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RISS 인기검색어
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- 저자 : Hajikhanmirzaei, L. (검색결과 2 건)
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Safaei, E.,Hajikhanmirzaei, L.,Alavi, S.,Lee, Y.I.,Wojtczak, A.,Jaglicic, Z. Pergamon Press 2016 Polyhedron Vol.118 No.-
<P>Two mononuclear manganese(III) complexes of bis(phenol) diamine ligands (H2LNEX) and 2,3,4,5-tetrabromocatechol (TBC), MnLNEX(TBC), were synthesized as models for enzyme-catechol adducts of the intradiol Fe-dependent catechol dioxygenases. X-ray analysis of the complexes has revealed that the manganese center in the model compounds has a distorted octahedral coordination sphere and is surrounded by the L-NEX ligand and two oxygen atoms of TBC. The phenolate moieties of MnLNEX(TBC) were electrochemically oxidized to phenoxyl radicals. Consistent with the electrochemical results, quantum chemical calculations showed that the HOMO and LUMO levels on both complexes are on the phenolate moieties. The paramagnetic properties of the manganese(III) center of the complexes have been investigated by magnetic susceptibility measurements. H2LNEX/MnCl2 showed quite good enzyme-mimicking reactivity. It utilized molecular oxygen in carrying out the cleavage of di-tert-butyl catechol at room temperature. To the best of our knowledge this is the second report where a manganese complex can perform oxygenase and not oxidase activity. (C) 2016 Elsevier Ltd. All rights reserved.</P>
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Safaei, E.,Hajikhanmirzaei, L.,Karimi, B.,Wojtczak, A.,Cotic, P.,Lee, Y.I. Pergamon Press 2016 Polyhedron Vol.106 No.-
<P>Mononuclear copper complexes of four-dentate N2O2 bis(phenol) diamine ligands (H2LNEX X: C and OB in which C and OB are chloro and tert-butyl-methoxy substituents on phenol groups) have been synthesized and characterized by IR, UV-Vis, single crystal X-ray diffraction, magnetic susceptibility studies and cyclic voltammetry techniques. The CuLNEX complexes show the square pyramid geometry of the coordination sphere with the copper centers surrounded by two nitrogen and oxygen atoms from the coordinating ligand and an axially bound water molecule. The effective magnetic moments of 1.7 and 1.8 BM confirm a monomer complex with copper(II) center. Electrochemical oxidation of these complexes yielded the corresponding Cu(II)-phenoxyl radical species. In addition, CuLNEX complexes, have shown efficient catalytic activities for TEMPO-mediated oxidation of a set of alcohols to the corresponding aldehydes in the presence of molecular oxygen as oxidant at room temperature. (C) 2015 Elsevier Ltd. All rights reserved.</P>
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