이온강화 소다라임 유리의 열처리에 따른 강화 풀림현상

황종희,임태영,이미재,김진호,Hwang, Jonghee,Lim, Tae-Young,Lee, Mi Jai,Kim, Jin-Ho 한국세라믹학회 2015 한국세라믹학회지 Vol.52 No.1

Recently, the use of ion-exchange strengthened glass has increased sharply, as it is now used as the cover glass for smart phone devices. Therefore, many researchers are focusing on methods that can be used to strengthen ion-exchange glass. However, research on how the improved strength can be maintained under thermal environment of device manufacturing is still insufficient. We tested the degradation of the characteristics of ion-exchange soda-lime glass samples, including their surface compressive stress characteristics, the depth of the ion-exchange layer (DOL), flexural strength, hardness, and modulus of rupture (MOR) values. Degradation of the characteristics of the ion-exchange glass samples occurred when they were heat-treated at a temperature that exceeded $350^{\circ}C$.

다양한 블록 크기의 전역 탐색 알고리즘을 위한 효율적인 구조를 갖는 움직임 추정기 설계

황종희(Jonghee Hwang),최윤식(Yoonsik Choe) 大韓電子工學會 2009 電子工學會論文誌-SD (Semiconductor and devices) Vol.46 No.11

움직임 추정은 영상 부호화 시스템에서 큰 비중을 차지하는 부분으로, 실시간 동작을 위해서는 효율적인 구조를 필요로 한다. 따라서 H.264 전체 시스템을 위한 움직임 추정기 블록의 구현은 부호화 과정을 고속으로 수행할 수 있도록 별도의 전용 하드웨어 모듈로 설계하는 것이 바람직하다. 본 논문에서는 많은 연산량을 효율적으로 줄일 수 있도록 병렬 처리를 바탕으로 움직임 추정 감지 블록, 41개의 SAD(Sum of Absolute Difference)값 계산 블록, 최소의 SAD값 계산과 움직임 벡터 생성 블록을 제안하고자 한다. 움직임 추정 감지 블록과 최소의 SAD값 계산기에서는 선계산(pre-computation) 방법을 적용함으로써, 입력 Switching Activity를 줄여 고속 구현이 가능하도록 하였으며, 움직임 추정 감지 블록과 41개의 SAD값 계산 블록에서 가장 많은 부분을 차지하는 가산기 구조를 일반적으로 사용되는 Ripple Carry Adder 대신에 Carry Skip Adder를 적용함으로써, Adder Tree 구조를 고속으로 처리할 수 있도록 하였다. 또한 외부에서 탐색 영역 제어와 같은 주요 변수를 쉽게 제어할 수 있도록 하여, 하드웨어 구조의 효율성을 높였다. 시뮬레이션 및 FPGA 검증 결과, 움직임 추정기의 임계 경로를 발생시키는 MED블록에서 일반적인 구조를 적용했을 때보다 19.89%의 Delay 감소 효과를 얻을 수 있었다. The motion estimation in video encoding system occupies the biggest part. So, we require the motion estimator with efficient structure for real-time operation. And for motion estimator's implementation, it is desired to design hardware module of an exclusive use that perform the encoding process at high speed. This paper proposes motion estimation detection block(MED), 41 SADs(Sum of Absolute Difference) calculation block, minimum SAD calculation and motion vector generation block based on parallel processing. The parallel processing can reduce effectively the amount of the operation. The minimum SAD calculation and MED block uses the pre-computation technique for reducing switching activity of the input signal. It results in high-speed operation. The MED and 41 SADs calculation blocks are composed of adder tree which causes the problem of critical path. So, the structure of adder tree has changed the most commonly used ripple carry adder(RCA) with carry skip adder(CSA). It enables adder tree to operate at high speed. In addition, as we enabled to easily control key variables such as control signal of search range from the outside, the efficiency of hardware structure increased. Simulation and FPGA verification results show that the delay of MED block generating the critical path at the motion estimator is reduced about 19.89% than the conventional strukcture.

유리조성에 따른 백색 LED용 색변환 유리의 광특성

허철민,황종희,임태영,김진호,이미재,유종성,박태호,문주호,Huh, Cheolmin,Hwang, Jonghee,Lim, Tae-Young,Kim, Jin-Ho,Lee, MiJai,Yoo, Jong-Sung,Park, Tae-Ho,Moon, Jooho 한국재료학회 2012 한국재료학회지 Vol.22 No.12

Yellow phosphor dispersed color conversion glasses are promising phosphor materials for white LED applications because of their good thermal durability, chemical stability, and anti-ultraviolet property. Six color conversion glasses were prepared with high Tg and low Tg specimens of glass. Luminous efficacy, luminance, CIE (Commission Internationale de l'Eclairage) chromaticity, CCT (Correlated Color Temperature), and CRI (Color Rendering Index) of the color conversion glasses were analyzed according to the PL spectrum. Color conversion glasses with high Tg glass frit, sintered at higher temperature, showed better luminous properties than did color conversion glasses with low Tg glass frit. The characteristics of the color conversion glass depended on the glass composition rather than on the sintering temperature. The XRD peaks of the YAG phosphor disappeared in the color conversion glass with major components of $B_2O_3$-ZnO-$SiO_2$-CaO and, in the XRD results, new crystalline peaks of $BaSi_2O_5$ appeared in the color conversion glass with major components of $Bi_2O_3$-ZnO-$B_2O_3$-MgO. The characteristics of CIE chromaticity, CCT, and the CRI of low Tg color conversion glasses showed worse color properties than those of high Tg color conversion glasses. However, these color characteristics of low Tg glasses were improved by thickness variation. So color conversion glasses with good characteristics of both luminous and color properties were attained.

Y₂O₃와 Fe₂O₃가 포함된 LAS 계 결정화 유리 특성

이지선,임태영,황종희,이영진,전대우,김선욱,라용호,김진호,Lee, Ji-Sun,Lim, Tae-Young,Hwang, Jonghee,Lee, Youngjin,Jeon, Dae-Woo,Kim, Sun-Woog,Ra, Yong-Ho,Kim, Jin-Ho 한국결정성장학회 2019 韓國結晶成長學會誌 Vol.29 No.4

용융 온도를 낮추고 균질화에 영향을 줄 수 있는 yttrium oxide(산화 이트륨)과 iron oxide(산화철)를 사용하여 $LI_2O-Al_2O_3-SiO_2$ 계 결정화 유리를 제조하였다. 조핵제는 Zirconium sulfate(황산지르코늄)을 사용했고, 유리 점도를 낮추기 위해 calcium phosphate(인산칼슘)을 사용해 유리 유동성을 원활하게 하였다. 결정화 유리는 열충격 $750^{\circ}C$ 이상을 만족했고, $800^{\circ}C$ 이상에서 열팽창계수가 급격하게 상승하는 온도를 약 $30^{\circ}C$ 이상 시프트 하였다. 따라서 yttrium oxide와 iron oxide 포함하는 LAS 계 유리는 고온에서 양호한 용융 상태와 우수한 열팽창 저항성을 확인하였고 특수 주방용 재료 분야에 충분히 활용이 가능하리라 판단되었다. The glass-ceramic of $Li_2O-Al_2O_3-SiO_2$ system was fabricated by using yttrium oxide and iron oxide that it can reduce the melting temperature and affect the homogenization. Zirconium sulfate was used as a nucleation agent. Calcium phosphate was used to improve the flow the glass so as reduce the viscosity of the glass. The glass-ceramics met a thermal shock test of more than $750^{\circ}C$ and the temperature at which the coefficient of thermal expansion rapidly increased at over $800^{\circ}C$ was shifted by about the above $30^{\circ}C$. Therefore, it is concluded that the glass-ceramic of $Li_2O-Al_2O_3-SiO_2$ system with yttrium oxide and iron oxide was founded to have good melting conditions and excellent thermal expansion resistance at high temperature such as special field for kitchen utensils.

ZnO가 포함된 BaO-GeO₂-La₂O₃ 계 광학 유리 특성

이지선,임태영,황종희,이영진,전대우,김선욱,라용호,김진호,Lee, Ji-Sun,Lim, Tae-Young,Hwang, Jonghee,Lee, Youngjin,Jeon, Dae-Woo,Kim, Sun-Woog,Ra, Yong-Ho,Kim, Jin-Ho 한국결정성장학회 2019 韓國結晶成長學會誌 Vol.29 No.5

$3{\sim}5{\mu}m$ 범위의 중적외선에서 75 % 이상의 투과율을 갖는 $BaO-GeO_2-La_2O_3-ZnO$ 계 유리를 제조 및 특성을 평가하였다. Flow button test를 통해 유리 용융이 가능한 조성을 선택 후, ZnO를 10 mol%, 20 mol% 각각 첨가하여 $1350^{\circ}C$에서 1시간 동안 용융하여 $BaO-GeO_2-La_2O_3-ZnO$ 계 유리를 제조하였다. 이 중에서 ZnO를 20 mol% 포함하는 16 mol% BaO-56 mol% $GeO_2-8mol%$ $La_2O_3-20mol%$ ZnO 계 유리 전이 온도 $660^{\circ}C$ 이하, 굴절률 1.70 이상, Knoop 경도 530 이상 값을 가지는 것을 확인하였다. 따라서, ZnO를 20 mol% 포함하는 $BaO-GeO_2-La_2O_3-ZnO$ 계 유리는 저온에서 양호한 용융 상태와 우수한 광학적 특성을 확인하였고 특수 광학용 재료 분야에 충분히 활용이 가능하리라 판단되었다. The glass of $BaO-GeO_2-La_2O_3-ZnO$ system with a transmittance of more than 75 % at mid-wave infrared (MWIR) region in the range of $3{\mu}m$ to $5{\mu}m$ is manufactured and its property is evaluated. After selecting construction that can melt glass through flow button test, $BaO-GeO_2-La_2O_3$ system where 10 mol%, 20 mol% of ZnO were added respectively were melted at $1350^{\circ}C$ for 1 hour and $BaO-GeO_2-La_2O_3$ system of glass was manufactured. Among them, with 20 mol% of ZnO, 16 mol% BaO-56 mol% $GeO_2-8mol%$ $La_2O_3-16mol%$ ZnO system of glass was found to has less than $660^{\circ}C$ of glass transition temperature, more than 1.70 of refractive index, and more than 530 of knoop hardness. Therefore, it is concluded that glass of $BaO-GeO_2-La_2O_3-ZnO$ system of glass with 20 mol% ZnO has good melting conditions at low temperatures and excellent optical properties, thus, can be utilized for special optical materials field.

CBD 방법에 의해 제조된 ZnO 나노로드의 전기적 특성

김진호,이미재,황종희,임태영,Kim, Jin-Ho,Lee, Mi-Jai,Hwang, Jonghee,Lim, Tae-Young 한국재료학회 2012 한국재료학회지 Vol.22 No.12

ZnO nanorods were successfully fabricated on Zn foil by chemical bath deposition (CBD) method. The ZnO precursor concentration and immersion time affected the surface morphologies, structure, and electrical properties of the ZnO nanorods. As the precursor concentration increased, the diameter of the ZnO nanorods increased from ca. 50 nm to ca. 150 nm. The thicknesses of the ZnO nanorods were from ca. $1.98{\mu}m$ to ca. $2.08{\mu}m$. ZnO crystalline phases of (100), (002), and (101) planes of hexagonal wurtzite structure were confirmed by XRD measurement. The fabricated ZnO nanorods showed a photoluminescene property at 380 nm. Especially, the ZnO nanorods deposited for 6 h in solution with a concentration of 0.005M showed a stronger (101) peak than they did (100) or (002) peaks. In addition, these ZnO nanorods showed a good electrical property, with the lowest resistance among the four samples, because the nanorods were densely in contact and relatively without pores. Therefore, a ZnO nanorod substrate is useful as a highly sensitive biochip substrate to detect biomolecules using an electrochemical method.

MBE 법에 의해 성장된 고종횡비 InGaN 나노와이어 광촉매

안소연,전대우,황종희,라용호,An, Soyeon,Jeon, Dae-Woo,Hwang, Jonghee,Ra, Yong-Ho 한국결정성장학회 2019 한국결정성장학회지 Vol.29 No.4

우리는 분자선 에피택시(Molecular Beam Epitaxy) 법을 사용하여 광전기화학적 물분해 수소생산용 고종횡비 GaN 기반 나노와이어를 Si 기판 위에 성공적으로 제작하였다. 주사전자현미경(SEM)과 에너지분산형 분광법(EDX)은 p-GaN:Mg 및 p-InGaN 나노와이어가 고밀도와 함께 수직으로 성장 되었음을 증명하였다. 또한, p-InGaN 나노와이어의 발광 파장을 552 nm에서 590 nm까지의 조절이 가능하다는 것을 확인하였다. 이렇게 제작된 p-InGaN 나노와이어는 태양광을 통해 외부 전위 없이 물분해가 가능한 수소생산용 광촉매로써 매우 유용하게 사용될 수 있다. We have successfully fabricated high aspect-ratio GaN-based nanowires on Si substrates using molecular beam epitaxy (MBE) system for high-efficiency hydrogen generation of photoelectrochemical water splitting. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) demonstrated that p-GaN:Mg and p-InGaN nanowires were grown vertically on the substrate with high density. Furthermore, it was also confirmed that the emission wavelength of p-InGaN nanowire can be adjusted from 552 nm to 590 nm. Such high-aspect ratio p-InGaN nanowire structure will be a solid foundation for the realization of ultrahigh-efficiency photoelectrochemical water splitting through sunlight.

Calcium Phosphate 유백제 투입량에 따른 LED Diffuser용 유백유리의 특성

구현우,임태영,황종희,김진호,이미재,신동욱,Ku, Hyun-Woo,Lim, Tae-Young,Hwang, Jonghee,Kim, Jin-Ho,Lee, Mi-Jai,Shin, Dong Wook 한국세라믹학회 2013 한국세라믹학회지 Vol.50 No.1

We fabricated translucent opal glass to replace the polycarbonate diffuser in LED lighting systems in order to solve the durability problem. Batch materials of opal glass with a composition of calcium phosphate were created and melted at $1550^{\circ}C$, and the effect of opaqueness was identified by an addition of 1~7% calcium phosphate as an opacifier raw material. As a result, translucent opal glass was obtained by the melting of the mixed batch materials with a composition of more than 5% calcium phosphate glass at $1550^{\circ}C$ for 2 hrs, which had excellent optical properties for the diffuser of a LED lighting system with no dazzling from direct light by a high haze value exceeding 90% and a low parallel transmittance value of about 5%. For the thermal properties, the thermal expansion coefficient was found to be $5.6{\sim}5.9{\times}10^{-6}/^{\circ}C$ and the softening point was $874{\sim}884^{\circ}C$. In addition, good thermal properties such as good thermal shock resistance and feasibility for use with a general manufacturing process during the forming of glass tubes and bulbs were noted. Therefore, it is concluded that this translucent opal glass can be used as a glass diffuser material for LED lighting due to its high heat resistance and high durability as a replacement for a polycarbonate diffuser.

Sol-gel 법을 이용한 내오염 반사방지 코팅막 제조

김정엽,이지선,황종희,임태영,이미재,현승균,김진호,Kim, Jung-Yup,Lee, Ji-Sun,Hwang, Jonghee,Lim, Tae-Young,Lee, Mi-Jai,Hyun, Soong-Keun,Kim, Jin-Ho 한국재료학회 2014 한국재료학회지 Vol.24 No.12

Anti-reflection coating films have used to increase the transmittance of displays and enhance the efficiency of solar cells. Hydrophobic anti-reflection coating films were fabricated on a glass substrate by sol-gel method. To fabricate an anti-reflection film with a high transmittance, poly ethylene glycol (PEG) was added to tetraethyl orthosilicate (TEOS) solution. The content of PEG was changed from 1 to 4 wt% in order to control the morphology, thickness, and refractive index of the $SiO_2$ thin films. The reflectance and transmittance of both sides of the coated thin film fabricated with PEG 4 wt% solution were 0.3% and 99.4% at 500 nm wavelength. The refractive index and thickness of the thin film were n = 1.29 and d = 105 nm. Fluoro alkyl silane (FAS) was used for hydrophobic treatment on the surface of the anti-reflection thin film. The contact angle was increased from $13.2^{\circ}$ to $113.7^{\circ}$ after hydrophobic treatment.

지르코니아 함량에 따른 내알칼리 유리섬유의 특성

이지선,임태영,이미재,황종희,김진호,현승균,Lee, Ji-Sun,Lim, Tae-Young,Lee, Mi-Jai,Hwang, Jonghee,Kim, Jin-Ho,Hyun, Soong-Keun 한국결정성장학회 2015 한국결정성장학회지 Vol.25 No.6

기존의 내알칼리 유리섬유는 복합재료의 보강섬유로 가장 널리 사용되고 있는 일반적인 E-glass fiber보다 우수한 내화학 특성을 갖고 있으나 용융유리의 점도가 너무 높아 섬유화가 어려운 문제점을 가지고 있다. 본 연구에서는 지르코니아 함량이 상용 제품에 비해 낮은 범위에서 지르코니아 함량별로 내알칼리유리섬유를 제조하고 이들의 특성을 E-glass 섬유와 비교하였다. 지르코니아의 함량을 0.5~16 wt%까지 변화시키면서 제조한 각각의 배치원료를 $1600^{\circ}C$에서 2시간 용융하여 투명하고 맑은 유리를 얻을 수 있었다. 이들 유리는 약 90 %의 높은 가시광 투과율을 나타내었고, 열적특성에서 $703{\sim}887^{\circ}C$의 연화점을 나타내었으며, 지르코니아의 함량이 증가함에 따라 연화점이 상승하는 경향을 나타내었다. 지르코니아 함량이 4 wt%인 조성을 E-glass 조성과 비교한 결과, 연화점에서는 $-94^{\circ}C$의 차이를, 고온점도에 있어서는 log3 온도가 $+68^{\circ}C$, log5 온도가 $-13^{\circ}C$의 차이를 나타내었다. 내알칼리 유리섬유를 알칼리용액에 48시간 및 72시간 침적 후 SEM을 통해 섬유의 내침식성이 양호함을 확인할 수 있었고, 인장강도도 일반 E-glass 섬유에 비해 48시간에서 1.7배와 72시간에서 2.2배의 높은 값을 나타냄을 알 수 있었다. 결론적으로 이러한 내알칼리 유리섬유는 쉬운 제조조건과 낮은 지르코니아 함량에도 불구하고 좋은 특성 때문에 일반적인 내알칼리 유리섬유로서 널리 사용될 수 있을 것으로 판단되었다. Commercial AR(Alkali Resistant)-glass fiber has a good chemical resistant property, but also has a problem of difficulty in fiberizing process because of high viscosity in melted glass compare with E-glass fiber which is the most widely used for reinforced fiber of composite materials. In this study, we fabricated AR-glass fiber with low zirconia contents compare with commercial AR-glass fiber relatively, and measured properties against E-glass fiber. We obtained transparent clear glass with zirconia contents of 0.5~16 wt% by melting at $1600^{\circ}C$ for 2 hours. These AR-glass samples had high visible transmittance of 89~90 %, softening temperature of $703{\sim}887^{\circ}C$. And softening temperatures of them were increased according to the increasing zirconia contents. Compare with E-glass, AR-glass contains 4 wt% zirconia has different value of $-94^{\circ}C$ in softening temperature, $+68^{\circ}C$ at Log3 temperature and $-13^{\circ}C$ at Log5 temperature in viscosity. We could verify good alkali resistant property of the AR-glass fiber with SEM after dipping in alkali solution for 48~72 hours, and also high tensile strength, 1.7 times compare with E-glass fiber at 48 hours and 2.2 times at 72 hours. We conclude that this AR-glass fiber can be widely used as general alkali resistant glass fiber because of easy manufacturing condition and good properties even though it has low zirconia contents.