. All these results demonstrate directly the feasibility of designing a new generation photocatalysts. (C) 2016 Published by Elsevier B.V.</P>

      • SCISCIESCOPUS

        Investigations on silver/polyaniline electrodes for electrochemical supercapacitors

        Patil, Dipali S.,Shaikh, J. S.,Pawar, S. A.,Devan, R. S.,Ma, Y. R.,Moholkar, A. V.,Kim, J. H.,Kalubarme, R. S.,Park, C. J.,Patil, P. S. The Royal Society of Chemistry 2012 Physical chemistry chemical physics Vol.14 No.34

        <P>Polyaniline (PANI) and silver doped polyaniline (Ag/PANI) thin films were deposited on stainless steel substrates by a dip coating technique. To study the effect of doping concentration of Ag on the specific capacitance of PANI the concentration of Ag was varied from 0.3 to 1.2 weight percent. Fourier transform-infrared and Fourier transform-Raman spectroscopy, and energy dispersion X-ray techniques were used for the phase identification and determination of the doping content in the PANI films, respectively. The surface morphology of the films was examined by Field Emission Scanning Electron Microscopy, which revealed a nanofiber like structure for PANI and nanofibers with bright spots of Ag particles for the Ag/PANI films. There was decrease in the room temperature electrical resistivity of the Ag/PANI films of the order of 10<SUP>2</SUP> with increasing Ag concentration. The supercapacitive behavior of the electrodes was tested in a three electrode system using 1.0 M H<SUB>2</SUB>SO<SUB>4</SUB> electrolyte. The specific capacitance increased from 285 F g<SUP>−1</SUP> (for PANI) to 512 F g<SUP>−1</SUP> for Ag/PANI at 0.9 weight percent doping of Ag, owing to the synergic effect of PANI and silver nanoparticles. This work demonstrates a simple strategy of improving the specific capacitance of polymer electrodes and may also be easily adopted for other dopants.</P> <P>Graphic Abstract</P><P>The presence of Ag nanoparticles on PANI nanofibers provides a least resistance path to electron transportation. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c2cp41757j'> </P>

      • Tailor-made dicationic ionic liquid as a fluorescent sensor for detection of hydroquinone and catechol

        Patil, Sandip K.,Patil, Suryakant A.,Vadiyar, Madagonda M.,Awale, Deepak V.,Sartape, Ashish S.,Walekar, Laxman S.,Kolekar, Govind B.,Ghorpade, Uma V.,Kim, Jin H.,Kolekar, Sanjay S. Elsevier 2017 Journal of molecular liquids Vol.244 No.-

        <P>We are exploring a geminal dicationic ionic liquid (DCIL), 1,1'-(propane-1,3-diyl)bis(4-aminopyridin-1-ium) dihydroxide, [C-3(Amp)(2)][OH](2) as a fluorescent probe for detection of dihydroxybenzenes viz. hydroquinone (HQ) and catechol (CC). Simple and sensitive spectrofluorometric method is described which accomplished with efficient quenching of fluorescence of aqueous DCIL by dihydroxybenzenes. The sensor offers good linear detection range of 1-400 mu M and 1-1000 mu M with detection limits of 0.31 mu M and 0.40 mu M for HQ and CC, respectively. Under alkaline conditions HQ/CC oxidizes to corresponding benzoquinones which interact with DCIL and consequently quenching of fluorescence is occurred. This essential alkaline condition is in situ provided by purposefully tuned DCIL to having basic nature. The plausible quenching mechanism that involves photo-induced charge transfer pathway is evidently discussed. The proposed method is competent over a broad detection range. Selectivity of method is demonstrated by scrutinizing intervention of various interfering species. Recoveries from water sample analysis emphasize the possible use of DCIL probe in the detection of HQ and CC from water sources. The proposed method certainly confers a new approach in sensing techniques for dihydroxybenzenes. (C) 2017 Published by Elsevier B.V.</P>

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