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- 저자 : Fariborz Omidi (검색결과 2 건)
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Zahra Beigzadeh,Farideh Golbabaei,Monireh Khadem,Fariborz Omidi,Mirghani Seyed Someah,Seyed Jamaleddin Shahtaheri 한국고분자학회 2020 Macromolecular Research Vol.28 No.4
Background: The incidence of neoplasm has significantly increased around the world over the last decades, resulting in use of anti-neoplastic drugs and the potential for occupational exposure to these drugs. One of the most commonly used chemotherapeutic drugs for treatment of malignancies is 5-fluorouracil (5-FU). Objectives: In this study, in order to develop an appropriate adsorbent for selective extraction of ultra-trace 5-fluorouracil from urine samples, molecularly imprinted membranes (MIMs) of 5-FU were prepared by encapsulating molecularly imprinted polymer nanoparticles (MIP-NPs) into the electrospun polyethylene terephthalate (PET) nanofibers. Methods: The MIP-NPs encapsulated into electrospun PET nanofibers were prepared by precipitation polymerization technique. These MIMs were used as selective sorbents for solid-phase extraction (SPE) of ultra-trace 5-FU from different samples prior to the analysis by high performance liquid chromatography (HPLC). Central Composite Design (CCD) was used for optimization of effective parameters in sorption and desorption steps of the molecularly imprinted membrane solid phase extraction (MIMSPE). Results: The optimum operating conditions for the proposed method were pH: 6.2, amount of sorbent: 10.3mg, and absorption time: 20.5h, the volume of eluent: 1 mL, the composition of elution solvent: the ratio of 90.3:9.7 methanol and acetic acid, and desorption time: 1.27 h. Under these optimized conditions, the limit of detection for 5-FU by MIMSPE was 0.07 μg L-1. The recoveries of 5-FU from urine sample ranged from 92.95±3.85 to 94.85±2.85%. Conclusion: The proposed MIMSPE-HPLC method can potentially be applied for selective detection of 5-FU in real samples with no special sample pretreatment steps.
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Reza Ali Fallahzadeh,Mohammad Hassan Ehrampoush,Mohsen Nabi Meybodi,Mohammad Taghi Ghaneian,Arash Dalvand,Fariborz Omidi,Mohammad Hossein Salmani,Hossien Fallahzadeh,Amir Hossein Mahvi 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.6
The presence of antibiotics in the environment as persistent micropollutants, due to their widespread consumption, has increased the concerns about the harmful effects of these compounds on human and animal health. Advanced oxidation processes are one of the most effective methods to remove these types of organic pollutants. In this study, amoxicillin (AMX) removal in a modified photoelectro-Fenton (PEF) reactor in which porous stainless steel was used as a cathode electrode, and the ability of air injection into its center to produce H2O2 was investigated. A graphite anode electrode equipped with iron rings was used to increase the electrochemical reaction surface and produce iron ions. The effect of current density, time, and electrolyte concentration on AMX removal efficiency was evaluated by Box-Behnken design method. Subsequently, the effect of AMX concentration variable and pH on removal efficiency was investigated. Finally, the chemical oxygen demand (COD) removal efficiency, toxicity, and effluent activity from the PEF reactor were investigated. The results showed that the modified photoelectro-Fenton process could have efficiency of 99% to remove AMX, in 20min using current density of 36 mA/cm2 and 16mM/L electrolyte concentration. Reducing pH and AMX concentration increased the removal efficiency. The PEF process can completely remove the COD in 58 min. Also, toxicity studies indicated an effective reduction in the effluent. This modified reactor improves the efficiency of the PEF process, which, in addition to the 99% removal of AMX, provides a proper function for COD removal, reducing the toxicity properties of the effluent.
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