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        논문 : 노외기계시스템공학 ; 코어샘플을 이용한 질소 등 토양성분 현장 측정방법의 비교평가

        권기영 ( G. Kweon ),( Eric Lund ),( Chase Maxton ),( Dreiling Kenton ) 한국농업기계학회 2011 바이오시스템공학 Vol.36 No.2

        Several methods of in-field measurements of Nitrogen and other soil properties using cores extracted by a hydraulic soil sampler were evaluated. A prototype core scanner was built to accommodate Veris Technologies commercial Vis-NIRS equipment. The testing result for pH, P and Mg were close to RPD (Ratio of Prediction to Deviation=Standard deviation/RMSE) of 2, however the scanner could not achieve the goal of RPD of 2 on some other properties, especially on nitrate nitrogen (NO3) and potassium (K). In situ NIRS/EC probe showed similar results to the core scanner; pH, P and Mg were close to RPD of 2, while NO3 and K were RPD of 1.5 and 1.2, respectively. Correlations between estimations using the probe and the core scanner were strong, with r2>0.7 for P, Mg, Total N, Total C and CEC. Preliminary results for mid-IR spectroscopy showed an r2 of 0.068 and an RMSE for nitrate (N) of 18ppm, even after the removal of calcareous samples and possible N outlier. After removal of calcareous samples on a larger sample set, results improved considerably with an r2 of 0.64 and RMSE of 6 ppm. However, this was only possible after carbonate samples were detected and eliminated, which would not be feasible under in-field measurements. Testing of NO3 and K ion-selective electrodes (ISEs) revealed promising results, with acceptable errors measuring soil solutions containing nitrate and potassium levels that are typical of production agriculture fields.

      • KCI등재

        Comparison of In-Field Measurements of Nitrogen and Other Soil Properties with Core Samples

        Kweon, Gi-Young,Lund, Eric,Maxton, Chase,Kenton, Dreiling Korean Society for Agricultural Machinery 2011 바이오시스템공학 Vol.36 No.2

        Several methods of in-field measurements of Nitrogen and other soil properties using cores extracted by a hydraulic soil sampler were evaluated. A prototype core scanner was built to accommodate Veris Technologies commercial Vis-NIRS equipment. The testing result for pH, P and Mg were close to RPD (Ratio of Prediction to Deviation = Standard deviation/RMSE) of 2, however the scanner could not achieve the goal of RPD of 2 on some other properties, especially on nitrate nitrogen ($NO_3$) and potassium (K). In situ NIRS/EC probe showed similar results to the core scanner; pH, P and Mg were close to RPD of 2, while $NO_3$ and K were RPD of 1.5 and 1.2, respectively. Correlations between estimations using the probe and the core scanner were strong, with $r^2$ > 0.7 for P, Mg, Total N, Total C and CEC. Preliminary results for mid-IR spectroscopy showed an $r^2$ of 0.068 and an RMSE for nitrate (N) of 18 ppm, even after the removal of calcareous samples and possible N outlier. After removal of calcareous samples on a larger sample set, results improved considerably with an $r^2$ of 0.64 and RMSE of 6 ppm. However, this was only possible after carbonate samples were detected and eliminated, which would not be feasible under in-field measurements. Testing of $NO_3$ and K ion-selective electrodes (ISEs) revealed promising results, with acceptable errors measuring soil solutions containing nitrate and potassium levels that are typical of production agriculture fields.

      • KCI등재

        Soil Profile Measurement of Carbon Contents using a Probe-type VIS-NIR Spectrophotometer

        Kweon, Gi-Young,Lund, Eric,Maxton, Chase,Drummond, Paul,Jensen, Kyle Korean Society for Agricultural Machinery 2009 바이오시스템공학 Vol.34 No.5

        An in-situ probe-based spectrophotometer has been developed. This system used two spectrometers to measure soil reflectance spectra from 450 nm to 2200 nm. It collects soil electrical conductivity (EC) and insertion force measurements in addition to the optical data. Six fields in Kansas were mapped with the VIS-NIR (visible-near infrared) probe module and sampled for calibration and validation. Results showed that VIS-NIR correlated well with carbon in all six fields, with RPD (the ratio of standard deviation to root mean square error of prediction) of 1.8 or better, RMSE of 0.14 to 0.22%, and $R^2$ of 0.69 to 0.89. From the investigation of carbon variability within the soil profile and by tillage practice, the 0-5 cm depth in a no-till field contained significantly higher levels of carbon than any other locations. Using the selected calibration model with the soil NIR probe data, a soil profile map of estimated carbon was produced, and it was found that estimated carbon values are highly correlated to the lab values. The array of sensors (VIS-NIR, electrical conductivity, insertion force) used in the probe allowed estimating bulk density, and three of the six fields were satisfactory. The VIS-NIR probe also showed the obtained spectra data were well correlated with nitrogen for all fields with RPD scores of 1.84 or better and coefficient of determination ($R^2$) of 0.7 or higher.

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