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        Radical Copolymerization of Acrylic Acid and OEGMA475: Monomer Reactivity Ratios and Structural Parameters of the Copolymer

        Hossein Abdollahi,Vahid Najafi,Farshid Ziaee,Kourosh Kabiri,Farhad Narimani 한국고분자학회 2014 Macromolecular Research Vol.22 No.12

        Alternative copolymers of acrylic acid (AA) and oligo(ethylene glycol) methyl ether methacryate (475 g/mol (OEGMA475)) macromer, having various amounts of two monomers, were synthesized using aqueous solutionfree radical copolymerization at 50 °C with ammonium persulfate (APS) as an initiator. The structures of the copolymerswere confirmed by nuclear magnetic resonance (NMR) spectroscopy. In fact, samples with different molarratios of two monomers in deionized water were prepared and subsequently copolymerization reaction was performedto low conversion levels (below 10%). Monomer reactivity ratios of OEGMA475, AA pair were estimatedusing the Finemann-Ross (FR), inverted Finemann-Ross (IFR), Kelen-Tüdös (KT), extended Kelen-Tüdös (EKT),Mayo-Lewis (ML) and Yezrelieve-Brokhina-Roskin (YBR) graphical methods. The value ranged from 0.908 to0.963 for rOEGMA and from 0.208 to 0.243 for rAA depending on conversion percentage and calculation methods ofmonomer reactivity ratios. In all the cases, rOEGMA×rAA<1 and rOEGMA>rAA indicate that the resulting copolymer has atendency toward alternation with an azeotropic point in MOEGMA=0.905. Structural parameters of the copolymerswere obtained by calculating the dyad monomer sequence fractions and the mean sequence length. Keywords: oligo(ethylene glycol) methyl ether methacrylate, acrylic acid, monomer reactivity ratios, altern

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