The explosive growth of data-centric applications in artificial intelligence, edge computing, and the Internet of Things has exposed the memory–processor bottleneck of von Neumann architectures. Neuromorphic computing, which emulates the parallel an...
The explosive growth of data-centric applications in artificial intelligence, edge computing, and the Internet of Things has exposed the memory–processor bottleneck of von Neumann architectures. Neuromorphic computing, which emulates the parallel and event-driven information processing of the brain, offers a path toward energy-efficient systems; however, its success hinges on analog synaptic devices that deliver linear, symmetric, and reliable weight updates. Among emerging memories, resistive random- access memory (RRAM) is attractive for its CMOS compatibility, speed, and multilevel capability, yet filamentary switching often yields non-ideal updates, variability, sneak- path currents in cross-point arrays, and degraded behavior at cryogenic temperatures. This dissertation develops RRAM synapses addressing those hurdles across three device directions. First, a selector-less Al2O3/HfO2 RRAM is introduced, where an ultrathin Al2O3 layer serves as a built-in exponential resistor to impart strong I–V nonlinearity that suppresses sneak currents while enabling gradual two-step set switching validated by real-time transient analysis. The device achieves linear and symmetric weight updates under identical pulses, preventing half-select disturbances and delivering high handwritten-digit recognition accuracy in IBM AIHWKIT-based simulations. Second, a fully sputtered HfOy/HfOx bilayer RRAM is developed to engineer oxygen- vacancy distributions for reliable, fast analog operation. The sub-stoichiometric HfOx switching layer and oxygen-rich HfOy interface layer jointly provide uniform D2D/C2C behavior, stable multilevel retention, and linear updates with 100-ns pulse widths, with transient measurements indicating ~8-ns switching delay and pJ-level energy per update; system simulations confirm high classification accuracy with efficient training. Third, a cryogenic RRAM analog synapse (CRAS) based on the sputtered HfOy/HfOx stack is demonstrated at 90 K. By reset engineering to form partially connected filaments, the device maintains linear potentiation under identical 50-ns pulses and robust multilevel retention, addressing the tendency toward abrupt, field-driven switching in low- temperature operation. Taken together, these selector-less design principles, sputtered-stack vacancy engineering, and cryogenic operation strategies establish practical guidelines for scalable, low-power RRAM synapses suited to next-generation neuromorphic accelerators and quantum-compatible cryo-computing platforms.