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Zeolite Membranes: Functionalizing of Properties by Tailored Compositions
Richter, Hannes,Weyd, Marcus,Simon, Adrian,Kuhnert, Jan-Thomas,Gunther, Christiane,Voigt, Ingolf,Michaelis, Alexander The Membrane Society of Korea 2017 멤브레인 Vol.27 No.6
Membrane separation is a technology of low energy consumption. Membranes made of zeolites are of great interest because their fixed and open pores in the size of small molecules inside crystalline structures allow separation processes under harsh conditions. While zeolite NaA (LTA-type) is industrially used for dewatering of organic solvents, its pore size and thermal and hydrothermal stability can be tuned by exchange of framework and extra-framework elements. SOD with pores of only 0.28 nm is of great interest for $H_2$- und $H_2O$-separation and also can be tuned by ion exchange. Zeolites open the opportunity to create membranes of adapted separation behavior for small molecules in conditions of surrounding technical processes. 분리막을 이용한 분리 기술은 에너지 소요가 적다. 제올라이트를 기반으로 제작한 분리막의 경우, 결정 구조 내에 작은 분자 크기의 기공을 갖고 있어 이를 이용하여 가혹한 조건에서도 분리가 가능하기 때문에, 그 관심도가 높다. NaA (LTA 유형의 제올라이트) 제올라이트의 경우, 산업적으로 유기 용매에서 수분을 제거하는 데 많이 사용되는 데, 해당 기공 크기나 열적/수열안정성은 제올라이트 내부나 외부의 원소를 바꿔줌으로써 조절할 수 있다. 더 작은 0.28 nm 크기를 지닌 SOD 유형의 제올라이트의 경우, 수소나 물 분리에 적합하여 그 관심도가 높아지고 있으며, 이 제올라이트 유형 또한, 이온교환과 같은 방법으로 성질을 변경할 수 있다. 제올라이트는 주변 기술 및 공정 조건에 맞게 작은 분자들을 적절하게 분리할 수 있는 분리막을 창출할 수 있다는 장점을 지닌 소재이다.
Zeolite Membranes: Functionalizing of Properties by Tailored Compositions
Hannes Richter,Marcus Weyd,Adrian Simon,Jan-Thomas Kühnert,Christiane Günther,Ingolf Voigt,Alexander Michaelis 한국막학회 2017 멤브레인 Vol.27 No.6
Membrane separation is a technology of low energy consumption. Membranes made of zeolites are of great interest because their fixed and open pores in the size of small molecules inside crystalline structures allow separation processes under harsh conditions. While zeolite NaA (LTA-type) is industrially used for dewatering of organic solvents, its pore size and thermal and hydrothermal stability can be tuned by exchange of framework and extra-framework elements. SOD with pores of only 0.28 nm is of great interest for H 2 - und H 2 O-separation and also can be tuned by ion exchange. Zeolites open the opportunity to create membranes of adapted separation behavior for small molecules in conditions of surrounding technical processes.
제올라이트 분리막: 조성 변경을 통한 분리막 성질의 조절
Hannes Richter,Marcus Weyd,Adrian Simon,Jan-Thomas Kühnert,Christiane Günther,Ingolf Voigt,Alexander Michaelis 한국막학회 2017 멤브레인 Vol.27 No.6
분리막을 이용한 분리 기술은 에너지 소요가 적다. 제올라이트를 기반으로 제작한 분리막의 경우, 결정 구조 내에 작은 분자 크기의 기공을 갖고 있어 이를 이용하여 가혹한 조건에서도 분리가 가능하기 때문에, 그 관심도가 높다. NaA (LTA 유형의 제올라이트) 제올라이트의 경우, 산업적으로 유기 용매에서 수분을 제거하는 데 많이 사용되는 데, 해당 기공 크기나 열적/수열안정성은 제올라이트 내부나 외부의 원소를 바꿔줌으로써 조절할 수 있다. 더 작은 0.28 nm 크기를 지닌 SOD 유형의 제올라이트의 경우, 수소나 물 분리에 적합하여 그 관심도가 높아지고 있으며, 이 제올라이트 유형 또한, 이온 교환과 같은 방법으로 성질을 변경할 수 있다. 제올라이트는 주변 기술 및 공정 조건에 맞게 작은 분자들을 적절하게 분리할 수 있는 분리막을 창출할 수 있다는 장점을 지닌 소재이다. Membrane separation is a technology of low energy consumption. Membranes made of zeolites are of great interest because their fixed and open pores in the size of small molecules inside crystalline structures allow separation processes under harsh conditions. While zeolite NaA (LTA-type) is industrially used for dewatering of organic solvents, its pore size and thermal and hydrothermal stability can be tuned by exchange of framework and extra-framework elements. SOD with pores of only 0.28 nm is of great interest for H2- und H2O-separation and also can be tuned by ion exchange. Zeolites open the opportunity to create membranes of adapted separation behavior for small molecules in conditions of surrounding technical processes.
RNA buffers the phase separation behavior of prion-like RNA binding proteins
Maharana, Shovamayee,Wang, Jie,Papadopoulos, Dimitrios K.,Richter, Doris,Pozniakovsky, Andrey,Poser, Ina,Bickle, Marc,Rizk, Sandra,Guillé,n-Boixet, Jordina,Franzmann, Titus M.,Jahnel, Marcus,Mar American Association for the Advancement of Scienc 2018 Science Vol.360 No.6391
<P>Prion-like RNA binding proteins (RBPs) such as TDP43 and FUS are largely soluble in the nucleus but form solid pathological aggregates when mislocalized to the cytoplasm. What keeps these proteins soluble in the nucleus and promotes aggregation in the cytoplasm is still unknown. We report here that RNAcritically regulates the phase behavior of prion-like RBPs. Low RNA/protein ratios promote phase separation into liquid droplets, whereas high ratios prevent droplet formation in vitro. Reduction of nuclear RNA levels or genetic ablation of RNA binding causes excessive phase separation and the formation of cytotoxic solid-like assemblies in cells. We propose that the nucleus is a buffered system in which high RNA concentrations keep RBPs soluble. Changes in RNA levels or RNA binding abilities of RBPs cause aberrant phase transitions.</P>
Luca Papavero,Gregor Schmeiser,Ralph Kothe,Bronek Boszczyk,Oliver Heese,Yoshiharu Kawaguchi,Anna MacDowall,Claes Olerud,Nikolaos Paidakakos,Anastasios Panagiotou,Tobias Pitzen,Marcus Richter,K. Daniel 대한척추신경외과학회 2020 Neurospine Vol.17 No.1
Objective: To validate with a prospective study a decision-supporting coding system for the surgical approach for multilevel degenerative cervical myelopathy. Methods: Ten cases were presented on an internet platform, including clinical and imaging data. A single-approach (G1), a choice between 2 (G2), or 3 approaches (G3) were options. Senior and junior spine surgeons analyzed 7 parameters: location and extension of the compression of the spinal cord, C-spine alignment and instability, general morbidity and bone diseases, and K-line and multilevel corpectomy. For each parameter, an anterior, posterior, or combined approach was suggested. The most frequent letter or the last letter (if C) of the resulting 7-letter code (7LC) suggested the surgical approach. Each surgeon performed 2 reads per case within 8 weeks. Results: G1: Interrater reliability between junior surgeons improved from the first read (κ=0.40) to the second (κ=0.76, p<0.001) but did not change between senior surgeons (κ=0.85). The intrarater reliability was similar for junior (κ=0.78) and senior (κ=0.71) surgeons. G2: Junior/senior surgeons agreed completely (58%/62%), partially (24%/23%), or did not agree (18%/15%) with the 7LC choice. G3: junior/senior surgeons agreed completely (50%/50%) or partially (50%/50%) with the 7LC choice. Conclusion: The 7LC showed good overall reliability. Junior surgeons went through a learning curve and converged to senior surgeons in the second read. The 7LC helps less experienced surgeons to analyze, in a structured manner, the relevant clinical and imaging parameters influencing the choice of the surgical approach, rather than simply pointing out the only correct one.