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    칩 온 보드 패키지 적용을 위한 프리프레그 표면 잔류 불순물이 봉지재의 젖음성에 미치는 영향 = Effect of the Residual Impurity on the Prepreg Surface on the Wettability of Encapsulant for Chip on Board Package

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    https://www.riss.kr/link?id=A109148134

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    다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

    The effect of the residual impurity on the prepreg surface on the wettability of encapsulant for chip on board package was analyzed with microstructure, compositions and chemical bonds using a scanning electron microscope and X-ray photoelectron spectroscopy. As a result, the contact angle of w/ residual impurity sample was measured to be 28° higher than that of w/o residual impurity sample, and the C-O bond was decreased to be 4% lower than that of w/o residual impurity sample. The surface energy of the prepreg decreased because the impurity ions, Na and F, generated by the manufacturing process and wet etching, reacted chemically with the C on the prepreg surface, forming C-F bonds and breaking the C-O bonds on the prepreg surface. Therefore, the wettability of the encapsulant was degraded because the contact angle between the encapsulant and the prepreg was increased.
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    The effect of the residual impurity on the prepreg surface on the wettability of encapsulant for chip on board package was analyzed with microstructure, compositions and chemical bonds using a scanning electron microscope and X-ray photoelectron spect...

    The effect of the residual impurity on the prepreg surface on the wettability of encapsulant for chip on board package was analyzed with microstructure, compositions and chemical bonds using a scanning electron microscope and X-ray photoelectron spectroscopy. As a result, the contact angle of w/ residual impurity sample was measured to be 28° higher than that of w/o residual impurity sample, and the C-O bond was decreased to be 4% lower than that of w/o residual impurity sample. The surface energy of the prepreg decreased because the impurity ions, Na and F, generated by the manufacturing process and wet etching, reacted chemically with the C on the prepreg surface, forming C-F bonds and breaking the C-O bonds on the prepreg surface. Therefore, the wettability of the encapsulant was degraded because the contact angle between the encapsulant and the prepreg was increased.

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    참고문헌 (Reference)

    1 B. Wunderle, "Thermo-Mechanical Reliability during Technology Development of Power Chip-on-board Assemblies with Encapsulation" 15 : 1467-, 2009

    2 O. -W. Kweon, "The Development of a Multichip COB Memory Package" IEIE 419 : 1994

    3 Y. X. Liu, "Surface Graft Copolymerization Enhanced Adhesion of an Epoxy-based Printed Circuit Board Substrate(FR-4)to Copper" 22 (22): 214-, 1999

    4 박영주 ; 정건주 ; 김광석, "Research Trends in Thermal Interface Materials for Flexible and Stretchable Electronic Device(in Kor. )" 31 (31): 7-, 2024

    5 김민주 ; 현준혁 ; 허정아 ; 이소연, "Reliability of Cu Interconnect under Compressive Fatigue Deformation Varying Interfacial Adhesion Treatment(in Kor. )" 30 (30): 105-, 2023

    6 김병준 ; 정명혁 ; 황성환 ; 이호영 ; 이성원 ; 전기도 ; 박영배 ; 주영창, "Relationship between Tensile Characteristics and Failure by Folding or Bending in Cu Foil on Flexible Substrate(in Kor. )" 18 (18): 55-, 2011

    7 김민호 ; 백영남 ; 이경엽, "Plasma Treatment of Carbon/Epoxy Prepreg and its Effect on the Durability of Carbon/Epoxy Laminated Composites" 54 (54): 1325-, 2008

    8 M. S. Seo, "Package and Test to increase Semiconductor added Value" Hanol 212-216, 2020

    9 C. J. Van Oss, "Monopolar Surfaces" 28 : 35-, 1987

    10 김형준 ; 안광호 ; 오승진 ; 김도한 ; 김재성 ; 김은숙 ; 김택수, "Measurement of EMC/PCB Interfacial Adhesion Energy of Chip Package Considering Warpage(in Kor. )" 26 (26): 101-, 2019

    1 B. Wunderle, "Thermo-Mechanical Reliability during Technology Development of Power Chip-on-board Assemblies with Encapsulation" 15 : 1467-, 2009

    2 O. -W. Kweon, "The Development of a Multichip COB Memory Package" IEIE 419 : 1994

    3 Y. X. Liu, "Surface Graft Copolymerization Enhanced Adhesion of an Epoxy-based Printed Circuit Board Substrate(FR-4)to Copper" 22 (22): 214-, 1999

    4 박영주 ; 정건주 ; 김광석, "Research Trends in Thermal Interface Materials for Flexible and Stretchable Electronic Device(in Kor. )" 31 (31): 7-, 2024

    5 김민주 ; 현준혁 ; 허정아 ; 이소연, "Reliability of Cu Interconnect under Compressive Fatigue Deformation Varying Interfacial Adhesion Treatment(in Kor. )" 30 (30): 105-, 2023

    6 김병준 ; 정명혁 ; 황성환 ; 이호영 ; 이성원 ; 전기도 ; 박영배 ; 주영창, "Relationship between Tensile Characteristics and Failure by Folding or Bending in Cu Foil on Flexible Substrate(in Kor. )" 18 (18): 55-, 2011

    7 김민호 ; 백영남 ; 이경엽, "Plasma Treatment of Carbon/Epoxy Prepreg and its Effect on the Durability of Carbon/Epoxy Laminated Composites" 54 (54): 1325-, 2008

    8 M. S. Seo, "Package and Test to increase Semiconductor added Value" Hanol 212-216, 2020

    9 C. J. Van Oss, "Monopolar Surfaces" 28 : 35-, 1987

    10 김형준 ; 안광호 ; 오승진 ; 김도한 ; 김재성 ; 김은숙 ; 김택수, "Measurement of EMC/PCB Interfacial Adhesion Energy of Chip Package Considering Warpage(in Kor. )" 26 (26): 101-, 2019

    11 J. J. Kim, "Manufacturing Method of Prepreg (in Kor.)"

    12 K. K. C. Ho, "Interfacial behavior between Atmospheric Plasma Fluorinated Carbon Fibers and Poly(vinylidene fluoride)" 313 : 476-, 2007

    13 김정규 ; 손기락 ; 박영배, "Interfacial Adhesion and Reliability between Epoxy Resin and Polyimide for Flexible Printed Circuit Board(in Kor. )" 24 (24): 75-, 2017

    14 심범주 ; 최열 ; 이준신, "Improvement of COF Bending-induced Lead Broken Failure in LCD Module(in Kor. )" 21 : 265-, 2008

    15 김은경, "Heterogeneous Device Packaging Technology for the Internet of Things Applications(in Kor. )" 23 (23): 1-, 2016

    16 K. K. C. Ho, "Fluorination of Carbon fibres in Atmospheric Plasma" 45 : 775-, 2007

    17 손기락 ; 김가희 ; 박영배, "Effects of Dielectric Curing Temperature and T/H Treatment on the Interfacial Adhesion Energies of Ti/PBO for Cu RDL Applications of FOWLP(in Kor. )" 30 (30): 52-, 2023

    18 B. I. Noh, "Effect of Plasma Treatment on Adhesion Characteristics at Interfaces between Underfill and Substrate" 27 (27): 200-, 2007

    19 민경진 ; 이기욱 ; 김재동 ; 김도근 ; 이건환 ; 박영배 ; 박성철, "Effect of Ion-beam Pre-treatment of the Interfacial Adhesion of Sputter-deposited Cu film on FR-4 Substrate(in Kor. )" 47 (47): 26-, 2009

    20 민경진 ; 박영배, "Effect of Desmear Treatment on the Interfacial Bonding Mechanism of Electroless-Plated Cu film on FR-4 Substrate(in Kor. )" 19 (19): 625-, 2009

    21 J. -Y. Kim, "Development of an Automatic Test System for Chip on Boards(in Kor. )" 18 : 237-, 2003

    22 F. Steiner, "Correlation Analysis of Wettability Intermetallic Compound Formation and PCB Contamination" 41 (41): 70-, 2015

    23 H. Jiang, "Contact angles from Young’s equation in Molecular Dynamics Simulations" 147 (147): 084708-, 2017

    24 S. W. Park, "Adhesive Joint Strength of Glass/Epoxy Composites Surface treated with Nano-size Carbon Black" IEEE 2009

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